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For the practical application of thermochemistry to the development and control of tech nical processes, the data for as many substances as possible are needed in conjunction with rapid and simple methods of calculating equilibrium constants, heat balances and the EMF of galvanic cells. For these three types of calculation the following three ther modynamic functions are suitable: The Planck function, the enthalpy and the Gibbs free energy, which are here defined and tabulated as unambigous functions of temperature for pure substances. The first edition of the tables was published in 1973 under the title "Thermochemical Properties of Inorganic Substances". The present supplementary volume contains the data and functions for a further 800 inorganic substances. In addition, the data for about 250 substances from the first volume have been up-dated. These usually small corrections produce better consistency with the data from more recent publications. The comments of users and reviewers of the first volume have largely been concerned with the difference between the present thermodynamic functions and the system used in the JANAF tables, the somewhat unconventional handling of heat balances adopted here, the notation of cell reactions, the description of non-stoichiometric phases and the accuracy of the tabulated data. To answer these questions and criticims the theore tical concepts and the practical use of the tables are dealt with in more detail in the introduction, following the recommendation of some reviewers.
The 'Red Book' is the definitive guide for scientists requiring internationally approved inorganic nomenclature in a legal or regulatory environment.
Inorganic Substances is complementary in its approach to conventional inorganic chemistry textbooks. Written with the undergraduate in mind, it gives an introduction to descriptive inorganic chemistry, a systematic survey of the chemistry of the elements according to the Periodic Classification. In this way, the reader acquires a firm grasp of the principles which underlie which inorganic substances can be made, their preparations, structures, chemical reactions and physical properties. The book presents theory as a background to the facts of inorganic chemistry, rather than as an end in itself. It does not concentrate on structural detail or reaction mechanisms but stresses the interplay between thermodynamic and kinetic considerations in understanding stability. The ways in which the various theories of structure and bonding are related are thoroughly dealt with throughout. The approach of this book makes it a useful companion to any intermediate inorganic chemistry course. It should also be useful to other science students, especially earth and material scientists who need a good grounding in modern inorganic chemistry.
Modern Inorganic Synthetic Chemistry, Second Edition captures, in five distinct sections, the latest advancements in inorganic synthetic chemistry, providing materials chemists, chemical engineers, and materials scientists with a valuable reference source to help them advance their research efforts and achieve breakthroughs. Section one includes six chapters centering on synthetic chemistry under specific conditions, such as high-temperature, low-temperature and cryogenic, hydrothermal and solvothermal, high-pressure, photochemical and fusion conditions. Section two focuses on the synthesis and related chemistry problems of highly distinct categories of inorganic compounds, including superheavy elements, coordination compounds and coordination polymers, cluster compounds, organometallic compounds, inorganic polymers, and nonstoichiometric compounds. Section three elaborates on the synthetic chemistry of five important classes of inorganic functional materials, namely, ordered porous materials, carbon materials, advanced ceramic materials, host-guest materials, and hierarchically structured materials. Section four consists of four chapters where the synthesis of functional inorganic aggregates is discussed, giving special attention to the growth of single crystals, assembly of nanomaterials, and preparation of amorphous materials and membranes. The new edition's biggest highlight is Section five where the frontier in inorganic synthetic chemistry is reviewed by focusing on biomimetic synthesis and rationally designed synthesis. - Focuses on the chemistry of inorganic synthesis, assembly, and organization of wide-ranging inorganic systems - Covers all major methodologies of inorganic synthesis - Provides state-of-the-art synthetic methods - Includes real examples in the organization of complex inorganic functional materials - Contains more than 4000 references that are all highly reflective of the latest advancement in inorganic synthetic chemistry - Presents a comprehensive coverage of the key issues involved in modern inorganic synthetic chemistry as written by experts in the field
For anyone that needs property data for compounds, CASRN numbers for computer or other searches, a consistent tabulation of molecular weights to synthesize inorganic materials on a laboratory scale, or information on commercial and other uses for various compounds, this volume is the perfect reference. This second edition is fully revised and updated. New data include optical inorganics, radiation detection inorganics, thermochromic compounds, piezochromic compounds, metal ion coordination complexes, expanded crystallographic and structural data for inorganics, catalysts, superconductors, and luminescent (fluorescent and phosphorescent) inorganics.
Environmental Inorganic Chemistry for Engineers explains the principles of inorganic contaminant behavior, also applying these principles to explore available remediation technologies, and providing the design, operation, and advantages or disadvantages of the various remediation technologies. Written for environmental engineers and researchers, this reference provides the tools and methods that are imperative to protect and improve the environment. The book's three-part treatment starts with a clear and rigorous exposition of metals, including topics such as preparations, structures and bonding, reactions and properties, and complex formation and sequestering. This coverage is followed by a self-contained section concerning complex formation, sequestering, and organometallics, including hydrides and carbonyls. Part Two, Non-Metals, provides an overview of chemical periodicity and the fundamentals of their structure and properties. - Clearly explains the principles of inorganic contaminant behavior in order to explore available remediation technologies - Provides the design, operation, and advantages or disadvantages of the various remediation technologies - Presents a clear exposition of metals, including topics such as preparations, structures, and bonding, reaction and properties, and complex formation and sequestering
Inorganic Pollutants in Water provides a clear understanding of inorganic pollutants and the challenges they cause in aquatic environments. The book explores the point of source, how they enter water, the effects they have, and their eventual detection and removal. Through a series of case studies, the authors explore the success of the detection and removal techniques they have developed. Users will find this to be a single platform of information on inorganic pollutants that is ideal for researchers, engineers and technologists working in the fields of environmental science, environmental engineering and chemical engineering/ sustainability. Through this text, the authors introduce new researchers to the problem of inorganic contaminants in water, while also presenting the current state-of-the-art in terms of research and technologies to tackle this problem. Presents existing solutions to pollution problems, along with their challenges Includes case studies that detail success stories, challenges and the implementation of these tools Provides solutions that are both economically and ecologically sustainable
A unique interdisciplinary approach to inorganic materialsdesign Textbooks intended for the training of chemists in the inorganicmaterials field often omit many relevant topics. With itsinterdisciplinary approach, this book fills that gap by presentingconcepts from chemistry, physics, materials science, metallurgy,and ceramics in a unified treatment targeted towards the chemistryaudience. Semiconductors, metal alloys and intermetallics, as wellas ceramic substances are covered. Accordingly, the book shouldalso be useful to students and working professionals in a varietyof other disciplines. This book discusses a number of topics that are pertinent to thedesign of new inorganic materials but are typically not covered instandard solid-state chemistry books. The authors start with anintroduction to structure at the mesoscopic level and progress tosmaller-length scales. Next, detailed consideration is given toboth phenomenological and atomistic-level descriptions of transportproperties, the metal-nonmetal transition, magnetic and dielectricproperties, optical properties, and mechanical properties. Finally,the authors present introductions to phase equilibria, synthesis,and nanomaterials. Other features include: * Worked examples demonstrating concepts unfamiliar to thechemist * Extensive references to related literature, leading readers tomore in-depth coverage of particular topics * Biographies introducing the reader to great contributors to thefield of inorganic materials science in the twentieth century With their interdisciplinary approach, the authors have set thegroundwork for communication and understanding among professionalsin varied disciplines who are involved with inorganic materialsengineering. Armed with this publication, students and researchersin inorganic and physical chemistry, physics, materials science,and engineering will be better equipped to face today's complexdesign challenges. This textbook is appropriate for senior-levelundergraduate and graduate course work.