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Published under the asspices of both IUPAC and its affiliated body, the International Association of Chemical Thermodynamics (IACT), this book will serve as a guide to scientists or technicians who use equations of state for fluids. Concentrating on the application of theory, the practical use of each type of equation is discussed and the strengths and weaknesses of each are addressed. It includes material on the equations of state for chemically reacting and non-equilibrium fluids which have undergone significant developments and brings up to date the equations of state for fluids and fluid mixtures. Applied Thermodynamics of Fluids addresses the need of practitioners within academia, government and industry by assembling an international team of distinguished experts to provide each chapter. The topics presented in the book are important to the energy business, particularly the hydroncarbon economy and the development of new power sources and are also significant for the application of liquid crystals and ionic liquids to commericial products. This reference will be useful for post graduate researchers in the fields of chemical engineering, mechanical engineering, chemistry and physics.
Although the basic theories of thermodynamics are adequately covered by a number of existing texts, there is little literature that addresses more advanced topics. In this comprehensive work the author redresses this balance, drawing on his twenty-five years of experience of teaching thermodynamics at undergraduate and postgraduate level, to produce a definitive text to cover thoroughly, advanced syllabuses. The book introduces the basic concepts which apply over the whole range of new technologies, considering: a new approach to cycles, enabling their irreversibility to be taken into account; a detailed study of combustion to show how the chemical energy in a fuel is converted into thermal energy and emissions; an analysis of fuel cells to give an understanding of the direct conversion of chemical energy to electrical power; a detailed study of property relationships to enable more sophisticated analyses to be made of both high and low temperature plant and irreversible thermodynamics, whose principles might hold a key to new ways of efficiently covering energy to power (e.g. solar energy, fuel cells). Worked examples are included in most of the chapters, followed by exercises with solutions. By developing thermodynamics from an explicitly equilibrium perspective, showing how all systems attempt to reach a state of equilibrium, and the effects of these systems when they cannot, the result is an unparalleled insight into the more advanced considerations when converting any form of energy into power, that will prove invaluable to students and professional engineers of all disciplines.
Mechanical Engineering
Modern Engineering Thermodynamics - Textbook with Tables Booklet offers a problem-solving approach to basic and applied engineering thermodynamics, with historical vignettes, critical thinking boxes and case studies throughout to help relate abstract concepts to actual engineering applications. It also contains applications to modern engineering issues. This textbook is designed for use in a standard two-semester engineering thermodynamics course sequence, with the goal of helping students develop engineering problem solving skills through the use of structured problem-solving techniques. The first half of the text contains material suitable for a basic Thermodynamics course taken by engineers from all majors. The second half of the text is suitable for an Applied Thermodynamics course in mechanical engineering programs. The Second Law of Thermodynamics is introduced through a basic entropy concept, providing students a more intuitive understanding of this key course topic. Property Values are discussed before the First Law of Thermodynamics to ensure students have a firm understanding of property data before using them. Over 200 worked examples and more than 1,300 end of chapter problems provide an extensive opportunity to practice solving problems. For greater instructor flexibility at exam time, thermodynamic tables are provided in a separate accompanying booklet. University students in mechanical, chemical, and general engineering taking a thermodynamics course will find this book extremely helpful. Provides the reader with clear presentations of the fundamental principles of basic and applied engineering thermodynamics. Helps students develop engineering problem solving skills through the use of structured problem-solving techniques. Introduces the Second Law of Thermodynamics through a basic entropy concept, providing students a more intuitive understanding of this key course topic. Covers Property Values before the First Law of Thermodynamics to ensure students have a firm understanding of property data before using them. Over 200 worked examples and more than 1,300 end of chapter problems offer students extensive opportunity to practice solving problems. Historical Vignettes, Critical Thinking boxes and Case Studies throughout the book help relate abstract concepts to actual engineering applications. For greater instructor flexibility at exam time, thermodynamic tables are provided in a separate accompanying booklet.
Applied Chemical Engineering Thermodynamics provides the undergraduate and graduate student of chemical engineering with the basic knowledge, the methodology and the references he needs to apply it in industrial practice. Thus, in addition to the classical topics of the laws of thermodynamics,pure component and mixture thermodynamic properties as well as phase and chemical equilibria the reader will find: - history of thermodynamics - energy conservation - internmolecular forces and molecular thermodynamics - cubic equations of state - statistical mechanics. A great number of calculated problems with solutions and an appendix with numerous tables of numbers of practical importance are extremely helpful for applied calculations. The computer programs on the included disk help the student to become familiar with the typical methods used in industry for volumetric and vapor-liquid equilibria calculations.
Revised, updated, and rewritten where necessary, but keeping the clear writing and organizational style that made previous editions so popular, Elements of Environmental Engineering: Thermodynamics and Kinetics, Third Edition contains new problems and new examples that better illustrate theory. The new edition contains examples with practical flavor such as global warming, ozone layer depletion, nanotechnology, green chemistry, and green engineering. With detailed theoretical discussion and principles illuminated by numerical examples, this book fills the gaps in coverage of the principles and applications of kinetics and thermodynamics in environmental engineering and science. New topics covered include: Green Chemistry and Engineering Biological Processes Life Cycle Analysis Global Climate Change The author discusses the applications of thermodynamics and kinetics and delineates the distribution of pollutants and the interrelationships between them. His demonstration of the theoretical foundations of chemical property estimations gives students an in depth understanding of the limitations of thermodynamics and kinetics as applied to environmental fate and transport modeling and separation processes for waste treatment. His treatment of the material underlines the multidisciplinary nature of environmental engineering. This book is unusual in environmental engineering since it deals exclusively with the applications of chemical thermodynamics and kinetics in environmental processes. The book’s multimedia approach to fate and transport modeling and in pollution control design options provides a science and engineering treatment of environmental problems.
The aim of this book is to present Classical Thermodynamics in a unified way, from the most fundamental principles to non-uniform systems, thereby requiring the introduction of coarse graining methods, leading for instance to phase field methods. Solutions thermodynamics and temperature-concentration phase diagrams are covered, plus also a brief introduction to statistical thermodynamics and topological disorder. The Landau theory is included along with a general treatment of multicomponent instabilities in various types of thermodynamic applications, including phase separation and order-disorder transitions. Nucleation theory and spinodal decomposition are presented as extreme cases of a single approach involving the all-important role of fluctuations.In this way, it is hoped that this coverage will reconcile in a unified manner techniques generally presented separately in physics and materials texts.
The laws of thermodynamics are amongst the most assured and wide-ranging of all scientific laws. They do not pretend to explain any observation in molecular terms but, by showing the necessary relationships between different physical properties, they reduce otherwise disconnected results to compact order, and predict new effects. This classic title, first published in 1957, is a systematic exposition of principles, with examples of applications, especially to changes of places and the conditions for stability. In all this entropy is a key concept.