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The third volume in a series dedicated to colloids and interfaces, Drops and Bubbles in Contact with Solid Surfaces presents an up-to-date overview of the fundamentals and applications of drops and bubbles and their interaction with solid surfaces. The chapters cover the theoretical and experimental aspects of wetting and wettability, liquid-solid
This book presents a comprehensive overview of fluid mechanical, thermal and physico-chemical aspects of drop-surface interactions. Basic physical mechanisms pertaining to free-surface flow phenomena characteristic of drop impact on solid and liquid surfaces are explained emphasizing the importance of scaling. Moreover, physico-chemical fundamentals relating to a forced spreading of complex solutions, analytical tools for calculating compressibility effects, and heat transfer and phase change phenomena occurring during solidification and evaporation processes, respectively, are introduced in detail. Finally, numerical approaches particularly suited for modeling drop-surface interactions are consisely surveyed with a particular emphasis on boundary integral methods and Navier-Stokes algorithms (volume of fluid, level set and front tracking algorithms). The book is closed by contributions to a workshop on Drop-Surface Interactions held at the International Centre of Mechanical Sciences.
The shape of drops and bubbles is the centre of interest for many interfacial scientists. This book describes the most recent accomplishments to make use of drops and bubbles in fundamental research and application.After a general introduction into the mechanics of liquid menisci, chapters are dedicated to methods based on drops or bubbles. The chapters about the three main drop experiments provide the theoretical basis, a description of experimental set-ups, specific advantages and disadvantages, correction and calibration problems, experimental examples and their interpretation: pendent and sessile drop, drop volume, and spinning drop technique. The chapter about capillary pressure methods summarises different techniques and gives examples of applications, for instance measurements under microgravity.The maximum bubble pressure technique as a particular capillary pressure method is described, with emphasis on the most recent developments which made this technique applicable to extremely short adsorption times, down to the range of milliseconds and less. Problems connected with aerodynamics and hydrodynamics are discussed and used to show the limits of this widely used standard method.The oscillating bubble technique provides information not available by other techniques, for example about the dilational rheology of adsorption layers and relaxation processes at the interface. The description of rising bubbles in surfactant solutions will contain the hydrodynamic basis as well as the theoretical description of the effect of interfacial layers on the movement of bubbles. Besides the theoretical basis experimental data, such as water purification, flotation processes etc. and the relevance for practical applications will be presented. The chapter about lung alveols demonstrates how important bubbles built by biological membranes are in everyday life. The relevance for medicine and biology as well as model studies is discussed.An important example for the application of drops is metallurgy, where the surface tension of metals and alloys is an important parameter for many applications. The chapters on drop shape analysis by using fibre technique and on force measurements between emulsion droplets are of much practical relevance.Lists of references and symbols are given separately at the end of each chapter while a common subject index is given at the end of the book.
Fluid flows that transfer heat and mass often involve drops and bubbles, particularly if there are changes of phase in the fluid in the formation or condensation of steam, for example. Such flows pose problems for the chemical and mechanical engineer significantly different from those posed by single-phase flows. This book reviews the current state of the field and will serve as a reference for researchers, engineers, teachers, and students concerned with transport phenomena. It begins with a review of the basics of fluid flow and a discussion of the shapes and sizes of fluid particles and the factors that determine these. The discussion then turns to flows at low Reynolds numbers, including effects due to phase changes or to large radial inertia. Flows at intermediate and high Reynolds numbers are treated from a numerical perspective, with reference to experimental results. The next chapter considers the effects of solid walls on fluid particles, treating both the statics and dynamics of the particle-wall interaction and the effects of phase changes at a solid wall. This is followed by a discussion of the formation and breakup of drops and bubbles, both with and without phase changes. The last two chapters discuss compound drops and bubbles, primarily in three-phase systems, and special topics, such as transport in an electric field.
