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Fundamentals of Petroleum Refining presents the fundamentals of thermodynamics and kinetics, and it explains the scientific background essential for understanding refinery operations. The text also provides a detailed introduction to refinery engineering topics, ranging from the basic principles and unit operations to overall refinery economics. The book covers important topics, such as clean fuels, gasification, biofuels, and environmental impact of refining, which are not commonly discussed in most refinery textbooks. Throughout the source, problem sets and examples are given to help the reader practice and apply the fundamental principles of refining. Chapters 1-10 can be used as core materials for teaching undergraduate courses. The first two chapters present an introduction to the petroleum refining industry and then focus on feedstocks and products. Thermophysical properties of crude oils and petroleum fractions, including processes of atmospheric and vacuum distillations, are discussed in Chapters 3 and 4. Conversion processes, product blending, and alkylation are covered in chapters 5-10. The remaining chapters discuss hydrogen production, clean fuel production, refining economics and safety, acid gas treatment and removal, and methods for environmental and effluent treatments. This source can serve both professionals and students (on undergraduate and graduate levels) of Chemical and Petroleum Engineering, Chemistry, and Chemical Technology. Beginners in the engineering field, specifically in the oil and gas industry, may also find this book invaluable. - Provides balanced coverage of fundamental and operational topics - Includes spreadsheets and process simulators for showing trends and simulation case studies - Relates processing to planning and management to give an integrated picture of refining
Written by an author with over 38 years of experience in the chemical and petrochemical process industry, this handbook will present an analysis of the process steps used to produce industrial hydrocarbons from various raw materials. It is the first book to offer a thorough analysis of external factors effecting production such as: cost, availability and environmental legislation. An A-Z list of raw materials and their properties are presented along with a commentary regarding their cost and availability. Specific processing operations described in the book include: distillation, thermal cracking and coking, catalytic methods, hydroprocesses, thermal and catalytic reforming, isomerization, alkylation processes, polymerization processes, solvent processes, water removal, fractionation and acid gas removal. - Flow diagrams and descriptions of more than 250 leading-edge process technologies - An analysis of chemical reactions and process steps that are required to produce chemicals from various raw materials - Properties, availability and environmental impact of various raw materials used in hydrocarbon processing
This text examines the thermal and catalytic processes involved in the refining of petroleum including visbreaking, coking, pyrolysis, catalytic cracking, oligomerization, alkylation, hydrofining, hydroisomerization, hydrocracking, and catalytic reforming. It analyzes the thermodynamics, reaction mechanisms, and kinetics of each process, as well as
This book covers petroleum refining and gas purification processes, including refinery configurations comprising of relevant units with special emphasis on processing of heavy crudes with high acid number. It includes a short review of distillation principles, distillation column auxiliaries, critical column pressure control strategies, critical issues of crude and vacuum distillation units particularly for heavy crude processing. Different corrosion mechanisms and their prevention with regards to heavy high TAN crude processing are also included. Fundamentals are explained with support of steady-state simulation and presented with simulation flowsheets and outputs, supported by examples of calculations and troubleshooting case studies. Features: • Deals with principles and practices in the hydrocarbon industry and petroleum refinery with emphasis on heavy crude processing • Focuses on operation and practices of the major process units with simulation examples and aimed at the professional engineer • Covers acid gas treatment in view of increased emphasis on carbon capture and storage, and introduction of residue gasification processes • Elucidates methodologies for safety relief load computation for distillation columns • Explains real-life problems in reboilers, column internals, column pressure controls and corrosion in crude, and vacuum distillation and secondary units with several case studies This book is aimed at professionals in petroleum engineering and graduate students in chemical engineering.
