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This book puts hydrogen sulfide in context with other gaseous mediators such as nitric oxide and carbon monoxide, reviews the available mechanisms for its biosynthesis and describes its physiological and pathophysiological roles in a wide variety of disease states. Hydrogen sulfide has recently been discovered to be a naturally occurring gaseous mediator in the body. Over a relatively short period of time this evanescent gas has been revealed to play key roles in a range of physiological processes including control of blood vessel caliber and hence blood pressure and in the regulation of nerve function both in the brain and the periphery. Disorders concerning the biosynthesis or activity of hydrogen sulfide may also predispose the body to disease states such as inflammation, cardiovascular and neurological disorders. Interest in this novel gas has been high in recent years and many research groups worldwide have described its individual biological effects. Moreover, medicinal chemists are beginning to synthesize novel organic molecules that release this gas at defined rates with a view to exploiting these new compounds for therapeutic benefit.
On-board fires can occur on submarines after events such as collision or explosion. These fires expose crew members to toxic concentrations of combustion products such as ammonia, carbon monoxide, hydrogen chloride, and hydrogen sulfide. Exposure to these substances at high concentrations may cause toxic effects to the respiratory and central nervous system; leading possible to death. T protect crew members on disabled submarines, scientists at the U.S. Navy Health Research Center's Toxicology Detachment have proposed two exposure levels, called submarine escape action level (SEAL) 1 and SEAL 2, for each substance. SEAL 1 is the maximum concentration of a gas in a disabled submarine below which healthy submariners can be exposed for up to 10 days without encountering irreversible health effects while SEAL 2 the maximum concentration of a gas in below which healthy submariners can be exposed for up to 24 hours without experiencing irreversible health effects. SEAL 1 and SEAL 2 will not impair the functions of the respiratory system and central nervous system to the extent of impairing the ability of crew members in a disabled submarine to escape, be rescued, or perform specific tasks. Hoping to better protect the safety of submariners, the chief of the Bureau of Medicine and Surgery requested that the National Research Council (NRC) review the available toxicologic and epidemiologic data on eight gases that are likely to be produced in a disabled submarine and to evaluate independently the scientific validity of the Navy's proposed SEALs for those gases. The NRC assigned the task to the Committee on Toxicology's (COT's) Subcommittee on Submarine Escape Action Levels. The specific task of the subcommittee was to review the toxicologic, epidemiologic, and related data on ammonia, carbon monoxide, chlorine, hydrogen chloride, hydrogen cyanide, hydrogen sulfide, nitrogen dioxide, and sulfur dioxide in order to validate the Navy's proposed SEALs. The subcommittee also considered the implications of exposures at hyperbaric conditions and potential interactions between the eight gases. Review of Submarine Escape Action Levels for Selected Chemicals presents the subcommittee's findings after evaluation human data from experimental, occupational, and epidemiologic studies; data from accident reports; and experimental-animal data. The evaluations focused primarily on high-concentration inhalation exposure studies. The subcommittee's recommended SEALs are based solely on scientific data relevant to health effects. The report includes the recommendations for each gas as determined by the subcommittee as well as the Navy's original instructions for these substances.
The NIOSH Pocket Guide to Chemical Hazards presents information taken from the NIOSH/OSHA Occupational Health Guidelines for Chemical Hazards, from National Institute for Occupational Safety and Health (NIOSH) criteria documents and Current Intelligence Bulletins, and from recognized references in the fields of industrial hygiene, occupational medicine, toxicology, and analytical chemistry. The information is presented in tabular form to provide a quick, convenient source of information on general industrial hygiene practices. The information in the Pocket Guide includes chemical structures or formulas, identification codes, synonyms, exposure limits, chemical and physical properties, incompatibilities and reactivities, measurement methods, respirator selections, signs and symptoms of exposure, and procedures for emergency treatment.
U.S. Navy personnel who work on submarines are in an enclosed and isolated environment for days or weeks at a time when at sea. Unlike a typical work environment, they are potentially exposed to air contaminants 24 hours a day. To protect workers from potential adverse health effects due to those conditions, the U.S. Navy has established exposure guidance levels for a number of contaminants. The Navy asked a subcommittee of the National Research Council (NRC) to review, and develop when necessary, exposure guidance levels for specific contaminants. This volume, the third in a series, recommends 1-hour and 24-hour emergency exposure guidance levels (EEGLs) and 90-day continuous exposure guidance levels (CEGLs) for acetaldehyde, hydrogen chloride, hydrogen fluoride, hydrogen sulfide, and propylene glycol dinitrate.
