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This concise, elementary treatment illustrates the ways in which an atomic-molecular perspective yields new insights and powers operative in the realms of macroscopic thermodynamics. Starting with an analysis of some very simple microcanonical ensembles, it proceeds to the Boltzmann distribution law and a systematic exploration of the proper formulation, evaluation, and application of partition functions. The concepts of equilibrium and entropy thus acquire new significance, and readers discover how thermodynamic parameters may be calculated from spectroscopic data. Encompassing virtually all of the forms of statistical mechanics customary to undergraduate physical chemistry books, this brief text requires prior acquaintance with only the rudiments of the calculus and a few of the simplest propositions of classical thermodynamics. Appropriate for introductory college chemistry courses, it further lends itself to use as a supplementary text for independent study by more advanced students.
This self-contained primer covers statistical thermodynamics in a rigorous yet approachable manner, making it the perfect text for undergraduates.
Four-part treatment covers principles of quantum statistical mechanics, systems composed of independent molecules or other independent subsystems, and systems of interacting molecules, concluding with a consideration of quantum statistics.
Sufficiently rigorous for introductory or intermediate graduate courses, this text offers a comprehensive treatment of the techniques and limitations of statistical mechanics. 82 figures. 15 tables. 1962 edition.
Clearly connects macroscopic and microscopic thermodynamics and explains non-equilibrium behavior in kinetic theory and chemical kinetics.
The laws of thermodynamics are amongst the most assured and wide-ranging of all scientific laws. They do not pretend to explain any observation in molecular terms but, by showing the necessary relationships between different physical properties, they reduce otherwise disconnected results to compact order, and predict new effects. This classic title, first published in 1957, is a systematic exposition of principles, with examples of applications, especially to changes of places and the conditions for stability. In all this entropy is a key concept.
Statistical Mechanics discusses the fundamental concepts involved in understanding the physical properties of matter in bulk on the basis of the dynamical behavior of its microscopic constituents. The book emphasizes the equilibrium states of physical systems. The text first details the statistical basis of thermodynamics, and then proceeds to discussing the elements of ensemble theory. The next two chapters cover the canonical and grand canonical ensemble. Chapter 5 deals with the formulation of quantum statistics, while Chapter 6 talks about the theory of simple gases. Chapters 7 and 8 examine the ideal Bose and Fermi systems. In the next three chapters, the book covers the statistical mechanics of interacting systems, which includes the method of cluster expansions, pseudopotentials, and quantized fields. Chapter 12 discusses the theory of phase transitions, while Chapter 13 discusses fluctuations. The book will be of great use to researchers and practitioners from wide array of disciplines, such as physics, chemistry, and engineering.
Learn classical thermodynamics alongside statistical mechanics and how macroscopic and microscopic ideas interweave with this fresh approach to the subjects.
This book deals with the basic principles and techniques of nonequilibrium statistical mechanics. The importance of this subject is growing rapidly in view of the advances being made, both experimentally and theoretically, in statistical physics, chemical physics, biological physics, complex systems and several other areas. The presentation of topics is quite self-contained, and the choice of topics enables the student to form a coherent picture of the subject. The approach is unique in that classical mechanical formulation takes center stage. The book is of particular interest to advanced undergraduate and graduate students in engineering departments.