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Environmental and Low-Temperature Geochemistry presents conceptual and quantitative principles of geochemistry in order to foster understanding of natural processes at and near the earth’s surface, as well as anthropogenic impacts on the natural environment. It provides the reader with the essentials of concentration, speciation and reactivity of elements in soils, waters, sediments and air, drawing attention to both thermodynamic and kinetic controls. Specific features include: • An introductory chapter that reviews basic chemical principles applied to environmental and low-temperature geochemistry • Explanation and analysis of the importance of minerals in the environment • Principles of aqueous geochemistry • Organic compounds in the environment • The role of microbes in processes such as biomineralization, elemental speciation and reduction-oxidation reactions • Thorough coverage of the fundamentals of important geochemical cycles (C, N, P, S) • Atmospheric chemistry • Soil geochemistry • The roles of stable isotopes in environmental analysis • Radioactive and radiogenic isotopes as environmental tracers and environmental contaminants • Principles and examples of instrumental analysis in environmental geochemistry The text concludes with a case study of surface water and groundwater contamination that includes interactions and reactions of naturally-derived inorganic substances and introduced organic compounds (fuels and solvents), and illustrates the importance of interdisciplinary analysis in environmental geochemistry. Readership: Advanced undergraduate and graduate students studying environmental/low T geochemistry as part of an earth science, environmental science or related program. Additional resources for this book can be found at: www.wiley.com/go/ryan/geochemistry.
Environmental and Low-Temperature Geochemistry presents conceptual and quantitative principles of geochemistry in order to foster understanding of natural processes at and near the earth’s surface, as well as anthropogenic impacts on the natural environment. It provides the reader with the essentials of concentration, speciation and reactivity of elements in soils, waters, sediments and air, drawing attention to both thermodynamic and kinetic controls. Specific features include: • An introductory chapter that reviews basic chemical principles applied to environmental and low-temperature geochemistry • Explanation and analysis of the importance of minerals in the environment • Principles of aqueous geochemistry • Organic compounds in the environment • The role of microbes in processes such as biomineralization, elemental speciation and reduction-oxidation reactions • Thorough coverage of the fundamentals of important geochemical cycles (C, N, P, S) • Atmospheric chemistry • Soil geochemistry • The roles of stable isotopes in environmental analysis • Radioactive and radiogenic isotopes as environmental tracers and environmental contaminants • Principles and examples of instrumental analysis in environmental geochemistry The text concludes with a case study of surface water and groundwater contamination that includes interactions and reactions of naturally-derived inorganic substances and introduced organic compounds (fuels and solvents), and illustrates the importance of interdisciplinary analysis in environmental geochemistry. Readership: Advanced undergraduate and graduate students studying environmental/low T geochemistry as part of an earth science, environmental science or related program. Additional resources for this book can be found at: www.wiley.com/go/ryan/geochemistry.
Environmental and Low-Temperature Geochemistry presents conceptual and quantitative principles of geochemistry in order to foster understanding of natural processes at and near the earth’s surface, as well as anthropogenic impacts and remediation strategies. It provides the reader with principles that allow prediction of concentration, speciation, mobility and reactivity of elements and compounds in soils, waters, sediments and air, drawing attention to both thermodynamic and kinetic controls. The scope includes atmosphere, terrestrial waters, marine waters, soils, sediments and rocks in the shallow crust; the temporal scale is present to Precambrian, and the spatial scale is nanometers to local, regional and global. This second edition of Environmental and Low-Temperature Geochemistry provides the most up-to-date status of the carbon cycle and global warming, including carbon sources, sinks, fluxes and consequences, as well as emerging evidence for (and effects of) ocean acidification. Understanding environmental problems like this requires knowledge based in fundamental principles of equilibrium, kinetics, basic laws of chemistry and physics, empirical evidence, examples from the geological record, and identification of system fluxes and reservoirs that allow us to conceptualize and understand. This edition aims to do that with clear explanations of fundamental principles of geochemistry as well as information and approaches that provide the student or researcher with knowledge to address pressing questions in environmental and geological sciences. New content in this edition includes: Focus Boxes – one every two or three pages – providing case study examples (e.g. methyl isocyanate in Bhopal, origins and health effects of asbestiform minerals), concise explanations of fundamental concepts (e.g. balancing chemical equations, isotopic fractionation, using the Keq to predict reactivity), and useful information (e.g. units of concentration, titrating to determine alkalinity, measuring redox potential of natural waters); Sections on emerging contaminants for which knowledge is rapidly increasing (e.g. perfluorinated