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This book brings together an emerging consensus on our understanding of the complex functional materials including ferroics, perovskites, multiferroics, CMR and high-temperature superconductors. The common theme is the existence of many competing ground states and frustration as a collusion of spin, charge, orbital and lattice degrees of freedom in the presence of disorder and (both dipolar and elastic) long-range forces. An important consequence of the complex unit cell and the competing interactions is that the emergent materials properties are very sensitive to external fields thus rendering these materials with highly desirable, technologically important applications enabled by cross-response.
This book provides the state-of-the art of the present understanding of avalanche phenomena in both functional materials and geophysics. The main emphasis of the book is analyzing these apparently different problems within the common perspective of out-of-equilibrium phenomena displaying spatial and temporal complexity that occur in a broad range of scales. Many systems, when subjected to an external force, respond intermittently in the form of avalanches that often span over a wide range of sizes, energies and durations. This is often related to a class of critical behavior characterized by the absence of characteristic scales. Typical examples are magnetization processes, plastic deformation and failure occuring in functional materials. These phenomena share many similarities with seismicity arising from the earth crust failure due to stresses that originate from plate tectonics.
A highly coveted objective of modern materials science is to optimize multiple coupled functionalities in the same single phase material and control the cross-response via multiple external fields. One important example of such multi-functionality are multiferroic materials where two or more ferroic properties are intrinsically coupled. They include, among others, the magneto-electric and magneto-structural materials, which are well understood at the nano- and continuum length (and time) scales. The next emerging frontier is to connect these two limiting scales by probing the mesoscale physics of these materials. This book not only attempts to provide this connection but also presents the state-of-the art of the present understanding and potential applications of many related complex multifunctional materials. The main emphasis is on the multiscale bridging of their properties with the aim to discover novel properties and applications in the context of materials by design. This interdisciplinary book serves both graduate students and expert researchers alike.
This book provides a comprehensive introduction to ferroics and frustrated materials. Ferroics comprise a range of materials classes with functionalities such as magnetism, polarization, and orbital degrees of freedom and strain. Frustration, due to geometrical constraints, and disorder, due to chemical and/or structural inhomogeneities, can lead to glassy behavior, which has either been directly observed or inferred in a range of materials classes from model systems such as artificial spin ice, shape memory alloys, and ferroelectrics to electronically functional materials such as manganites. Interesting and unusual properties are found to be associated with these glasses and have potential for novel applications. Just as in prototypical spin glass and structural glasses, the elements of frustration and disorder lead to non-ergodocity, history dependence, frequency dependent relaxation behavior, and the presence of inhomogeneous nano clusters or domains. In addition, there are new states of matter, such as spin ice; however, it is still an open question as to whether these systems belong to the same family or universality class. The purpose of this work is to collect in a single volume the range of materials systems with differing functionalities that show many of the common characteristics of geometrical frustration, where interacting degrees of freedom do not fit in a lattice or medium, and glassy behavior is accompanied by additional presence of disorder. The chapters are written by experts in their fields and span experiment and theory, as well as simulations. Frustrated Materials and Ferroic Glasses will be of interest to a wide range of readers in condensed matter physics and materials science.
This comprehensive handbook and ready reference details all the main achievements in the field of perovskite-based and related mixed-oxide materials. The authors discuss, in an unbiased manner, the potentials as well as the challenges related to their use, thus offering new perspectives for research and development on both an academic and industrial level. The first volume begins by summarizing the different synthesis routes from molten salts at high temperatures to colloidal crystal template methods, before going on to focus on the physical properties of the resulting materials and their related applications in the fields of electronics, energy harvesting, and storage as well as electromechanics and superconductivity. The second volume is dedicated to the catalytic applications of perovskites and related mixed oxides, including, but not limited to total oxidation of hydrocarbons, dry reforming of methane and denitrogenation. The concluding section deals with the development of chemical reactors and novel perovskite-based applications, such as fuel cells and high-performance ceramic membranes. Throughout, the contributions clearly point out the intimate links between structure, properties and applications of these materials, making this an invaluable tool for materials scientists and for catalytic and physical chemists.
