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Thermodynamics is the much abused slave of many masters • physicists who love the totally impractical Carnot process, • mechanical engineers who design power stations and refrigerators, • chemists who are successfully synthesizing ammonia and are puzzled by photosynthesis, • meteorologists who calculate cloud bases and predict föhn, boraccia and scirocco, • physico-chemists who vulcanize rubber and build fuel cells, • chemical engineers who rectify natural gas and distil f- mented potato juice, • metallurgists who improve steels and harden surfaces, • - trition counselors who recommend a proper intake of calories, • mechanics who adjust heat exchangers, • architects who construe – and often misconstrue – ch- neys, • biologists who marvel at the height of trees, • air conditioning engineers who design saunas and the ventilation of air plane cabins, • rocket engineers who create supersonic flows, et cetera. Not all of these professional groups need the full depth and breadth of ther- dynamics. For some it is enough to consider a well-stirred tank, for others a s- tionary nozzle flow is essential, and yet others are well-served with the partial d- ferential equation of heat conduction. It is therefore natural that thermodynamics is prone to mutilation; different group-specific meta-thermodynamics’ have emerged which serve the interest of the groups under most circumstances and leave out aspects that are not often needed in their fields.
Provides an essential treatment of the subject and rigorous methods to solve all kinds of energy engineering problems.
Now in a new edition, this book continues to set the standard for teaching readers how to be effective problem solvers, emphasizing the authors's signature methodologies that have taught over a half million students worldwide. This new edition provides a student-friendly approach that emphasizes the relevance of thermodynamics principles to some of the most critical issues of today and coming decades, including a wealth of integrated coverage of energy and the environment, biomedical/bioengineering, as well as emerging technologies. Visualization skills are developed and basic principles demonstrated through a complete set of animations that have been interwoven throughout.
A concise treatment of the fundamentals of thermodynamics is presented in this book. In particular, emphasis is placed on discussions of the second law, a unique feature of thermodynamics, which states the limitations of converting thermal energy into mechanical energy. The entropy function that permits the loss in the potential of a real thermodynamic process to be assessed, the maximum possible work in a process, and irreversibility and equilibrium are deduced from the law through physical and intuitive considerations. They are applicable in mitigating waste heat and are useful for solving energy, power, propulsion and climate-related issues. The treatment is not restricted to properties and functions of ideal gases. The ideal gas assumption is invoked as a limiting case. Reversible paths between equilibrium states are obtained using reversible heat engines and reversible heat pumps between environment and systems to determine the entropy changes and the maximum work. The conditions of thermodynamic equilibrium comprising mechanical, thermal, chemical and phase equilibrium are addressed and the species formed at equilibrium in a chemical reaction at a given temperature and pressure are obtained. The molecular basis for the laws of thermodynamics, temperature, internal energy changes, entropy, reversibility and equilibrium are briefly discussed. The book serves as a reference for undergraduate and graduate students alongside thermodynamics textbooks.
Fundamentals of Chemical Engineering Thermodynamics is the clearest and most well-organized introduction to thermodynamics theory and calculations for all chemical engineering undergraduates. This brand-new text makes thermodynamics far easier to teach and learn. Drawing on his award-winning courses at Penn State, Dr. Themis Matsoukas organizes the text for more effective learning, focuses on "why" as well as "how," offers imagery that helps students conceptualize the equations, and illuminates thermodynamics with relevant examples from within and beyond the chemical engineering discipline. Matsoukas presents solved problems in every chapter, ranging from basic calculations to realistic safety and environmental applications.
