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Two dramatically different philosophical approaches to classical mechanics were proposed during the 17th - 18th centuries. Newton developed his vectorial formulation that uses time-dependent differential equations of motion to relate vector observables like force and rate of change of momentum. Euler, Lagrange, Hamilton, and Jacobi, developed powerful alternative variational formulations based on the assumption that nature follows the principle of least action. These variational formulations now play a pivotal role in science and engineering.This book introduces variational principles and their application to classical mechanics. The relative merits of the intuitive Newtonian vectorial formulation, and the more powerful variational formulations are compared. Applications to a wide variety of topics illustrate the intellectual beauty, remarkable power, and broad scope provided by use of variational principles in physics.The second edition adds discussion of the use of variational principles applied to the following topics:(1) Systems subject to initial boundary conditions(2) The hierarchy of related formulations based on action, Lagrangian, Hamiltonian, and equations of motion, to systems that involve symmetries.(3) Non-conservative systems.(4) Variable-mass systems.(5) The General Theory of Relativity.Douglas Cline is a Professor of Physics in the Department of Physics and Astronomy, University of Rochester, Rochester, New York.
This revised, updated edition provides a comprehensive and rigorous description of the application of Hamilton’s principle to continuous media. To introduce terminology and initial concepts, it begins with what is called the first problem of the calculus of variations. For both historical and pedagogical reasons, it first discusses the application of the principle to systems of particles, including conservative and non-conservative systems and systems with constraints. The foundations of mechanics of continua are introduced in the context of inner product spaces. With this basis, the application of Hamilton’s principle to the classical theories of fluid and solid mechanics are covered. Then recent developments are described, including materials with microstructure, mixtures, and continua with singular surfaces.
DIVHistorical, theoretical survey with many insights, much hard-to-find material. Hamilton’s principle, Hamilton-Jacobi equation, etc. /div
Recent years have seen a growing trend to derive models of macroscopic phenomena encountered in the fields of engineering, physics, chemistry, ecology, self-organisation theory and econophysics from various variational or extremum principles. Through the link between the integral extremum of a functional and the local extremum of a function (explicit, for example, in the Pontryagin's maximum principle variational and extremum principles are mutually related. Thus it makes sense to consider them within a common context. The main goal of Variational and Extremum Principles in Macroscopic Systems is to collect various mathematical formulations and examples of physical reasoning that involve both basic theoretical aspects and applications of variational and extremum approaches to systems of the macroscopic world. The first part of the book is focused on the theory, whereas the second focuses on applications. The unifying variational approach is used to derive the balance or conservation equations, phenomenological equations linking fluxes and forces, equations of change for processes with coupled transfer of energy and substance, and optimal conditions for energy management. - A unique multidisciplinary synthesis of variational and extremum principles in theory and application - A comprehensive review of current and past achievements in variational formulations for macroscopic processes - Uses Lagrangian and Hamiltonian formalisms as a basis for the exposition of novel approaches to transfer and conversion of thermal, solar and chemical energy
New textbooks at all levels of chemistry appear with great regularity. Some fields like basic biochemistry, organic reaction mechanisms, and chemical thermody namics are well represented by many excellent texts, and new or revised editions are published sufficiently often to keep up with progress in research. However, some areas of chemistry, especially many of those taught at the graduate level, suffer from a real lack of up-to-date textbooks. The most serious needs occur in fields that are rapidly changing. Textbooks in these subjects usually have to be written by scientists actually involved in the research which is advancing the field. It is not often easy to persuade such individuals to set time aside to help spread the knowledge they have accumulated. Our goal, in this series, is to pinpoint areas of chemistry where recent progress has outpaced what is covered in any available textbooks, and then seek out and persuade experts in these fields to produce relatively concise but instructive introductions to their fields. These should serve the needs of one semester or one quarter graduate courses in chemistry and biochemistry. In some cases, the availability of texts in active research areas should help stimulate the creation of new courses. New York, New York CHARLES R. CANTOR Preface This book is not a traditional quantum chemistry textbook. Instead, it represents a concept that has evolved from teaching graduate courses in quantum chemistry over a number of years, and encountering students with diverse backgrounds.
