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Instantaneous amounts of organic carbon, both particulate and dissolved, in a number of freshwaters ranging from unproductive tarns to moderately productive reservoirs were measured by acid-persulfate digestion and infrared absorption. Organic carbon was designated as net seston carbon, filter seston carbon, or dissolved carbon based on filtering techniques. Repeated sampling showed amounts of organic carbon, either dissolved or particulate, fluctuated considerably over short periods of time; the dissolved fraction probably varying less than particulate forms. Almost daily measurements in samples incubated over three week periods also revealed erratic changes, with no clear reduction in total organic carbon. The data have descriptive value, although they cannot, at this time, be related satisfactorily to the general limnological knowledge.
This book is written as a reference on organic substances in natural waters and as a supplementary text for graduate students in water chemistry. The chapters address five topics: amount, origin, nature, geochemistry, and characterization of organic carbon. Of these topics, the main themes are the amount and nature of dissolved organic carbon in natural waters (mainly fresh water, although seawater is briefly discussed). It is hoped that the reader is familiar with organic chemistry, but it is not necessary. The first part of the book is a general overview of the amount and general nature of dissolved organic carbon. Over the past 10 years there has been an exponential increase in knowledge on organic substances in water, which is the result of money directed toward the research of organic compounds, of new methods of analysis (such as gas chromatography and mass spectrometry), and most importantly, the result of more people working in this field. Because of this exponential increase in knowledge, there is a need to pull together and summarize the data that has accumulated from many disciplines over the last decade.
Humic substances occur in all kinds of aquatic systems, but are particularly important in northern, coniferous areas. They strongly modify the aquatic ecosystems and also constitute a major problem in the drinking water supply. This volume covers all aspects of aquatic humic substances, from their origin and chemical properties, their effects on light and nutrient regimes and biogeochemical cycling, to their role regarding organisms, productivity and food web organization from bacteria to fish. Special emphasis is paid to carbon cycling and food web organization in humic lakes, but aspects of marine carbon cycling related to humus are treated as well.