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In many instances of mechanical interaction between two materials, the physical contact affects only the outermost surface layer, with little discernible influence on the bulk of the material. The resultant high pressures in these localised regimes can induce surface structural changes such as deformation, phase transformation and amorphization.
Surface science has evolved from being a sub-field of chemistry or physics, and has now established itself as an interdisciplinary topic. Knowledge has developed sufficiently that we can now understand catalysis from a surface science perspective. No-where is the underpinning nature of surface science better illustrated than with nanoscience. Now in its third edition, this successful textbook aims to provide students with an understanding of chemical transformations and the formation of structures at surfaces. The chapters build from simple to more advanced principles with each featuring exercises, which act not only to demonstrate concepts arising in the text but also to form an integral part of the book, with the last eight chapters featuring worked solutions. This completely revised and expanded edition features: More than 100 new pages of extensive worked solutions New topics, including: Second harmonic generation (SHG), Sum Frequency Generation (SFG) at interfaces and capillary waves An expanded treatment of charge transfer and carbon-based materials including graphene Extended ‘Frontiers and Challenges’ sections at the end of each chapter. This text is suitable for all students taking courses in surface science in Departments of Chemistry, Physics, Chemical Engineering and Materials Science, as well as for researchers and professionals requiring an up-to-date review of the subject.
This volume contains peer-reviewed manuscripts describing the scientific and technological advances presented at the 6th Natural Gas Conversion Sumposium held in Alaska in June 2001. This symposium continues the tradition of excellence and the status as the premier technical meeting in this area established by previous meetings.The 6th Natural Gas Conversion Symposium is conducted under the overall direction of the Organizing Committee. The Program Committee was responsible for the review, selection, editing of most of the manuscripts included in this volum. A standing International Advisory Board has ensured the effective long-term planning and the continuity and technical excellence of these meetings.
Surface science has a wide range of applications that include semiconductor processing, catalysis, vacuum technology, microelectronics, flat-panel displays, compact disks, televisions, computers, environmental monitoring of pollutants, biomaterials, artificial joints, soft tissues, food safety, pharmacy, and many more. This volume is intended for upper-level undergraduate and graduate students in universities, individual research groups and researchers working on surfaces of materials. It is of interest to chemists, solid-state physists, materials scientists, surface chemists, polymer scientists, electrical engineers, chemical engineers, and everyone involved in materials science.
This new book covers the physics and chemistry of surfaces. The scope includes the structure, thermodynamics, and mobility of clean surfaces, as well as the interaction of gas molecules with solid surfaces. The energetic particle interactions that are the basis for the majority of techniques developed to reveal the structure and chemistry of surfaces are explored including auger electron spectroscopy, photoelectron spectroscopy, inelastic scattering of electrons and ions, low energy electron diffraction, scanning probe microscopy, and interfacial segregation. Crystal nucleation and growth are also considered. Principles such as adsorption, desorption and reactions between adsorbates are examined, with coverage also of new developments in the growth of epitaxial, and Langmuir-Blodgett films, as well as treatment of the etching of surfaces. Modern analytical techniques and applications to thin films and nanostructures are included. The latest in-depth research from around the world is presented.
This unique book covers the latest surface science studies on model catalysts, including single crystals, non-colloidal nanocatalysts, and nanoparticles in various forms with the control of size, shape and composition. This book addresses the issue of bridging “materials and pressure gaps” and also discusses the important issue of metal-oxide interface and hot electron flows in heterogeneous catalysis. The current development of in-situ surface techniques that is relevant to bridging “pressure gaps” is also highlighted.
The Chemical Physics of Solid Surfaces, Volume 6: Coadsorption, Promoters, and Poisons focuses on the processes, reactions, and approaches involved in coadsorption and the functions of promoters and poisons in synthesis and reactions. The selection first offers information on adsorbate-adsorbate interactions on metal surfaces and interaction between alkali metal adsorbates and adsorbed molecules. Discussions focus on coadsorption of alkali metals and other molecules; model experiments of catalyst promotion; effective medium theory; direct and indirect hybridization effects; and elastic interaction between adsorbates. The publication then ponders on coadsorption of carbon monoxide and hydrogen on metal surfaces and adsorption on bimetallic surfaces. The manuscript examines the chemical properties of alloy single crystal surfaces and promotion in ammonia synthesis. Topics include substrate dependence of nitrogen adsorption and ammonia synthesis; effects of promotion on nitrogen dissociation and ammonia synthesis; and theoretical modeling. The text then elaborates on promotion in the Fischer-Tropsch hydrocarbon synthesis, promoters and poisons in the water-gas shift reaction, and strong metal-support interactions. The selection is a recommended reference for physicists and readers interested in coadsorption, promoters, and poisons.
In this book "surface science" is understood in a broad sense, taken to include two-dimensional structures such as thin films and superlattices. Thecontributions reflect current research activities in surface and thin-film science in Latin-America, presenting a clear picture of the research centers, equipment and expertise available in the region in this rapidly developing field of physics. The topics treated cover the whole spectrum of the subject, with the latest theoretical results beingreported alongside details of industrial applications such as materials characterization and photovoltaic cells. Surface scientists, engineers and research admistrators will find this volume of interest.
The purpose of this Conference was to discuss the results of recent developments and the future prospect in science and technology of the field. The field has been growing and flourishing, while indicating many problems to be uncovered and solved. The conference was structured to encourage interaction and to stimulate the exchange of ideas to accomplish the above purpose.Key issues and materials related to the Conference were included as follows: • Molecular Assemblies in Solutions; • Fine Particles and Colloidal Dispersions; • Supramolecular Organized Films; • Nanostructural Solid Surfaces; • Industrial Applications and Products.The Conference comprised 2 plenary lectures, 42 invited lectures, 150 oral presentations and 266 poster presentations.