compounds, pharmaceuticals and other domestic and industrial chemicals); Greater attention to interrelationships of inorganic, organic and biotic phases and processes; Descriptions, theoretical frameworks and examples of emerging methodologies in geochemistry research, e.g. clumped C-O isotopes to assess seawater temperature over geological time, metal stable isotopes to assess source and transport processes, X-ray absorption spectroscopy to study oxidation state and valence configuration of atoms and molecules; Additional end-of-chapter problems, including more quantitatively based questions. Two detailed case studies that examine fate and transport of organic contaminants (VOCs, PFCs), with data and interpretations presented separately. These examples consider the chemical and mineralogical composition of rocks, soils and waters in the affected system; microbial influence on the decomposition of organic compounds; the effect of reduction-oxidation on transport of Fe, As and Mn; stable isotopes and synthetic compounds as tracers of flow; geological factors that influence flow; and implications for remediation. The interdisciplinary approach and range of topics – including environmental contamination of air, water and soil as well as the processes that affect both natural and anthropogenic systems – make it well-suited for environmental geochemistry courses at universities as well as liberal arts colleges.
Environmental Geochemistry: Site Characterization, Data Analysis and Case Histories, Second Edition, reviews the role of geochemistry in the environment and details state-of-the-art applications of these principles in the field, specifically in pollution and remediation situations. Chapters cover both philosophy and procedures, as well as applications, in an array of issues in environmental geochemistry including health problems related to environment pollution, waste disposal and data base management. This updated edition also includes illustrations of specific case histories of site characterization and remediation of brownfield sites. - Covers numerous global case studies allowing readers to see principles in action - Explores the environmental impacts on soils, water and air in terms of both inorganic and organic geochemistry - Written by a well-respected author team, with over 100 years of experience combined - Includes updated content on: urban geochemical mapping, chemical speciation, characterizing a brownsfield site and the relationship between heavy metal distributions and cancer mortality
Many geochemists focus on natural systems with less emphasis on the human impact on those systems. Environmental chemists frequently approach their subject with less consideration of the historical record than geoscientists. The field of environmental geochemistry combines these approaches to address questions about the natural environment and anthropogenic effects on it. Eby provides students with a solid foundation in basic aqueous geochemistry before discussing the important role carbon compounds, isotopes, and minerals play in environmental issues. He then guides students through how these concepts apply to problems facing our atmosphere, continental lands, and oceans. Rather than broadly discussing a variety of environmental problems, the author focuses on principles throughout the text, leading students to understand processes and how knowledge of those processes can be applied to environmental problem solving. A wide variety of case studies and quantitative problems accompany each chapter, giving each instructor the flexibility to tailor the material to his/her course. Many problems have no single correct answer, illustrating the analytical nature of solving real-world environmental problems.
Low-temperature geochemistry -- a 'hot topic' in geochemistry at present -- deals with geological and chemical processes and the geochemical evolution of elements in nature below 200C, including the geochemical behaviour of elements in the processes of their extraction, remobilization, transport and mineralization at room temperature and below 0C. This book focuses on the low-temperature geochemical behaviour of precious metals, REE, some individual dispersed elements and some non-metallic elements and their minergenesis at low-temperatures. The book deals with the following topics: 1) geochemistry of selected low-temperature deposits or prospects (horizons); 2) geochemistry of elements during diagenesis, buried metamorphism and low-grade metamorphism; 3) remobilization, transport and precipitation of some ore-forming elements under low-temperature conditions; 4) water/rock interactions in low-temperature open systems
Volume 49 of Reviews in Mineralogy and Geochemistry reviews the state of the art of synchrotron radiation applications in low temperature geochemistry and environmental science, and offer speculations on future developments. The reader of this volume will acquire an appreciation of the theory and applications of synchrotron radiation in low temperature geochemistry and environmental science, as well as the significant advances that have been made in this area in the past two decades. It gives a fairly comprehensive overview of synchrotron radiation applications in low temperature geochemistry and environmental science, describes the ways that synchrotron radiation is generated, including a history of synchrotrons and a discussion of aspects of synchrotron radiation that are important to the experimentalist, describes specific synchrotron methods that are most useful for single-crystal surface and mineral-fluid interface studies as well as methods that can be used more generally for investigating complex polyphase fine-grained or amorphous materials, including soils, rocks, and organic matter.