This book is the second volume in the series "Contact Angle, Wettability and Adhesion." The premier volume was published in 2013. Even a cursory glance at the literature show that in recent years the interest in understanding and controlling wetting behavior has grown exponentially. Currently, there is tremendous research activity in rendering surfaces superhydrophobic, superhydrophilic, superoleophobic, superoleophilic, omniphobic and omniphilic because of their applications in many technologically important fields. Also the durability or robustness of materials with such super" characteristics is extremely significant, as well as the utilization of "green" (biobased) materials to obtain such surfaces. This book containing 19 articles reflects more recent developments in certain areas covered in its predecessor volume as well as it includes some topics which were not covered before. Concomitantly, this book provides a medium to keep abreast of the latest research activity and developments in the arena of contact angle, wettability and adhesion. The topics discussed include: Understanding of wetting hysteresis; fabrication of superhydrophobic materials; plasma treatment to achieve superhydrophilic surfaces; highly liquid repellent textiles; modification of paper surfaces to control liquid wetting and adhesion; Cheerios effect and its control; engineering materials with superwettability; laser ablation to create micro/nano-patterned surfaces; liquid repellent amorphous carbon nanoparticle networks; mechanical durability of liquid repellent surfaces; wetting of solid walls and spontaneous capillary flow; relationship between roughness and oleophilicity; superhydrophobic and superoleophobic green materials; computational analysis of wetting on hydrophobic surfaces: application to self-cleaning mechanisms; bubble adhesion to superhydrophilic surfaces; surface free energy of superhydrophobic materials; and role of surface free energy in pharmaceutical tablet tensile strength.
Wetting and Spreading Dynamics explains how surface forces acting at the three-phase contact line determine equilibrium, hysteresis contact angles, and other equilibrium and kinetics features of liquids when in contact with solids or with other immiscible liquids. It examines the interaction of surface forces, capillary forces, and properties of the transition zone between the bulk liquid and solid substrate. Significantly revised and updated, the Second Edition features new chapters that cover spreading of non-Newtonian liquids over porous substrates, hysteresis of contact angles on smooth homogeneous substrates, equilibrium and hysteresis contact angles on deformable substrates, and kinetics of simultaneous spreading and evaporation. Drawing together theory and experimental data while presenting over 150 figures to illustrate the concepts, Wetting and Spreading Dynamics, Second Edition is a valuable resource written for both newcomers and experienced researchers.
Liquid-Vapor Phase-Change Phenomena presents the basic thermophysics and transport principles that underlie the mechanisms of condensation and vaporization processes. The text has been thoroughly updated to reflect recent innovations in research and to strengthen the fundamental focus of the first edition. Starting with an integrated presentation of the nonequilibrium thermodynamics and interfacial phenomena associated with vaporization and condensation, coverage follows of the heat transfer and fluid flow mechanisms in such processes. The second edition includes significant new material on the nanoscale and microscale thermophysics of boiling and condensation phenomena and the use of advanced computational tools to create new models of phase-change events. The importance of basic phenomena to a wide variety of applications is emphasized and illustrated throughout using examples and problems. Suitable for senior undergraduate and first-year graduate students in mechanical or chemical engineering, the book can also be a helpful reference for practicing engineers or scientists studying the fundamental physics of nucleation, boiling and condensation.
This book presents a comprehensive overview of fluid mechanical, thermal and physico-chemical aspects of drop-surface interactions. Basic physical mechanisms pertaining to free-surface flow phenomena characteristic of drop impact on solid and liquid surfaces are explained emphasizing the importance of scaling. Moreover, physico-chemical fundamentals relating to a forced spreading of complex solutions, analytical tools for calculating compressibility effects, and heat transfer and phase change phenomena occurring during solidification and evaporation processes, respectively, are introduced in detail. Finally, numerical approaches particularly suited for modeling drop-surface interactions are consisely surveyed with a particular emphasis on boundary integral methods and Navier-Stokes algorithms (volume of fluid, level set and front tracking algorithms). The book is closed by contributions to a workshop on Drop-Surface Interactions held at the International Centre of Mechanical Sciences.
This systematic introduction to the topic includes theoretical concepts to help readers understand and predict surface forces, while also integrating experimental techniques and practical applications with up-to-date examples plus motivating exercises. Starting with intermolecular forces, the authors discuss different surfaces forces, with a major part devoted to surface forces between solid surfaces in liquid media. In addition, they cover surface forces between liquid-vapor interfaces and between liquid-liquid interfaces.
Rev. ed. of: Surface chemistry of froth flotation / Jan Leja. c1982.