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Authored by an insider with over 40 years of high energy materials (HEMs) experience in academia, industry and defense organizations, this handbook and ready reference covers all important HEMs from the 1950s to the present with their respective properties and intended purposes. Written at an attainable level for professionals, engineers and technicians alike, the book provides a comprehensive view of the current status and suggests further directions for research and development. An introductory chapter on the chemical and thermodynamic basics allows the reader to become acquainted with the fundamental features of explosives, before moving on to the important safety aspects in processing, handling, transportation and storage of high energy materials. With its collation of results and formulation strategies hitherto scattered in the literature, this should be on the shelf of every HEM researcher and developer.
Demystifying Explosives: Concepts in High Energy Materials explains the basic concepts of and the science behind the entire spectrum of high energy materials (HEMs) and gives a broad perspective about all types of HEMs and their interrelationships. Demystifying Explosives covers topics ranging from explosives, deflagration, detonation, and pyrotechnics to safety and security aspects of HEMS, looking at their aspects, particularly their inter-relatedness with respect to properties and performance. The book explains concepts related to the molecular structure of HEMs, their properties, performance parameters, detonation and shock waves including explosives and propellants. The theory-based title also deals with important (safety and security) and interesting (constructive applications) aspects connected with HEMs and is of fundamental use to students in their introduction to these materials and applications. - Explains the concept of high energy materials in simple language and down-to-earth examples - Worked examples and problems are given wherever required - Demystifies the concept of explosives - Limited use of big and complex equations - Questions and Suggested Reading are given at the end of each chapter
This book comprehensively and systematically demonstrates the theory and practice of designing, synthesizing and improving the performance of fuels. The contents range from polycyoalkane fuels, strained fuels, alky-diamondoid fuels, hypergolic and nanofluid fuels derived from fossil and biomass. All the chapters together clearly describe the important aspects of high-energy-density fuels including molecular design, synthesis route, physiochemical properties, and their application in improving the aerocraft performance. Vivid schematics and illustrations throughout the book enhance the accessibility to the relevant theory and technologies. This book provides the readers with fundamentals on high-energy-density fuels and their potential in advanced aerospace propulsion, and also provides the readers with inspiration for new development of advanced aerospace fuels.
Nanomaterials in Rocket Propulsion Systems covers the fundamentals of nanomaterials and examines a wide range of innovative applications, presenting the current state-of-the-art in the field. Opening with a chapter on nano-sized energetic materials, the book examines metal nanoparticles-based fuels, ballistic modifiers, stabilizers and catalysts as the components of rocket propellants. Hydrogen storage materials for rocket propulsion based on nanotubes are then discussed, as are nano-porous materials and metal organic frameworks, nano-gelled propellants, nano-composite ablators and ceramic nano-composites. Other applications examined include high thermal conductivity metallic nano-composite nozzle liners, nano-emitters for Coulomb propulsion of space-crafts, and highly thermostable nano-ceramics for rocket motors. The book finishes with coverage of combustion of nano-sized rocket fuels, nano-particles and their combustion in micro- and nano-electromechanical systems (MEMS/NEMS), plasma propulsion and nano-scale physics. Users will find this to be a valuable resource for academic and government institutions, professionals, new researchers and graduate students working in the application of nanomaterials in the aerospace industry.
Incorporation of particular components with specialized properties allows one to tailor the end product's properties. For instance, the sensitivity, burning behavior, thermal or mechanical properties or stability of energetic materials can be affected and even controllably varied through incorporation of such ingredients. This book examines particle technologies as applied to energetic materials such as propellants and explosives, thus filling a void in the literature on this subject. Following an introduction covering general features of energetic materials, the first section of this book describes methods of manufacturing particulate energetic materials, including size reduction, crystallization, atomization, particle formation using supercritical fluids and microencapsulation, agglomeration phenomena, special considerations in mixing explosive particles and the production of nanoparticles. The second section discusses the characterization of particulate materials. Techniques and methods such as particle size analysis, morphology elucidation and the determination of chemical and thermal properties are presented. The wettability of powders and rheological behavior of suspensions and solids are also considered. Furthermore, methods of determining the performance of particular energetic materials are described. Each chapter deals with fundamentals and application possibilities of the various methods presented, with particular emphasis on issues applicable to particulate energetic materials. The book is thus equally relevant for chemists, physicists, material scientists, chemical and mechanical engineers and anyone interested or engaged in particle processing and characterization technologies.
This dictionary contains 739 entries with about 1400 references to the primary literature. Details on the composition, performance, sensitivity and other pertinent properties of Energetic Materials such as High Explosives, Propellants, Pyrotechnics, as well as important ingredients such as Oxidizers, Fuels, Binders, and Modifiers are given and presented partly in over 180 tables with more than 240 structural formulas . In detail the dictionary gives elaborate descriptions of 460 Chemical Substances 170 Pyrotechnic Compositions 360 High Explosive and Propellant Formulations In addition, the basic physical and thermochemical properties of 435 pure substances (elements & compounds) typically occuring as ingredients or reaction products are given too. 150 Figures, schemes and diagrams explain Applications, Test methods, Scientific facilities, and finally Individuals closely tied with the development and investigation of Energetic Materials. The book is intended for readers with a technical or scientific background, active in governmental agencies, research institutes, trade and industry, concerned with the procurement, development, manufacture, investigation and use of Energetic Materials, such as High Explosives, Propellants, Pyrotechnics, Fireworks and Ammunition. The book serves both as a daily reference for the experienced as well as an introduction for the newcomer to the field.
The 4th revised edition expands on the basic chemistry of high energy materials of the precious editions and examines new research developments, including hydrodynamics and ionic liquids. Applications in military and civil fields are discussed. This work is of interest to advanced students in chemistry, materials science and engineering, as well as to all those working in defense technology.
This up-to-date overview provides the latest information on the performance, sensitivity, strength and processability aspects of propellants and explosive formulations, with the nature of polymer binder/plasticizer as the variable factor. Apart from applications, this monograph explores the principles behind energetic polymers, while discussing the synthetic routes and energetic characteristics of individual family of energetic polymers. Furthermore, a number of case studies illustrate the role of energetic polyerms on enhancing the performance of formulations as compared to their inert counterparts. The emphasis is on safety throughout, with practical guidance on how to safely handle and formulate energetic polymer based formulations. With the advent of a new generation of energetic polymers, this book is relevant to industry and defense organizations as well as for academic research.
Advanced energetic materialsâ€"explosive fill and propellantsâ€"are a critical technology for national security. While several new promising concepts and formulations have emerged in recent years, the Department of Defense is concerned about the nation's ability to maintain and improve the knowledge base in this area. To assist in addressing these concerns, two offices within DOD asked the NRC to investigate and assess the scope and health of the U.S. R&D efforts in energetic materials. This report provides that assessment. It presents several findings about the current R&D effort and recommendations aimed at improving U.S. capabilities in developing new energetic materials technology. This study reviewed U.S. research and development in advanced energetics being conducted by DoD, the DoE national laboratories, industries, and academia, from a list provided by the sponsors. It also: (a) reviewed papers and technology assessments of non-U.S. work in advanced energetics, assessed important parameters, such as validity, viability, and the likelihood that each of these materials can be produced in quantity; (b) identified barriers to scale-up and production, and suggested technical approaches for addressing potential problems; and (c) suggested specific opportunities, strategies, and priorities for government sponsorship of technologies and manufacturing process development.