Thermodynamics: Fundamentals and Applications for Chemical Engineers explores the concepts and properties of thermodynamics and illustrates how they can be applied to solve practical problems. The book introduces the fundamentals of thermodynamics for multi-phase, multi-component systems, providing a framework for dealing with problems in chemical engineering including mixing, compressing, and distilling fluids. The first eight chapters of Thermodynamics focus on single-component thermodynamics, introducing important concepts that will be referenced throughout subsequent chapters. Later chapters introduce modeling for multi-component systems. Topics covered include: properties as a function of state variables; first and second law of thermodynamics; power cycles, combustion, refrigeration cycles, and heat pumps; equilibrium phase relationships; correlations and calculations of vapor-liquid equilibrium data; elementary theories of solutions; and the efficiency of multicomponent separation and reaction processes. The Second Law of Thermodynamics, availability concepts, and process efficiency receive extensive coverage. The clear, well-organized sequence of the chapters helps students successfully learn and retain information. Each of the fifteen chapters includes updated sample problems that underline key principles and problem-solving steps. The book has numerous appendixes for quick reference on everything from conversion factors to Francis constants, and from properties of pure substances to thermodynamics tables and Diagrams. Thermodynamics can be used by chemical, petroleum, and mechanical engineering departments in introductory and intermediate courses on engineering thermodynamics and thermodynamics fundamentals. Born and raised in Chile, Miguel T. Fleischer earned his M.S. and Ph.D. in chemical engineering from the University of Houston where he is an adjunct professor and the undergraduate program director of the Chemical and Biomolecular Engineering Department. Dr. Fleischer worked at Royal Dutch Shell for more than 26 years in research and development, manufacturing, finance, and management. He began teaching when he was an undergraduate student in Chile where he developed a program sponsored by Universidad CatOlica de Chile to prepare high school students for college. He was the co-owner and CEO of Fleischer International Trading, a private enterprise that imported and distributed wines from all over the world for 13 years. He continued teaching while he was a graduate student at the University of Houston. He has received the Outstanding Lecturer award of the Cullen College of Engineering four times, the University's Teaching Excellence Award, the Cullen College of Engineering's Career Teaching Award, and the Cullen College of Engineering's Distinguished Engineering Alumni Award.
With the growing attention to the exploitation of renewable energies and heat recovery from industrial processes, the traditional steam and gas cycles are showing themselves often inadequate. The inadequacy is due to the great assortment of the required sizes power and of the large kind of heat sources. Closed Power Cycles: Thermodynamic Fundamentals and Applications offers an organized discussion about the strong interaction between working fluids, the thermodynamic behavior of the cycle using them and the technological design aspects of the machines. A precise treatment of thermal engines operating in accordance with closed cycles is provided to develop ideas and discussions strictly founded on the basic thermodynamic facts that control the closed cycles operation and design. Closed Power Cycles: Thermodynamic Fundamentals and Applications also contains numerous examples which have been carried out with the help of the Aspen Plus®R program. Including chapters on binary cycles, the organic Rankine cycle and real closed gas cycles, Closed Power Cycles: Thermodynamic Fundamentals and Applications acts a solid introduction and reference for post-graduate students and researchers working in applied thermodynamics and energy conversion with thermodynamic engines.
This 2006 textbook discusses the fundamentals and applications of statistical thermodynamics for beginning graduate students in the physical and engineering sciences. Building on the prototypical Maxwell–Boltzmann method and maintaining a step-by-step development of the subject, this book assumes the reader has no previous exposure to statistics, quantum mechanics or spectroscopy. The book begins with the essentials of statistical thermodynamics, pauses to recover needed knowledge from quantum mechanics and spectroscopy, and then moves on to applications involving ideal gases, the solid state and radiation. A full introduction to kinetic theory is provided, including its applications to transport phenomena and chemical kinetics. A highlight of the textbook is its discussion of modern applications, such as laser-based diagnostics. The book concludes with a thorough presentation of the ensemble method, featuring its use for real gases. Numerous examples and prompted homework problems enrich the text.
There are many thermodynamics texts on the market, yet most provide a presentation that is at a level too high for those new to the field. This second edition of Thermodynamics continues to provide an accessible introduction to thermodynamics, which maintains an appropriate rigor to prepare newcomers for subsequent, more advanced topics. The book p