An examination of both theoretical and practical approaches to the geochemistry of natural waters with a more tightly focused emphasis on fresh-water environments. The third edition focuses more on environmental issues than the previous edition, reflecting the importance on environmental geochemistry as a result of increased environmental awareness and regulatory requirements. Prepares readers to interpret the probable cause of a particular water composition and to predict the probable water chemistry in those situations where data do not exist.
This book provides a comprehensive introduction to the field of geochemistry. The book first lays out the ‘geochemical toolbox’: the basic principles and techniques of modern geochemistry, beginning with a review of thermodynamics and kinetics as they apply to the Earth and its environs. These basic concepts are then applied to understanding processes in aqueous systems and the behavior of trace elements in magmatic systems. Subsequent chapters introduce radiogenic and stable isotope geochemistry and illustrate their application to such diverse topics as determining geologic time, ancient climates, and the diets of prehistoric peoples. The focus then broadens to the formation of the solar system, the Earth, and the elements themselves. Then the composition of the Earth itself becomes the topic, examining the composition of the core, the mantle, and the crust and exploring how this structure originated. A final chapter covers organic chemistry, including the origin of fossil fuels and the carbon cycle’s role in controlling Earth’s climate, both in the geologic past and the rapidly changing present. Geochemistry is essential reading for all earth science students, as well as for researchers and applied scientists who require an introduction to the essential theory of geochemistry, and a survey of its applications in the earth and environmental sciences. Additional resources can be found at: www.wiley.com/go/white/geochemistry
The Encyclopedia is a complete and authoritative reference work for this rapidly evolving field. Over 200 international scientists, each experts in their specialties, have written over 330 separate topics on different aspects of geochemistry including geochemical thermodynamics and kinetics, isotope and organic geochemistry, meteorites and cosmochemistry, the carbon cycle and climate, trace elements, geochemistry of high and low temperature processes, and ore deposition, to name just a few. The geochemical behavior of the elements is described as is the state of the art in analytical geochemistry. Each topic incorporates cross-referencing to related articles, and also has its own reference list to lead the reader to the essential articles within the published literature. The entries are arranged alphabetically, for easy access, and the subject and citation indices are comprehensive and extensive. Geochemistry applies chemical techniques and approaches to understanding the Earth and how it works. It touches upon almost every aspect of earth science, ranging from applied topics such as the search for energy and mineral resources, environmental pollution, and climate change to more basic questions such as the Earth’s origin and composition, the origin and evolution of life, rock weathering and metamorphism, and the pattern of ocean and mantle circulation. Geochemistry allows us to assign absolute ages to events in Earth’s history, to trace the flow of ocean water both now and in the past, trace sediments into subduction zones and arc volcanoes, and trace petroleum to its source rock and ultimately the environment in which it formed. The earliest of evidence of life is chemical and isotopic traces, not fossils, preserved in rocks. Geochemistry has allowed us to unravel the history of the ice ages and thereby deduce their cause. Geochemistry allows us to determine the swings in Earth’s surface temperatures during the ice ages, determine the temperatures and pressures at which rocks have been metamorphosed, and the rates at which ancient magma chambers cooled and crystallized. The field has grown rapidly more sophisticated, in both analytical techniques that can determine elemental concentrations or isotope ratios with exquisite precision and in computational modeling on scales ranging from atomic to planetary.