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Fluid-Solid Reactions, Second Edition takes a detailed and thorough look at the scope of fluid-solid reaction systems, focusing on the four phenomena: external mass transfer, pore diffusion, chemical reaction, and adsorption/desorption. This completely revised new edition builds on the classic original edition through the introduction of cutting-edge new theories and applications, including the formulation and application of a new and convenient law that governs fluid-solid reaction kinetics. This book will be of primary interest to practicing engineers engaged in process research, development, and design in the many fields where fluid-solid reactions are critical to workflow and research. Fluid-solid reactions play a major role in the technology of most industrialized nations. These reactions encompass a very broad field, including the extraction of metals from their ores, the combustion of solid fuels, coal gasification, and the incineration of solid refuse. Features 50% new and revised content, arming researchers with the latest developments in the field Details a new unified approach to modeling the rates of fluid-solid reaction systems Authored by one of the world’s foremost experts on fluid-solid reactions and their applications in the field
Designed to give chemical engineers background for managing chemical reactions, this text examines the behavior of chemical reactions and reactors; conservation equations for reactors; heterogeneous reactions; fluid-fluid and fluid-solid reaction systems; heterogeneous catalysis and catalytic kinetics; diffusion and heterogeneous catalysis; and analyses and design of heterogeneous reactors. 1976 edition.
Reaction Engineering clearly and concisely covers the concepts and models of reaction engineering and then applies them to real-world reactor design. The book emphasizes that the foundation of reaction engineering requires the use of kinetics and transport knowledge to explain and analyze reactor behaviors. The authors use readily understandable language to cover the subject, leaving readers with a comprehensive guide on how to understand, analyze, and make decisions related to improving chemical reactions and chemical reactor design. Worked examples, and over 20 exercises at the end of each chapter, provide opportunities for readers to practice solving problems related to the content covered in the book. Seamlessly integrates chemical kinetics, reaction engineering, and reactor analysis to provide the foundation for optimizing reactions and reactor design Compares and contrasts three types of ideal reactors, then applies reaction engineering principles to real reactor design Covers advanced topics, like microreactors, reactive distillation, membrane reactors, and fuel cells, providing the reader with a broader appreciation of the applications of reaction engineering principles and methods
Gas-Solid Reactions describes gas-solid reaction systems, focusing on the four phenomena—external mass transfer, pore diffusion, adsorption/desorption, and chemical reaction. This book consists of eight chapters. After the introduction provided in Chapter 1, the basic components of gas-solid reactions are reviewed in Chapter 2. Chapter 3 describes the reactions of individual nonporous solid particles, while Chapter 4 elaborates the reaction of single porous particles. Solid-solid reactions proceeding through gaseous intermediates are considered in Chapter 5. Chapter 6 deals with the experimental approaches to the study of gas-solid reaction systems. How information on single-particle behavior may be used for the design of multiparticle, large-scale assemblies, and packed- and fluidized-bed reaction systems is deliberated in Chapter 7. The last chapter covers the specific gas-solid reaction systems, including some statistical indices indicating the economic importance of the systems and processes it's based on. This publication is recommended for practicing engineers engaged in process research, development, and design in the many fields where gas-solid reactions are important.
Chemical reaction engineering is at the core of chemical engineering education. Unfortunately, the subject can be intimidating to students, because it requires a heavy dose of mathematics. These mathematics, unless suitably explained in the context of the physical phenomenon, can confuse rather than enlighten students. Bearing this in mind, Reaction Engineering Principles is written primarily from a student’s perspective. It is the culmination of the author’s more than twenty years of experience teaching chemical reaction engineering. The textbook begins by covering the basic building blocks of the subject—stoichiometry, kinetics, and thermodynamics—ensuring students gain a good grasp of the essential concepts before venturing into the world of reactors. The design and performance evaluation of reactors are conveniently grouped into chapters based on an increasing degree of difficulty. Accordingly, isothermal reactors—batch and ideal flow types—are addressed first, followed by non-isothermal reactor operation, non-ideal flow in reactors, and some special reactor types. For better comprehension, detailed derivations are provided for all important mathematical equations. Narrative of the physical context in which the formulae work adds to the clarity of thought. The use of mathematical formulae is elaborated upon in the form of problem solving steps followed by worked examples. Effects of parameters, changing trends, and comparisons between different situations are presented graphically. Self-practice exercises are included at the end of each chapter.
