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Inorganic Species, Part 2
Inorganic Species, Part 1 separately considers the various inorganic and organic components that occur in water. While this separation is traditional, it does provide some distinct organizational advantages. This is important because of the wide-ranging audience likely to be using these works. Both practicing professionals and students in environmentally related disciplines will find these volumes to be a useful reference source. This book comprises six chapters, and begins with a focus on the origin and nature of selected inorganic constituents in natural waters. Succeeding chapters go on to discuss redox potential, which discusses its measurement and importance in water systems; alkalinity and acidity; conductance, which is defined here as a collective measure of dissolved ions; the theory and measurement of turbidity and residue; and, finally, a summary of methods for water-quality analysis of specific species. This book will be of interest to practitioners in the fields of geology and environmental engineering.
The contributors to this book discuss inorganic synthesis reactions, dealing with inorganic synthesis and preparative chemistry under specific conditions. They go on to describe the synthesis, preparation and assembly of six important categories of compounds with wide coverage of distinct synthetic chemistry systems
The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.
Environmental Inorganic Chemistry for Engineers explains the principles of inorganic contaminant behavior, also applying these principles to explore available remediation technologies, and providing the design, operation, and advantages or disadvantages of the various remediation technologies. Written for environmental engineers and researchers, this reference provides the tools and methods that are imperative to protect and improve the environment. The book's three-part treatment starts with a clear and rigorous exposition of metals, including topics such as preparations, structures and bonding, reactions and properties, and complex formation and sequestering. This coverage is followed by a self-contained section concerning complex formation, sequestering, and organometallics, including hydrides and carbonyls. Part Two, Non-Metals, provides an overview of chemical periodicity and the fundamentals of their structure and properties. - Clearly explains the principles of inorganic contaminant behavior in order to explore available remediation technologies - Provides the design, operation, and advantages or disadvantages of the various remediation technologies - Presents a clear exposition of metals, including topics such as preparations, structures, and bonding, reaction and properties, and complex formation and sequestering
Reactions of Solids with Gases
Diffusion-Limited Reactions
This monograph deals with the effects of reactant spatial correlations arising in the course of basic bimolecular reactions describing defect recombination, energy transfer and exciton annihilation in condensed matter. These effects lead to the kinetics considered abnormal from the standard chemical kinetics point of view. Numerous bimolecular reaction regimes and conditions are analysed in detail. Special attention is paid to the development and numerous applications of a novel, many-point density (MPD) formalism, which is based on Kirkwood's superposition approximation used for decoupling three-particle correlation functions.The book demonstrates that incorporation of the reaction-induced spatial correlations of similar reactants (e.g., vacancy-vacancy) leads to the development of an essentially non-Poisson spectrum of reactant density fluctuations. This can completely change the kinetics at longer times since it no longer obeys the law of mass action. The language of the correlation lengths and critical exponents similar to physics of critical phenomena is used instead. A relation between MPD theory and synergistics is discussed. The validity of the theorem giving a critical complexity for the two-step reactions exhibiting self-organization phenomena is questioned. Theoretical results are illustrated by numerous experimental data.
This book aims to provide a straightforward introduction to chemical applications of the catastrophe theory. It is primarily intended for chemists interested in placing chemical reactions in the broader context of non-linear science, but it has a practical relevance for scientists in general. Catastrophe theory deals with those non-linear phenomena in which a continuous change in the control parameters results in a discontinuous alteration of a characteristic quantity of the system. The author discusses the origins of catastrophe theory, giving examples of occurrences in the areas of physics, chemistry and biology. Elementary theory and non-chemical applications are also described. The chemical kinetics and methods of analysis of chemical kinetic equations arising from elementary and generalized catastrophe theories are reviewed. Finally, the theory is applied to analyse and classify phenomena associated with the stability loss that may occur in chemical reactions. The book contains over 100 figures and an extensive subject index.
This book has been written by a group of mathematicians and chemists whose common interest is in the complex dynamics of catalytic reactions. Based on developments in mathematical chemistry, a general theory is described that allows the investigation of the relationships between the kinetic characteristics of complex reactions and their detailed reaction mechanism. Furthermore, a comprehensive analysis is made of some typical mechanism of catalytic reactions, in particular for the oxidation of carbon monoxide on platinum metals. In fact, the book presents three kinetics: (a) detailed, oriented to the elucidation of a detailed reaction mechanism according to its kinetic laws; (b) applied, with the aim of obtaining kinetic relationships for the further design of chemical reactors; and (c) mathematical kinetics whose purpose is the analysis of mathematical models for heterogeneous catalytic reactions taking place under steady- or unsteady-state conditions.