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High temperature gas-solid reactions are ubiquitous on planetary bodies, distributing chemical elements over a range of geologic settings and temperatures. This volume reviews the critical role gas-solid reactions play in early solar system formation, volcanism, metamorphism and industrial processes. The field evidence, experimental and theoretical approaches for examining gas-solid reaction are presented, building on advances in fields outside of Earth Sciences. Computational chemistry techniques are used to probe the nature of molecular clusters and solvation in volcanic vapors and mineral-gas reaction mechanisms. Specialised analytical methods for characterising solid reaction products are included since these reactions commonly form thin or dispersed films and metastable minerals. Finally, the volume contains rich field examples, laboratory experiments and thermodynamic modelling and kinetics of gas-solid reactions on Earth, Venus and beyond.
Advances in Chemical Engineering, Volume 58 in this long-running serial, highlights new advances in the field with this new volume presenting interesting and timely chapters written by an international board of authors. - Provides the authority and expertise of leading contributors from an international board of authors - Presents the latest release in the Advances in Chemical Engineering series
Open system behavior is predicated on a fundamental relationship between the timescale over which mass is transported and the timescale over which it is chemically transformed. This relationship describes the basis for the multidisciplinary field of reactive transport (RT). In the 20 years since publication of Review in Mineralogy and Geochemistry volume 34: Reactive Transport in Porous Media, RT principles have expanded beyond early applications largely based in contaminant hydrology to become broadly utilized throughout the Earth Sciences. RT is now employed to address a wide variety of natural and engineered systems across diverse spatial and temporal scales, in tandem with advances in computational capability, quantitative imaging and reactive interface characterization techniques. The present volume reviews the diversity of reactive transport applications developed over the past 20 years, ranging from the understanding of basic processes at the nano- to micrometer scale to the prediction of Earth global cycling processes at the watershed scale. Key areas of RT development are highlighted to continue advancing our capabilities to predict mass and energy transfer in natural and engineered systems.
Volume 86 of Reviews in Mineralogy and Geochemistry concentrates on understanding the variations among ratios of the three isotopes of oxygen, with primary emphasis on terrestrial systems. Triple oxygen isotope variations may be related to large, mass-independent fractionation effects such observed in the Earth atmosphere or may be small and related to minute variations due to purely mass-dependent processes. Recent advancements in analytical resolution now allow for the identification of processes and distinct reservoirs that were formerly hidden in the paradigm of a "single terrestrial fractionation line". New, high-resolution measurements are accompanied by advances in theoretical calculations that dovetail with empirical calibrations and applications throughout this volume. 14 chapters span a wide range of subjects: from ab-initio theoretical approaches to observation of triple oxygen isotope variations in the Earth litho-, hydro- and atmosphere.
This Special Issue delivered 16 scientific papers, with the aim of exploring the application of carbon capture and storage technologies for mitigating the effects of climate change. Special emphasis has been placed on mineral carbonation techniques that combine innovative applications to emerging problems and needs. The aim of this Special Issue is to contribute to improved knowledge of the ongoing research regarding climate change and CCS technological applications, focusing on carbon capture and storage practices. Climate change is a global issue that is interrelated with the energy and petroleum industry.
This volume is concerned primarily with the chemical and physical effects of shock waves on typical materials. It compares naturally occurring materials with similar materials produced by shock compression in the laboratory, providing clues about the environment and events that produced the natural materials.
This 1996 text reviews current ideas about the formation of chondrules in meteorites.
The sources, distributions, and transformation of organic compounds in the solar system are active study areas as a means to provide information about the evolution of the solar system and the possibilities of life elsewhere in the universe. There are many organic synthesis processes, however, and ambiguity surrounds the relative effectiveness of these processes in explaining the distribution of organic compounds in the solar system. As a consequence, NASA directed the NRC to determine what processes account for the reduced carbon compounds found throughout the solar system and to examine how planetary exploration can advance understanding of this central issue. This report presents a discussion of the chemistry of carbon; an analysis of the formation, modification, and preservation of organic compounds in the solar system; and an assessment of research opportunities and strategies for enhancing our understanding of organic material in the solar system.