The phenomenon of "mass transfer with chemical reaction" takes place whenever one phase is brought into contact with one or more other phases not in chemical equilibrium with it. This phenomenon has industrial, biological and physiological importance. In chemical process engineering, it is encountered in both separ ation processes and reaction engineering. In some cases, a chemical reaction may deliberately be employed for speeding up the rate of mass transfer and/or for increasing the capacity of the solvent; in other cases the multiphase reaction system is a part of the process with the specific aim of product formation. Finally, in some cases, for instance "distillation with chemical reaction", both objectives are involved. Although the subject is clearly a chemical engineering undertakin~, it requires often a good understanding of other subjects, such as chemistry and fluid mechanics etc., leading to publications in diversified areas. On the other har.d, the subject has always been a major field and one of the most fruitful for chemical engineers.
Fundamentals of Chemistry theme in two volumes, is a component of Encyclopedia of Chemical Sciences, Engineering and Technology Resources in the global Encyclopedia of Life Support Systems (EOLSS), which is an integrated compendium of twenty one Encyclopedias. The Theme is organized into six different topics which represent the main scientific areas : History and Fundamentals of Chemistry; Chemical Experimentation and Instrumentation; Theoretical Approach to Chemistry; Chemical Thermodynamics; Rates of Chemical Reactions; Chemical Synthesis of Substances. These two volumes are aimed at the following five major target audiences: University and College students Educators, Professional practitioners, Research personnel and Policy analysts, managers, and decision makers and NGOs
The encyclopedia consists 13 subareas as follows: 1: Synthesis and Characterisation of Ionic Liquids (Section Editors: Prof. Fu-Wei Li and Prof. Zhen Li) 2: Physicochemical Properties of Ionic Liquids (Section Editors: Asso. Prof. Qing Zhou, Prof. Xingmei Lu and Prof. Xiaoyan Ji) 3: Computational and Theoretical Modeling of Ionic Liquids (Section Editors: Prof. Guang Feng and Prof. Peter T. Cummings) 4: Toxicology and Biodegradation of Ionic Liquids (Section Editors: Prof. Chunxi Li and Prof. Stefan Stolte) 5: Ionic Liquids in Electrochemistry (Section Editors: Prof. Yingying Lu, Prof. Houlong Zhuang and Prof. Chuan Zhao) 6. Ionic Liquids in Organic Reaction (Section Editors: Prof. Liang-Nian He and Prof. Bhalchandra M. Bhanage) 7. Ionic Liquids in Separation (Section Editors: Prof. Huabin Xing) 8. Ionic Liquids in Biomass and Biomolecules (Section Editors: Prof. Toshiyuki Itoh and Prof. Jian Sun) 9. Ionic Liquids in Materials Science (Section Editors: Prof. Sheng Dai and Prof. Tao Wang) 10. Ionic Liquids in Polymer Science (Section Editors: Asso. Prof. Jinming Zhang and Prof. Jun Zhang) 11. Ionic Liquids in Environmental Science (Section Editors: Prof. Tiancheng Mu, Prof. Arunprakash T. Karunanithi and Prof. Yingxiong Wang) 12. Ionic Liquids in Green Chemistry (Section Editors: Prof. Buxing Han and Prof. Peter Licence) 13. Emerging Applications of Ionic Liquids (Pharmacology, Food Science, Agriculture, Nuclear Science Technology, Optics) (Section Editors: Prof. Zhonghao Li and Prof. Maya Guncheva) This encyclopedia is systematic and comprehensive, with detailed descriptions about theory, technology, and industrial applications. This encyclopedia is valuable for students, researchers and industrial players, giving them a quick understanding and overview of ionic liquids in various aspects.