This book is a must-read for the latest generation of scientists, engineers, and researchers in the petroleum industry. The product of over four decades of research, experience, and study by Dr. Dwijen Banerjee, who carefully preserves the history of the thermal processing of hydrocarbons, giving credit to the pioneering scientists and discoverers of the process. In this first-of-its-kind book, the author summarizes and systematically leads readers through all aspects of the thermal cracking processes from the research laboratory to the commercial applications of the petrochemical industry. Fossil fuels consist of a continuous series of hydrocarbons mainly divided into natural gas (C1-C4), conventional crude oil (C5-C40), heavy oil/bitumen (>C40). This book discusses thermal processing of hydrocarbons -- with a special emphasis on lighter hydrocarbons -- whose main source is shale gas and tight oil that's recently been made abundant through fracking technology. This book details many technical parameters involved in choosing a process when considering the type of feedstocks; operating conditions; selectivity of the desired product; the market to be targeted; and the environmental regulations to be met while also considering the economic parameters such as the investment and profit margin that govern the final choice. Features and Benefits An introduction to the basic chemistry behind thermal processing, classifications, molecular structures, kinetics and thermodynamics, free radical reaction mechanisms, and product distributions. A focus on shale gas and tight oil production, properties, and processing as important sources of petrochemicals. Emphasis on the 'petroleum to petrochemicals' which has recently transformed the petroleum industry across the globe. An illustration of conversion technologies -- how the paraffinic hydrocarbons are converted into various petrochemicals and eventually lead to the finished products. Insight into the future of hydrocarbons based on environmental issues. Audience Scientists Engineers Researchers Students
Describes economic evaluations for both single processes and complete refineries, and illustrates how to use yield data, properties of products, and operating and capital costs in those evaluations. Two chapters on transportation fuels and environmental concerns have been added to the second edition. Annotation copyrighted by Book News, Inc., Portland, OR.
Besides covering topics like catalytic cracking, hydrocracking, and alkylation, this volume has chapters on waste water treatment and the economics of managing or commissioning the design of a petroleum refinery. Found only in this volume is material on operating a jointly owned and operated refinery. (Over the last decade, the ownership of many refineries has shifted to small companies, from the large, integrated companies. Because of this shift, many refineries are now jointly owned and operated.) Filled with handy process flow diagrams, this volume is the only reference that a chemical engineer or process manager in a petroleum refinery needs for answers to everyday process and operations questions.* Covers the technologies and operations of petroleum refineries* Provides material on operating a jointly owned and operated refinery* Gives readers a comprehensive introduction to petroleum refining, as well as a full reference to engineers in the field
A comprehensive review of the theory and practice of the simulation and optimization of the petroleum refining processes Petroleum Refinery Process Modeling offers a thorough review of how to quantitatively model key refinery reaction and fractionation processes. The text introduces the basics of dealing with the thermodynamics and physical property predictions of hydrocarbon components in the context of process modeling. The authors - three experts on the topic - outline the procedures and include the key data required for building reaction and fractionation models with commercial software. The text shows how to filter through the extensive data available at the refinery and using plant data to begin calibrating available models and extend the models to include key fractionation sub-models. It provides a sound and informed basis to understand and exploit plant phenomena to improve yield, consistency, and performance. In addition, the authors offer information on applying models in an overall refinery context through refinery planning based on linear programming. This important resource: -Offers the basic information of thermodynamics and physical property predictions of hydrocarbon components in the context of process modeling -Uses the key concepts of fractionation lumps and physical properties to develop detailed models and workflows for atmospheric (CDU) and vacuum (VDU) distillation units -Discusses modeling FCC, catalytic reforming and hydroprocessing units Written for chemical engineers, process engineers, and engineers for measurement and control, this resource explores the advanced simulation tools and techniques that are available to support experienced and aid new operators and engineers.
As feedstocks to refineries change, there must be an accompanying change in refinery technology. This means a movement from conventional means of refining heavy feedstocks using (typically) coking technologies to more innovative processes that will coax the last drips of liquid fuels from the feedstock. This book presents the evolution of refinery processes during the last century and as well as the means by which refinery processes will evolve during the next three-to-five decades. Chapters contain material relevant to (1) comparisons of current feedstocks with heavy oil and bio-feedstocks; (2) evolution of refineries since the 1950s, (3) properties and refinability of heavy oil and bio-feedstocks, (4) thermal processes vs. hydroprocesses, and (5) evolution of products to match the environmental market. Process innovations that have influenced refinery processing over the past three decades are presented, as well as the relevant patents that have the potential for incorporation into future refineries.• Comparison of current feedstocks with heavy oil and bio-feedstocks. • Evolution of refineries over the past three decades. • Properties and refinability of heavy oil and bio-feedstocks. • Thermal processes vs. Hydroprocesses. • Evolution of products to match the environmental market. - Investigates the engineering and plant design challenges presented by heavy oil and bio-feedstocks - Explores the legislatory and regulatory climate, including increasingly stringent environmental requirements - Examines the trade-offs of thermal processes vs. hydroprocesses