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Free radical initiators–chemical molecules which easily decompose into free radicals–serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include: Dialkyl Peroxides and Hydroperoxides Diacyl Peroxides, Peresters, and Organic Polyoxides Azo-Compounds Bimolecular Reactions of Free Radical Generation by Ozone, Dioxygen, Hydroperoxides, and Haloid Molecules Free Radical Abstraction Reactions Free Radical Addition Reactions Free Radical Recombination and Disproportoination Reactions Professionals and academic researchers in chemical engineering, pharmaceuticals, biotechnology, plastics, and rubbers will find the Handbook of Free Radical Initiators to be a distinguished, vital resource.
Provides the latest authoritative research on the developments, technology, and applications of rubbery materials. Presents structures, manufacturing techniques, and processing details for natural and synthetic rubbers, rubber-blends, rubber composites, and thermoplastic elastomers. 80% revised and rewritten material covers major advances since publication of the previous edition.
Controlled/living radical polymerization (CRP) has revolutionized and revitalized the field of synthetic polymer chemistry over the last twenty years as it is now possible to prepare a wide variety of previously inaccessible macromolecules under relatively mild conditions. Fundamentals of Controlled/Living Radical Polymerization provides an in-depth coverage of the essential chemical principles that enable and govern each of the CRP methods. The book starts with a brief historical overview of the major findings in polymer science which eventually led to the development of living ionic and living radical systems. It then goes on to introduce the main CRP techniques including their mechanistic understanding. The book also provides the information needed to select the appropriate reagents and conditions to conduct various CRP methods in a practical setting. Therefore, in addition to a newcomer gaining an appreciation for what has already been accomplished, the reader will be armed with the tools needed to begin independent research. Fundamentals of Controlled/Living Radical Polymerization provides essential insight into a rapidly growing field that goes beyond a simple literature review of the area. Written by leading experts in the field, the book is an indispensible resource for all researchers, instructors, and students in polymer chemistry.
A one-stop resource for understanding and applying polymerization catalysts An edited volume featuring contributions from leading researchers, the Handbook of Transition Metal Polymerization Catalysts covers the design and synthesis of catalysts, and their applications in synthesis of polymers. Dealing with those polymerization catalysts that afford commercially acceptable yields of polymer with respect to catalyst mass and promising newer catalysts, this practical reference provides polymer and organic chemists with a comprehensive overview of the known methods for developing and applying these important catalysts. With both recent advances and historically important catalysts, the subjects covered in this text include: Metal alkyls and other compounds that function as co-catalysts with a large number of catalysts The varieties of porous silica either necessary or valuable in certain catalyst formulations Catalyst scale-up and commercialization Copper catalysts for olefin polymerization Morphology control Along with the above topics, the Handbook of Transition Metal Polymerization Catalysts provides tables of valuable data to assist in reproducing a synthesis or applying the knowledge to a new problem. Polymerization reactivities, polymer properties, monomer and solvent purity requirements, molecular weights, distribution, and reactivity ratios are also covered. The Handbook of Transition Metal Polymerization Catalysts offers an excellent one-stop resource for understanding and applying polymerization catalysts.
Providing a range of information on polymers and polymerization techniques, this text covers the gamut of polymer science from synthesis, structure and properties to function and applications. It analyzes speciality polymers, including acrylics, fluoropolymers, polysiplanes, polyphosphazenes, and inorganic and conducting polymers. The book examines the stereochemistry of polymerization and the stereoregularity of polymers.
Kurti and Czako have produced an indispensable tool for specialists and non-specialists in organic chemistry. This innovative reference work includes 250 organic reactions and their strategic use in the synthesis of complex natural and unnatural products. Reactions are thoroughly discussed in a convenient, two-page layout--using full color. Its comprehensive coverage, superb organization, quality of presentation, and wealth of references, make this a necessity for every organic chemist. - The first reference work on named reactions to present colored schemes for easier understanding - 250 frequently used named reactions are presented in a convenient two-page layout with numerous examples - An opening list of abbreviations includes both structures and chemical names - Contains more than 10,000 references grouped by seminal papers, reviews, modifications, and theoretical works - Appendices list reactions in order of discovery, group by contemporary usage, and provide additional study tools - Extensive index quickly locates information using words found in text and drawings
Rodd's Chemistry of Carbon Compounds, Volume II: Alicyclic Compounds focuses on alicyclic chemistry. The book first ponders on acyclic and monocyclic monoterpenoids, including artemisyl, santolinyl, chrysanthemyl, and other irregular systems; naturally occurring halogenated monoterpenoids; cyclobutanes; and tetramethylcyclohexanes. The text discusses the carotenoid group of natural products. Trends in carotenoid chemical research; improved methodology; optical isomerism including aliene isomerism; and geometrical isomerism are described. The book discusses cycloheptanes and cyclooctanes, large alicyclic ring systems, and polycarbonic compounds with separate ring systems and spiro compounds. The text describes polycyclic compounds and polycarbocyclic bridged ring compounds, and then discusses bicarbocyclic natural products. The Wagner-Meerwein rearrangement; camphor and related compounds; fenchone and related compounds; and carane, thujane, and pinane groups are also considered. The text is a valuable reference for readers interested in the study of carbon compounds.