A comprehensive yet accessible exploration of quantum chemical methods for the determination of molecular properties of spectroscopic relevance Molecular properties can be probed both through experiment and simulation. This book bridges these two worlds, connecting the experimentalist's macroscopic view of responses of the electromagnetic field to the theoretician’s microscopic description of the molecular responses. Comprehensive in scope, it also offers conceptual illustrations of molecular response theory by means of time-dependent simulations of simple systems. This important resource in physical chemistry offers: A journey in electrodynamics from the molecular microscopic perspective to the conventional macroscopic viewpoint The construction of Hamiltonians that are appropriate for the quantum mechanical description of molecular properties Time- and frequency-domain perspectives of light–matter interactions and molecular responses of both electrons and nuclei An introduction to approximate state response theory that serves as an everyday tool for computational chemists A unified presentation of prominent molecular properties Principles and Practices of Molecular Properties: Theory, Modeling and Simulations is written by noted experts in the field. It is a guide for graduate students, postdoctoral researchers and professionals in academia and industry alike, providing a set of keys to the research literature.
Professor Ziman's classic textbook on the theory of solids was first pulished in 1964. This paperback edition is a reprint of the second edition, which was substantially revised and enlarged in 1972. The value and popularity of this textbook is well attested by reviewers' opinions and by the existence of several foreign language editions, including German, Italian, Spanish, Japanese, Polish and Russian. The book gives a clear exposition of the elements of the physics of perfect crystalline solids. In discussing the principles, the author aims to give students an appreciation of the conditions which are necessary for the appearance of the various phenomena. A self-contained mathematical account is given of the simplest model that will demonstrate each principle. A grounding in quantum mechanics and knowledge of elementary facts about solids is assumed. This is therefore a textbook for advanced undergraduates and is also appropriate for graduate courses.
Thereareabout500booksonvariationalprinciples. Theyareconcernedmostlywith the mathematical aspects of the topic. The major goal of this book is to discuss the physical origin of the variational principles and the intrinsic interrelations between them. For example, the Gibbs principles appear not as the rst principles of the theory of thermodynamic equilibrium but as a consequence of the Einstein formula for thermodynamic uctuations. The mathematical issues are considered as long as they shed light on the physical outcomes and/or provide a useful technique for direct study of variational problems. Thebookisacompletelyrewrittenversionoftheauthor’smonographVariational Principles of Continuum Mechanics which appeared in Russian in 1983. I have been postponing the English translation because I wished to include the variational pr- ciples of irreversible processes in the new edition. Reaching an understanding of this subject took longer than I expected. In its nal form, this book covers all aspects of the story. The part concerned with irreversible processes is tiny, but it determines the accents put on all the results presented. The other new issues included in the book are: entropy of microstructure, variational principles of vortex line dynamics, va- ational principles and integration in functional spaces, some stochastic variational problems, variational principle for probability densities of local elds in composites with random structure, variational theory of turbulence; these topics have not been covered previously in monographic literature.
This book deals with the foundations of classical physics from the OC symplecticOCO point of view, and of quantum mechanics from the OC metaplecticOCO point of view. The Bohmian interpretation of quantum mechanics is discussed. Phase space quantization is achieved using the OC principle of the symplectic camelOCO, which is a recently discovered deep topological property of Hamiltonian flows. The mathematical tools developed in this book are the theory of the metaplectic group, the Maslov index in a precise form, and the Leray index of a pair of Lagrangian planes. The concept of the OC metatronOCO is introduced, in connection with the Bohmian theory of motion. A precise form of Feynman''s integral is introduced in connection with the extended metaplectic representation. Contents: From Kepler to SchrAdinger OC and Beyond; Newtonian Mechanics; The Symplectic Group; Action and Phase; Semi-Classical Mechanics; The Metaplectic Group and the Maslov Index; SchrAdinger''s Equation and the Metatron. Readership: Researchers and graduate students in mathematical physics."