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This review volume contains articles on the recent developments, new ideas, as well as controversial issues dealing with the general phenomena of hopping transport in disordered systems. Examples of hopping systems of current interest are polymers and biological materials, mesoscopic systems, two- and one-dimensional systems such as MOSFETs, semiconductors near the metal-nonmetal transition, and the new high temperature superconducting materials (in their normal state). The fundamental problems addressed include effects of static and dynamic interactions with phonons, Coulomb interaction, new magnetic effects due to coherent scattering, effects of high electric fields, and relaxation phenomena.
The phenomenon of hopping, in which a particle executes a series of jumps between discrete states, has a fundamental role in a wide range of solid state transport phenomena. In these proceedings acknowledged experts in the field describe important recent progress in developing the phenomenology of hopping processes and applying it to different systems, including crystalline and amorphous semiconductors, glasses, polymers, mesoscopic conductors and high temperature superconductors.
The problem of superconductors has been a central issue in Solid State Physics since 1987. After the discovery of superconductivity (HTSC) in doped perovskites, it was realized that the HTSC appears in an unknown complex electronic phase of c- densed matter. In the early years, all theories of HTSC were focused on the physics of a homogeneous 2D metal with large electron–electron correlations or on a 2D polaron gas. Only after 1990, a novel paradigm started to grow where this 2D metallic phase is described as an inhomogeneous metal. This was the outcome of several experimental evidences of phase separation at low doping. Since 1992, a series of conferences on phase separation were organized to allow scientists to get together to discuss the phase separation and related issues. Following the discovery by the Rome group in 1992 that “the charges move freely mainly in one direction like the water running in the grooves in the corrugated iron foil,” a new scenario to understand superconductivity in the superconductors was open. Because the charges move like rivers, the physics of these materials shifts toward the physics of novel mesoscopic heterostructures and complex electronic solids. Therefore, understanding the striped phases in the perovskites not only provides an opportunity to understand the anomalous metallic state of cuprate superconductors, but also suggests a way to design new materials of technological importance. Indeed, the stripes are becoming a field of general scientific interest.
The book provides an overview of the author's work devoted to experimental study of hopping conductivity, which includes substantial contributions, such as solving the problem of critical indices of the metal-insulator transition in doped semiconductors, investigation of transitions from different kinds of hopping conductivity, development of the 'hopping spectroscopy' method that allows to reveal the details of the density-of-states near the Fermi level — appearance of a hard 'magnetic gap', temperature induced smearing of the soft Coulomb gap, the 'phononless' hopping and so on. A separate chapter is devoted to the hopping photoconductivity and inter-impurity radiative recombination of non-equilibrium carriers. This book is suitable for undergraduate and graduate students in physics, researchers in semiconductor electronics and even for the non-experts who wish to have a notion about hopping mechanism of transport. The explanations in the book are simple and detailed enough to capture the interest of the curious reader.
Presents fundamental, as well as state-of-the-art, information on the physics, chemistry, materials, fabrication, preparation, application and performance of organic photoreceptors in xerography. The book offers on-the-job situations to problems related to xerographic photoreceptors and related technologies, including electroluminescent, photorefractive, photovoltaic and transistor devices.
Optoelectronic devices are currently being developed at an extraordinary rate. Organic light-emitting diodes, photovoltaic devices and electro-optical modulators are pivotal to the future of displays, photosensors and solar cells, and communication technologies. This book details the theories underlying the mechanisms involved in the relevant organic materials and covers, at a basic level, how the organic components are made. The first part of the book introduces the fundamental theories used to describe ordered solids and goes onto detail on concepts applicable to localised energy levels. Then the methods used to determine energy levels particular to perfectly ordered molecular and macromolecular systems are discussed along with a detailed consideration of the effects of quasi-particles. The function of excitons and their transfer between two molecules is studied and, in addition, the problems associated with interfaces and charge injection into resistive media are presented. More technological aspects are covered in the second part, which details the actual methods used to fabricate devices based on organic materials, such as dry etching. The principal characterisation techniques are also highlighted. Specific attention is paid to visual displays using organic light-emitting diodes; the conversion of photons into electrical energy (the photovoltaic effect); and for communications and information technologies, the electro-optical modulation of signals.
In this book, the authors give an up-to-date account of thermoluminescence (TL) and other thermally stimulated phenomena. Although most recent experimental results of TL in different materials are described in some detail, the main emphasis in the present book is on general processes, and the approach is more theoretical. Thus the details of the possible processes which can take place during the excitation of the sample, and during its heating, are carefully analysed. The methods for analysing TL glow curves are critically discussed, and recommendations as to their application are made. Also discussed is the expected behavior of these phenomena as functions of the experimental parameters, for example, dose of excitation. The consequences of the main applications of TL (for example, radiation dosimetry) are also discussed in detail as are the similarities and dissimilarities of other thermally stimulated phenomena, and the simultaneous measurements of the latter and TL.
Contacts and photoinjection currents. Experimental techniques. Theory of time-dependent photoconductivity in disordered systems. Covalent semiconductors. Molecular crystals. Amorphous tetrahedrally bonded solids. Amorphous chalcogenides. Polymeric photoconductors. Non-polar liquids. Photoelectronic semiconductor devices. Electrophotography.