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This report does not seek to single out synthetic polymers as a special case. It aims to provide an overview of the whole subject of combustion toxicity and threat to life, whilst supplying specific information on the most frequently encountered polymeric materials, and combustion products such as dioxins which have received high levels of media attention. An additional indexed section containing several hundred abstracts from the Rapra Polymer Library database provides useful references for further reading.
Polymer Green Flame Retardants covers key issues regarding the response of polymers during fire, the mechanisms of their flame retardation, the regulations imposed on their use, and the health hazards arising from their combustion. Presenting the latest research developments, the book focuses in particular on nanocomposites, believed to be the most promising approach for producing physically superior materials with low flammability and ecological impact. The fire properties of nanocomposites of various matrixes and fillers are discussed, the toxicological characteristics of these materials are analyzed, addressing also their environmental sustainability. Edited by distinguished scientists, including an array of international industry and academia experts, this book will appeal to chemical, mechanical, environmental, material and process engineers, upper-level undergraduate and graduate students in these disciplines, and generally to researchers developing commercially attractive and environmentally friendly fire-proof products. - Provides recent findings on the manufacture of environmentally sustainable flame retardant polymeric materials - Covers legislation and regulations concerning flame retarded polymeric material use - Includes tables containing the fire properties of the most common polymeric materials
Toxic fire effluents are responsible for the majority of fire deaths, and an increasing large majority of fire injuries, driven by the widespread and increasing use of synthetic polymers. Fire safety has focused on preventing ignition and reducing flame spread through reducing the rate of heat release, while neglecting the important issue of fire toxicity. This is the first reference work on fire toxicity and the only scientific publication on the subject in the last 15 years.Assessment of toxic effects of fires is increasingly being recognised as a key factor in the assessment of fire hazards. This book raises important issues including the types of toxic effluents that different fires produce, their physiological effects, methods for generation and assessment of fire toxicity, current and proposed regulations and approaches to modelling the toxic impact of fires.The contributors to Fire toxicity represent an international team of the leading experts in each aspect of this challenging and important field. This book provides an important reference work for professionals in the fire community, including fire fighters, fire investigators, regulators, fire safety engineers, and formulators of fire-safe materials. It will also prove invaluable to researchers in academia and industry. - Investigates the controversial subject of toxic effluents as the cause of the majority of fire deaths and injuries - Describes the different types of toxic effluents and the specific fires that they produce, their physiological effects and methods for generation - Provides an overview of national and international fire safety regulations including current and proposed regulations such as a standardized framework for prediction of fire gas toxicity
"The bulk of this book consists of six case studies of major fires through which Wallace attempts to create sentiment against plastics, especially polyvinyl chloride (PVC), and for fire safety regulation--much as Rachel Carson did for pesticides in Silent Spring. Wallace does convince the reader that existing combustion tests, standards, fire and building codes, code enforcement, emergency services, public agencies, and private companies send out false assurances, and that neither firefighters nor the public are adequately protected against very toxic or fatal fumes from burning plastics. Her model of a successful resolution is the New York State Building Code, passed in 1986. The book is only a partially successful synthesis of technical and popular material;"--Library journal.
My heart sank when I was approached by Dr Hastings and by Professor Briggs (Senior Editor of Materials Science and Technology and Series Editor of Polymer Science and Technology Series at Chapman & Hall, respectively) to edit a book with the provisional title Handbook of Poly propylene. My reluctance was due to the fact that my former book [1] along with that of Moore [2], issued in the meantime, seemed to cover the information demand on polypropylene and related systems. Encour aged, however, by some colleagues (the new generation of scientists and engineers needs a good reference book with easy information retrieval, and the development with metallocene catalysts deserves a new update!), I started on this venture. Having some experience with polypropylene systems and being aware of the current literature, it was easy to settle the titles for the book chapters and also to select and approach the most suitable potential contributors. Fortunately, many of my first-choice authors accepted the invitation to contribute. Like all editors of multi-author volumes, I recognize that obtaining contributors follows an S-type curve of asymptotic saturation when the number of willing contributors is plotted as a function of time. The saturation point is, however, never reached and as a consequence, Dear Reader, you will also find some topics of some relevance which are not explicitly treated in this book (but, believe me, I have considered them).
FROM THE INTRODUCTION "Considerable effort has gone into the study of various aspects of flammability and of various plastic materials, so that these materials which are proving so useful to man will always be used in ways which will not compromise his safety. The task is a continuing one, because the family of plastics continues to grow, and, along with it, its variety of applications. Some of these future applications cannot even be conceived of at the present time. The needs of man and his society are changing, and with them the factors that affect his safety, comfort, and convenience. A flammability handbook for plastics must necessarily involve a variety of sciences and technologies spread across the whole spectrum of human knowledge, and it is impossible to discuss all the subjects in great depth. Any details extracted for attention are brought because they are believed to be significant to the overall effort to make plastics as useful and safe as humanly possible."
Combustion toxicology is a recent, applied science, the ultimate purpose of which is to reduce casualties from smoke inhalation. The present volume attempts an unbiased presentation of the state of the field. The authors have identified the misconceptions and unsupported conclusions in the literature, differentiating between fact and hypothesis and present the reader with an account of what is really known about the toxicity of smoke produced by materials. They also recommend an approach to evaluating the toxicity of combustion products.