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This thesis presents several new insights on the interface between mathematics and theoretical physics, with a central role for Riemann surfaces. First of all, the duality between Vafa-Witten theory and WZW models is embedded in string theory. Secondly, this model is generalized to a web of dualities connecting topological string theory and N=2 supersymmetric gauge theories to a configuration of D-branes that intersect over a Riemann surface. This description yields a new perspective on topological string theory in terms of a KP integrable system based on a quantum curve. Thirdly, this thesis describes a geometric analysis of wall-crossing in N=4 string theory. And lastly, it offers a novel approach to constuct metastable vacua in type IIB string theory.
This book provides an introduction to some of the most recent developments in string theory, and in particular to their mathematical implications and their impact in knot theory and algebraic geometry.