This book explores techniques for exploring hydrogen sulfide (H2S) and its effects on the vascular system through numerous experimental animal models and vascular preparations. Alterations of vascular H2S generation/signaling may be involved in the pathogenesis of systemic and pulmonary arterial hypertension, ischemic heart disease, ischemic stroke, preeclampsia, and erectile dysfunction, and H2S also serves as an attractive target for pharmacotherapy of cardiovascular diseases, as well as possible effects on cancer, wound healing, and diabetic retinopathy, among other pathologies. Written for the highly successful Methods in Molecular Biology series, chapters include introductions to their respective topics, lists of the necessary materials and reagents, step-by-step, readily reproducible laboratory protocols, and tips on troubleshooting and avoiding known pitfalls. Authoritative and practical, Vascular Effects of Hydrogen Sulfide: Methods and Protocols is an ideal aid for scientists working to extend our knowledge in this valuable and wide-ranging field of study.
Does the identification number 60 indicate a toxic substance or a flammable solid, in the molten state at an elevated temperature? Does the identification number 1035 indicate ethane or butane? What is the difference between natural gas transmission pipelines and natural gas distribution pipelines? If you came upon an overturned truck on the highway that was leaking, would you be able to identify if it was hazardous and know what steps to take? Questions like these and more are answered in the Emergency Response Guidebook. Learn how to identify symbols for and vehicles carrying toxic, flammable, explosive, radioactive, or otherwise harmful substances and how to respond once an incident involving those substances has been identified. Always be prepared in situations that are unfamiliar and dangerous and know how to rectify them. Keeping this guide around at all times will ensure that, if you were to come upon a transportation situation involving hazardous substances or dangerous goods, you will be able to help keep others and yourself out of danger. With color-coded pages for quick and easy reference, this is the official manual used by first responders in the United States and Canada for transportation incidents involving dangerous goods or hazardous materials.
Provides comprehensive coverage of corrosion inhibitors in the oil and gas industries Considering the high importance of corrosion inhibitor development for the oil and gas sectors, this book provides a thorough overview of the most recent advancements in this field. It systematically addresses corrosion inhibitors for various applications in the oil and gas value chain, as well as the fundamentals of corrosion inhibition and interference of inhibitors with co-additives. Corrosion Inhibitors in the Oil and Gas Industries is presented in three parts. The first part on Fundamentals and Approaches focuses on principles and processes in the oil and gas industry, the types of corrosion encountered and their control methods, environmental factors affecting inhibition, material selection strategies, and economic aspects of corrosion. The second part on Choice of Inhibitors examines corrosion inhibitors for acidizing processes, inhibitors for sweet and sour corrosion, inhibitors in refinery operations, high-temperature corrosion inhibitors, inhibitors for challenging corrosive environments, inhibitors for microbiologically influenced corrosion, polymeric inhibitors, vapor phase inhibitors, and smart controlled release inhibitor systems. The last part on Interaction with Co-additives looks at industrial co-additives and their interference with corrosion inhibitors such as antiscalants, hydrate inhibitors, and sulfide scavengers. -Presents a well-structured and systematic overview of the fundamentals and factors affecting corrosion -Acts as a handy reference tool for scientists and engineers working with corrosion inhibitors for the oil and gas industries -Collectively presents all the information available on the development and application of corrosion inhibitors for the oil and gas industries -Offers a unique and specific focus on the oil and gas industries Corrosion Inhibitors in the Oil and Gas Industries is an excellent resource for scientists in industry as well as in academia working in the field of corrosion protection for the oil and gas sectors, and will appeal to materials scientists, electrochemists, chemists, and chemical engineers.
This second edition is fully updated with new material to create a comprehensive and accessible reference book: New chapters on sulfur removal via bioelectrochemical systems, use of sulfate radicals in advanced oxidation processes and sulfur nanoparticle biosynthesis. New sections on: sulfur cycle chemistry and microbiology; sulfate removal vs. recovery of resources from sulfate-rich wastewaters; microaeration for biogas desulfurisation; biological treatment of gypsum and sulfur-rich solid waste; up-to-date process control for treatment of sulfur-rich waste streams. New case studies with emphasis on practices for sewer and steel corrosion control, odour mitigation, autotrophic denitrification and bioremediation of acid mine polluted sites in both developed and developing countries have been included. Novel concepts of environmental technologies to treat sulfur pollution of wastewater, off-gases, solid waste, soils and sediments are presented. Up-to-date research findings and innovative technologies for recovering resources, i.e. metals, fertiliser, biofuels and irrigation water, from sulfur polluted waste are provided. This book may serve both as an advanced textbook for undergraduate and graduate students majoring in environmental sciences, technology or engineering as well as a handbook for tertiary educators, researchers, professionals and policymakers who conduct research and practices in the sulfur related fields. It is essential reading for consulting companies when dealing with sulfur related environmental (bio)technologies.