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This book highlights introduction of thermodynamics; first law, second law, third law of thermodynamics and their applications; concepts of entropy, free energies, thermodynamic equilibrium, thermodynamic activity and fugacity; Maxwell relations; Gibbs-Helmholtz equation; Clausis-Clayperon equation, etc. have been discussed in detail and made easily understandable to the undergraduate students of metallurgy. Thermodynamics involved in formation of different types of solutions (ideal, real and regular solutions) has also been discussed in detail. This book also discusses the applications of various thermodynamic properties in different metallurgical operations. At the end of each and every chapter, different types of typical related problems have also been solved.
Fundamentals of Metallurgical Processes, Second Edition reviews developments in the design, control, and efficiency of metallurgical processes. Topics covered include thermodynamic functions and solutions as well as experimental and bibliographical methods, heterogeneous reactions, metal extraction, and iron and steelmaking. This book is comprised of eight chapters and begins with an overview of the fundamentals of thermodynamics (functions, relationships, and behavior of solutions), followed by a discussion on methods of obtaining thermodynamic data from tables and graphs and by experiment. The kinetics of heterogeneous reactions in metallurgy are examined next, with particular reference to heterogeneous catalysis and mass transfer between immiscible liquid phases. The following chapters focus on the extraction of metals from oxides, sulfides, and halides; the production of iron and steel; the structure and properties of slags; slag/metal reactions; and equilibria in iron and steel production. The final chapter consists entirely of solved problems. This monograph will be of interest to metallurgists and materials scientists.
Problems in Metallurgical Thermodynamics and Kinetics provides an illustration of the calculations encountered in the study of metallurgical thermodynamics and kinetics, focusing on theoretical concepts and practical applications. The chapters of this book provide comprehensive account of the theories, including basic and applied numerical examples with solutions. Unsolved numerical examples drawn from a wide range of metallurgical processes are also provided at the end of each chapter. The topics discussed include the three laws of thermodynamics; Clausius-Clapeyron equation; fugacity, activity, and equilibrium constant; thermodynamics of electrochemical cells; and kinetics. This book is beneficial to undergraduate and postgraduate students in universities, polytechnics, and technical colleges.
"The CD contains data and descriptive material for making detailed thermodynamic calculations involving materials processing"--Preface.
This book is dedicated to the processes of mineral transformation, recycling and reclamation of metals, for the purpose of turning metals and alloys into a liquid state ready for pouring. Even though "process metallurgy" is one of the oldest technologies implemented by man, technological innovation, with the development of processes that are both focused on product quality and economically and ecologically efficient, continues to be at the heart of these industries. This book explains the physico-chemical bases of transformations, vital to their understanding and control (optimization of operational conditions), and the foundations in terms of "process engineering" (heat and matter assessment, process coupling: chemical reactions and transport phenomena), vital to the optimal execution and analysis of transformation process operations. This book is addressed to students in the field of metallurgy and to engineers facing the problem of metal and alloy development (operation of an industrial unit or development of a new process).
As product specifications become more demanding, manufacturers require steel with ever more specific functional properties. As a result, there has been a wealth of research on how those properties emerge during steelmaking. Fundamentals of metallurgy summarises this research and its implications for manufacturers.The first part of the book reviews the effects of processing on the properties of metals with a range of chapters on such phenomena as phase transformations, types of kinetic reaction, transport and interfacial phenomena. Authors discuss how these processes and the resulting properties of metals can be modelled and predicted. Part two discusses the implications of this research for improving steelmaking and steel properties.With its distinguished editor and international team of contributors, Fundamentals of metallurgy is an invaluable reference for steelmakers and manufacturers requiring high-performance steels in such areas as automotive and aerospace engineering. It will also be useful for those dealing with non-ferrous metals and alloys, material designers for functional materials, environmentalists and above all, high technology industries designing processes towards materials with tailored properties. - Summarises key research and its implications for manufacturers - Essential reading for steelmakers and manufacturers - Written by leading experts from both industry and academia
This book is written specially for the students of B.E./B.Tech. of Metallurgical and Materials Engineering. It also serves the needs of allied scientific disciplines at the undergraduate, graduate level and practising professional engineers
The Book Attempts To Present A Comprehensive View Of Extractive Metallurgy, Especially Principles Of Extractive Metallurgy In A Concise Form. This Is The First Book In This Area Which Attempts To Do It. It Has Been Written In Textbook Style. It Presents The Various Concepts Step By Step, Shows Their Importance, Deals With Elementary Quantitative Formulations, And Illustrates Through Quantitative And Qualitative Informations. The Approach Is Such That Even Undergraduate Students Would Be Able To Follow The Topics Without Much Difficulty And Without Much Of A Background In Specialized Subjects. This Is Considered To Be A Very Useful Approach In This Area Of Technology. Moreover The Inter-Disciplinary Nature Of The Subject Has Been Duely Brought Out.While Teaching Concerned Course(S) In The Undergraduate And Postgraduate Level The Authors Felt The Need Of Such A Book. The Authors Found The Books Available On The Subject Did Not Fulfill The Requirements. No Other Book Was Concerned With All Relevant Concepts. Most Of Them Laid Emphasis Either On Thermodynamic Aspects Or On Discussing Unit Processes. Transport Phenomena Are Dealt With In Entirely Different Books. Reactor Concepts Were Again Lying In Chemical Engineering Texts. The Authors Tried To Harmonize And Synthesize The Concepts In Elementary Terms For Metallurgists.The Present Book Contains A Brief Descriptive Summary Of Some Important Metallurgical Unit Processes. Subsequently It Discusses Not Only Physical Chemistry Of Metallurgical Reactions And Processes But Also Rate Phenomena Including Heat And Mass Transfer, Fluid Flow, Mass And Energy Balance, And Elements Of Reactor Engineering. A Variety Of Scientific And Engineering Aspects Of Unit Processes Have Been Discussed With Stress On The Basic Principles All Throughout. There Is An Attempt To Introduce, As Much As Possible, Quantitative Treatments And Engineering Estimates. The Latter May Often Be Approximate From The Point Of View Of Theory But Yields Results That Are Very Valuable To Both Practicing Metallurgists As Well As Others.
This volume covers various aspects of the fundamentals, synthesis, analysis, design, monitoring, and control of metals, materials, and metallurgical processes and phenomena. Topics represented include but are not limited to: • Experimental, analytical, physical, and computer modeling of physical chemistry and thermodynamics • Modeling of the transport phenomena in materials processing and metallurgical processes involving iron, steel, nonferrous metals, and composites • Second-phase particles in metals and processes and the fundamentals (experimental studies or theoretical studies) on the nucleation, growth, motion, and removal of these particles from the molten metal or reactors • Physical chemistry, thermodynamics, and kinetics for the production and refining of rare-earth metals • Control of industrial processes in the field of extraction and processing of metals and materials