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This report presents a cost analysis of Ethyl tert-Butyl Ether (ETBE) production from butane and ethanol. The process examined consists of four catalytic processes: n-butane isomerization, similar to UOP's Butamer process; isobutane dehydrogenation, similar to UOP's Butamer process; diolefins saturation, similar to UOP's CSP process and isobutylene etherification, similar to UOP's Ethermax process. This report was developed based essentially on the following reference(s): Keywords: Etherification Reaction, butane dehydrogenation, isobutylene synthesis, Fuel Additive, Oxygenates
This report presents a cost analysis of Methyl Methacrylate (MMA) production from isobutylene using an oxidation process. The process examined is similar to Sumitomo/Nippon Shokubai process. In this process, methacrylic acid (MAA) intermediate is initially produced by two-stage catalytic oxidation of isobutene. Then, MAA is esterified with methanol to produce MMA. This report was developed based essentially on the following reference(s): (1) EP Patent 1052017, issued to Nippon Shokubai in 2012 (2) "Methacrylic Acid and Derivatives", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Isobutene, Methylpropene, Esterification, Two-Stage Oxidation, Japan Methacryl Monomer, JMM
This report presents a cost analysis of Ethyl tert-Butyl Ether (ETBE) production from an isobutylene rich stream from a butane dehydrogenation plant and ethanol. The process examined is similar to UOP's Ethermax process for isobutylene etherification. In this process the etherification reaction is conducted in two steps, the first step being a conventional reactor and the second a reactive distillation column. Other established commercial etherification processes with similar configuration, like CBI's CDMTBE, Axens' MTBE Process and Evonik's MTBE Process may as well be represented by the economic analysis presented in this report. This report was developed based essentially on the following reference(s): Keywords: Etherification Reaction, butane dehydrogenation, isobutylene synthesis, Fuel Additive, Oxygenates
This report presents a cost analysis of Ethyl tert-Butyl Ether (ETBE) production from raffinate-1 and ethanol. The process examined is similar to UOP's Ethermax process for isobutylene etherification. In this process the etherification reaction is conducted in two steps, the first step being a conventional reactor and the second a reactive distillation column. Other established commercial etherification processes with similar configuration, like CBI's CDMTBE, Axens' MTBE Process and Evonik's MTBE Process may as well be represented by the economic analysis presented in this report. This report was developed based essentially on the following reference(s): Keywords: Etherification Reaction, Steam Cracking C4, Raffinate-1, Fuel Additive, Oxygenates
This report presents a cost analysis of Ethyl tert-Butyl Ether (ETBE) production from catalytic cracking C4 raffinate stream and ethanol. The process examined is similar to UOP's Ethermax process for isobutylene etherification. In this process the etherification reaction is conducted in two steps, the first step being a conventional reactor and the second a reactive distillation column. Other established commercial etherification processes with similar configuration, like CBI's CDMTBE, Axens' MTBE Process and Evonik's MTBE Process may as well be represented by the economic analysis presented in this report. This report was developed based essentially on the following reference(s): Keywords: Etherification Reaction, Fluid Catalytic Cracking, C4 raffinate, Fuel Additive, Oxygenates
This report presents a cost analysis of Maleic Anhydride production from butane via partial oxidation process. The process examined is similar to the one owned by Huntsman. In this process, Maleic Anhydride is produced by the partial oxidation reaction of n-butane with oxygen carried out in a fixed-bed reactor. The reactor effluent is sent to a solvent-based recovery system for Maleic Anhydride separation. This report examines one-time costs associated with the construction of a United States-based plant and the continuing costs associated with the daily operation of such a plant. More specifically, it discusses: * Capital Investment, broken down by: - Total fixed capital required, divided in production unit (ISBL); infrastructure (OSBL) and contingency - Alternative perspective on the total fixed capital, divided in direct costs, indirect costs and contingency - Working capital and costs incurred during industrial plant commissioning and start-up * Production cost, broken down by: - Manufacturing variable costs (raw materials, utilities) - Manufacturing fixed costs (maintenance costs, operating charges, plant overhead, local taxes and insurance) - Depreciation and corporate overhead costs * Raw materials consumption, products generation and labor requirements * Process block flow diagram and description of industrial site installations (production unit and infrastructure) This report was developed based essentially on the following reference(s): (1) US Patent 4118403 issued to Monsanto in 1978 (assigned to Huntsman in 1994); (2) US Patent 6090245, issued to Huntsman in 2000 Keywords: Fixed Bed, Maleic Acid Anhydride, C4 Oxidation, Huntsman, Monsanto