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Volumes 26 and 27 are both concerned with reactions occurring at electrodes arising through the passage of current. They provide a comprehensive review of the study of electrode kinetics. The basic ideas and experimental methodology are presented in Volume 26 whilst Volume 27 deals with reactions at particular types of electrodes.Chapter 1 serves as an introduction to both volumes and is a survey of the fundamental principles of electrode kinetics. Chapter 2 deals with mass transport - how material gets to and from an electrode. Chapter 3 provides a review of linear sweep and cyclic voltammetry which constitutes an extensively used experimental technique in the field. Chapter 4 discusses a.c. and pulse methods which are a rich source of electrochemical information. Finally, chapter 5 discusses the use of electrodes in which there is forced convection, the so-called ``hydrodynamic electrodes''.
Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)
Das führende Werk auf seinem Gebiet - jetzt durchgängig auf den neuesten Stand gebracht! Die theoretischen Grundlagen der Elektrochemie, erweitert um die aktuellsten Erkenntnisse in der Theorie des Elektronentransfers, werden hier ebenso besprochen wie alle wichtigen Anwendungen, darunter modernste Verfahren (Ultramikroelektroden, modifizierte Elektroden, LCEC, Impedanzspektrometrie, neue Varianten der Pulsvoltammetrie und andere). In erster Linie als Lehrbuch gedacht, läßt sich das Werk aber auch hervorragend zum Selbststudium und zur Auffrischung des Wissensstandes verwenden. Lediglich elementare Grundkenntnisse der physikalischen Chemie werden vorausgesetzt.
Rotating Electrode Methods and Oxygen Reduction Electrocatalysts provides the latest information and methodologies of rotating disk electrode and rotating ring-disk electrode (RDE/RRDE) and oxygen reduction reaction (ORR). It is an ideal reference for undergraduate and graduate students, scientists, and engineers who work in the areas of energy, electrochemistry science and technology, fuel cells, and other electrochemical systems. - Presents a comprehensive description, from fundamentals to applications, of catalyzed oxygen reduction reaction and its mechanisms - Portrays a complete description of the RDE (Rotating Disc Electrode)/RRDE (Rotating Ring-Disc Electrode) techniques and their use in evaluating ORR (Oxygen Reduction Reaction) catalysts - Provides working examples along with figures, tables, photos and a comprehensive list of references to help understanding of the principles involved
The new edition of the cornerstone text on electrochemistry Spans all the areas of electrochemistry, from the basicsof thermodynamics and electrode kinetics to transport phenomena inelectrolytes, metals, and semiconductors. Newly updated andexpanded, the Third Edition covers important new treatments, ideas,and technologies while also increasing the book's accessibility forreaders in related fields. Rigorous and complete presentation of the fundamentalconcepts In-depth examples applying the concepts to real-life designproblems Homework problems ranging from the reinforcing to the highlythought-provoking Extensive bibliography giving both the historical developmentof the field and references for the practicing electrochemist.
This comprehensive book describes modern electrochemistry, from fundamental principles to the methods that can be used to study electrode and electrochemical processes, and finally, at the wide-ranging applications in sensors, industry, corrosion, and bioelectrochemistry. The breadth of coverage ensures that this volume will be valuable not only to undergraduate and graduate students, but also to research workers.
Electrochemistry is an old branch of physical chemistry. Due to the development of surface sensitive techniques, and a technological interest in fuel cells and batteries, it has recently undergone a rapid development. This textbook treats the field from a modern, atomistic point of view while integrating the older, macroscopic concepts. The increasing role of theory is reflected in the presentation of the basic ideas in a way that should appeal to experimentalists and theorists alike. Special care is taken to make the subject comprehensible to scientists from neighboring disciplines, especially from surface science. The book is suitable for an advanced course at the master or Ph.D. level, but should also be useful for practicing electrochemists, as well as to any scientist who wants to understand modern electrochemistry.
This book presents a complete overview of the powerful but often misused technique of Electrochemical Impedance Spectroscopy (EIS). The book presents a systematic and complete overview of EIS. The book carefully describes EIS and its application in studies of electrocatalytic reactions and other electrochemical processes of practical interest. This book is directed towards graduate students and researchers in Electrochemistry. Concepts are illustrated through detailed graphics and numerous examples. The book also includes practice problems. Additional materials and solutions are available online.
Fuel Cells and Hydrogen: From Fundamentals to Applied Research provides an overview of the basic principles of fuel cell and hydrogen technology, which subsequently allows the reader to delve more deeply into applied research. In addition to covering the basic principles of fuel cells and hydrogen technologies, the book examines the principles and methods to develop and test fuel cells, the evaluation of the performance and lifetime of fuel cells and the concepts of hydrogen production. Fuel Cells and Hydrogen: From Fundamentals to Applied Research acts as an invaluable reference book for fuel cell developers and students, researchers in industry entering the area of fuel cells and lecturers teaching fuel cells and hydrogen technology. - Includes laboratory methods for fuel cell characterization and manufacture - Outlines approaches in modelling components, cells and stacks - Covers practical and theoretical methods for hydrogen production and storage
Now in full color for a more intuitive learning experience, this new edition of the long-selling reference also features a number of new developments in methodology and the application of enzyme kinetics. Starting with a description of ligand binding equilibria, the experienced author goes on to discuss simple and complex enzyme reactions in kinetic terms. Special cases such as membrane-bound and immobilized enzymes are considered, as is the influence of external conditions, such as temperature and pH value. The final part of the book then covers a range of widely used measurement methods and compares their performance and scope of application. With its unique mix of theory and practical advice, this is an invaluable aid for teaching as well as for experimental work.