Functional oxides are used both as insulators and metallic conductors in key applications across all industrial sectors. This makes them attractive candidates in modern technology ? they make solar cells cheaper, computers more efficient and medical instrumentation more sensitive. Based on recent research, experts in the field describe novel materials, their properties and applications for energy systems, semiconductors, electronics, catalysts and thin films. This monograph is divided into 6 parts which allows the reader to find their topic of interest quickly and efficiently. * Magnetic Oxides * Dopants, Defects and Ferromagnetism in Metal Oxides * Ferroelectrics * Multiferroics * Interfaces and Magnetism * Devices and Applications This book is a valuable asset to materials scientists, solid state chemists, solid state physicists, as well as engineers in the electric and automotive industries.
Magnetism and Structure in Functional Materials addresses three distinct but related topics: (i) magnetoelastic materials such as magnetic martensites and magnetic shape memory alloys, (ii) the magnetocaloric effect related to magnetostructural transitions, and (iii) colossal magnetoresistance (CMR) and related manganites. The goal is to identify common underlying principles in these classes of materials that are relevant for optimizing various functionalities. The emergence of apparently different magnetic/structural phenomena in disparate classes of materials clearly points to a need for common concepts in order to achieve a broader understanding of the interplay between magnetism and structure in this general class of new functional materials exhibiting ever more complex microstructure and function. The topic is interdisciplinary in nature and the contributors correspondingly include physicists, materials scientists and engineers. Likewise the book will appeal to scientists from all these areas.
A structure is an assembly that serves an engineering function. A smart structure is one that serves this function smartly, i.e. by responding adaptively in a pre-designed useful and efficient manner to changing environmental conditions. Adaptive behaviour of one or more materials constituting a smart structure requires nonlinear response. This book describes the three main types of nonlinear-response materials: ferroic materials, soft materials, and nanostructured materials. Information processing by biological and artificial smart structures is also discussed. A smart structure typically has sensors, actuators, and a control system. Progress in all these aspects of smart structures has leant heavily on mimicking Nature, and the all-important notion in this context has been that of evolution. Artificial Darwinian and Lamarckian evolution holds the key to the development of truly smart structures. Modestly intelligent robots are already on the horizon. Projections about the low-cost availability of adequate computing power and memory size indicate that the future really belongs to smart structures. This book covers in a compact format the entire gamut of concepts relevant to smart structures. It should be of interest to a wide range of students and professionals in science and engineering.
Even before it was identified as a science and given a name, nanotechnology was the province of the most innovative inventors. In medieval times, craftsmen, ingeniously employing nanometer-sized gold particles, created the enchanting red hues found in the gold ruby glass of cathedral windows. Today, nanomaterials are being just as creatively used to improve old products, as well as usher in new ones. From tires to CRTs to sunscreens, nanomaterials are becoming a part of every industry. The Nanomaterials Handbook provides a comprehensive overview of the current state of nanomaterials. Employing terminology familiar to materials scientists and engineers, it provides an introduction that delves into the unique nature of nanomaterials. Looking at the quantum effects that come into play and other characteristics realized at the nano level, it explains how the properties displayed by nanomaterials can differ from those displayed by single crystals and conventional microstructured, monolithic, or composite materials. The introduction is followed by an in-depth investigation of carbon-based nanomaterials, which are as important to nanotechnology as silicon is to electronics. However, it goes beyond the usual discussion of nanotubes and nanofibers to consider graphite whiskers, cones and polyhedral crystals, and nanocrystalline diamonds. It also provides significant new information with regard to nanostructured semiconductors, ceramics, metals, biomaterials, and polymers, as well as nanotechnology’s application in drug delivery systems, bioimplants, and field-emission displays. The Nanomaterials Handbook is edited by world-renowned nanomaterials scientist Yury Gogotsi, who has recruited his fellow-pioneers from academia, national laboratories, and industry, to provide coverage of the latest material developments in America, Asia, Europe, and Australia.