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Covers the major experimental and theoretical methods currently used to study the energetics of stable molecules and reactive intermediates. Reviews the ate of the art and shows the interplay of experimental and theoretical methods used to probe bonding energetics and reactivity and a wide range of chemical species. A modern and invaluable introduction to the study of molecular energetics. A reference for workers currently involved in the field.
The chemistry of reactive intermediates is central to a modern mechanistic and quantitative understanding of organic chemistry. Moreover, it underlies a significant portion of modern synthetic chemistry and is integral to a molecular view of biological chemistry. Reviews in Reactive Intermediate Chemistry presents an up-to-date, authoritative guide to this fundamental topic. Although it follows Reactive Intermediate Chemistry by the same authors, it serves as a free-standing resource for the entire chemical and biochemical community. The book includes: Relevant, practical applications Coverage of such topics as mass spectrometry methods, reactive intermediates in interstellar medium, quantum mechanical tunnelling, solvent effects, reactive intermediates in biochemical processes, and excited state surfaces Discussions of emerging areas, particularly those involving dynamics and theories Concluding sections identifying key directions for future research are provided at the end of each chapter
Understanding the energy it takes to build or break chemical bonds is essential for scientists and engineers in a wide range of innovative fields, including catalysis, nanomaterials, bioengineering, environmental chemistry, and space science. Reflecting the frequent additions and updates of bond dissociation energy (BDE) data throughout the literat
Environmental Chemistry, Eighth Edition builds on the same organizational structure validated in previous editions tosystematically develop the principles, tools, and techniques of environmental chemistry to provide students and professionals with a clear understanding of the science and its applications. Revised and updated since the publication of the best-selling Seventh Edition, this text continues to emphasize the major concepts essential to the practice of environmental science, technology, and chemistry while introducing the newest innovations to the field. The author provides clear explanations to important concepts such as the anthrosphere, industrial ecosystems, geochemistry, aquatic chemistry, and atmospheric chemistry, including the study of ozone-depleting chlorofluorocarbons. The subject of industrial chemistry and energy resources is supported by pertinent topics in recycling and hazardous waste. Several chapters review environmental biochemistry and toxicology, and the final chapters describe analytical methods for measuring chemical and biological waste. New features in this edition include: enhanced coverage of chemical fate and transport; industrial ecology, particularly how it is integrated with green chemistry; conservation principles and recent accomplishments in sustainable chemical science and technology; a new chapter addressing terrorism and threats to the environment; and the use of real world examples.
With clear explanations, real-world examples and updated ancillary material, the 11th edition of Environmental Chemistry emphasizes the concepts essential to the practice of environmental science, technology and chemistry. The format and organization popular in preceding editions is used, including an approach based upon the five environmental spheres and the relationship of environmental chemistry to the key concepts of sustainability, industrial ecology and green chemistry. The new edition provides a comprehensive view of key environmental issues, and significantly looks at diseases and pandemics as an environmental problem influenced by other environmental concerns like climate change. Features: The most trusted and best-selling text for environmental chemistry has been fully updated and expanded once again The author has preserved the basic format with appropriate updates including a comprehensive overview of key environmental issues and concerns New to this important text is material on the threat of pathogens and disease, deadly past pandemics that killed millions, recently emerged diseases and the prospects for more environment threats related to disease This outstanding legacy appeals to a wide audience and can also be an ideal interdisciplinary book for graduate students with degrees in a variety of disciplines other than chemistry New! Long-awaited companion website featuring additional ancillary material
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The Second Edition features new problems that engage readers in contemporary reactor design Highly praised by instructors, students, and chemical engineers, Introduction to Chemical Engineering Kinetics & Reactor Design has been extensively revised and updated in this Second Edition. The text continues to offer a solid background in chemical reaction kinetics as well as in material and energy balances, preparing readers with the foundation necessary for success in the design of chemical reactors. Moreover, it reflects not only the basic engineering science, but also the mathematical tools used by today’s engineers to solve problems associated with the design of chemical reactors. Introduction to Chemical Engineering Kinetics & Reactor Design enables readers to progressively build their knowledge and skills by applying the laws of conservation of mass and energy to increasingly more difficult challenges in reactor design. The first one-third of the text emphasizes general principles of chemical reaction kinetics, setting the stage for the subsequent treatment of reactors intended to carry out homogeneous reactions, heterogeneous catalytic reactions, and biochemical transformations. Topics include: Thermodynamics of chemical reactions Determination of reaction rate expressions Elements of heterogeneous catalysis Basic concepts in reactor design and ideal reactor models Temperature and energy effects in chemical reactors Basic and applied aspects of biochemical transformations and bioreactors About 70% of the problems in this Second Edition are new. These problems, frequently based on articles culled from the research literature, help readers develop a solid understanding of the material. Many of these new problems also offer readers opportunities to use current software applications such as Mathcad and MATLAB®. By enabling readers to progressively build and apply their knowledge, the Second Edition of Introduction to Chemical Engineering Kinetics & Reactor Design remains a premier text for students in chemical engineering and a valuable resource for practicing engineers.
Reactive Intermediate Chemistry presents a detailed and timely examination of key intermediates central to the mechanisms of numerous organic chemical transformations. Spectroscopy, kinetics, and computational studies are integrated in chapters dealing with the chemistry of carbocations, carbanions, radicals, radical ions, carbenes, nitrenes, arynes, nitrenium ions, diradicals, etc. Nanosecond, picosecond, and femtosecond kinetic realms are explored, and applications of current dynamics and electronic structure calculations are examined. Reactive Intermediate Chemistry provides a deeper understanding of contemporary physical organic chemistry, and will assist chemists in the design of new reactions for the efficient synthesis of pharmaceuticals, fine chemicals, and agricultural products. Among its features, this authoritative volume is: Edited and authored by world-renowned leaders in physical organic chemistry. Ideal for use as a primary or supplemental graduate textbook for courses in mechanistic organic chemistry or physical chemistry. Enhanced by supplemental reading lists and summary overviews in each chapter.
This book describes how chemical reactions take place at the atomic level and how one can calculate the rate of such reactions. The book features a systematic and comprehensive presentation of the subject with a wide range of examples and end-of-chapter problems.