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PHREEQC version 3 is a computer program written in the C and C++ programming languages that is designed to perform a wide variety of aqueous geochemical calculations. PHREEQC implements several types of aqueous models: two ion-association aqueous models (the Lawrence Livermore National Laboratory model and WATEQ4F), a Pitzer specific-ion-interaction aqueous model, and the SIT (Specific ion Interaction Theory) aqueous model. Using any of these aqueous models, PHREEQC has capabilities for (1) speciation and saturation-index calculations; (2) batch-reaction and one-dimensional (1D) transport calculations with reversible and irreversible reactions, which include aqueous, mineral, gas, solid-solution, surface-complexation, and ion-exchange equilibria, and specified mole transfers of reactants, kinetically controlled reactions, mixing of solutions, and pressure and temperature changes; and (3) inverse modeling, which finds sets of mineral and gas mole transfers that account for differences in composition between waters within specified compositional uncertainty limits.
An indispensable primer and reference textbook, the third edition of Geochemical and Biogeochemical Reaction Modeling carries the reader from the field's origins and theoretical underpinnings through to a collection of fully worked examples. A clear exposition of the underlying equations and calculation techniques is balanced by real-world example calculations. The book depicts geochemical reaction modeling as a vibrant field of study applicable to a wide spectrum of issues of scientific, practical, and societal concern. The new edition offers a thorough description of surface complexation modeling, including two- and three-layer methods; broader treatment of kinetic rate laws; the effect of stagnant zones on transport; and techniques for determining gas partial pressures. This handbook demystifies and makes broadly accessible an elegant technique for portraying chemical processes in the geosphere. It will again prove to be invaluable for geochemists, environmental scientists and engineers, aqueous and surface chemists, microbiologists, university teachers, and government regulators.
The single most important factor for the successful application of a geochemical model is the knowledge and experience of the individual(s) conducting the modeling. Geochemical Modeling for Mine Site Characterization and Remediation is the fourth of six volumes in the Management Technologies for Metal Mining Influenced Water series about technologies for management of metal mine and metallurgical process drainage. This handbook describes the important components of hydrogeochemical modeling for mine environments, primarily those mines where sulfide minerals are present—metal mines and coal mines. It provides general guidelines on the strengths and limitations of geochemical modeling and an overview of its application to the hydrogeochemistry of both unmined mineralized sites and those contaminated from mineral extraction and mineral processing. The handbook includes an overview of the models behind the codes, explains vital geochemical computations, describes several modeling processes, provides a compilation of codes, and gives examples of their application, including both successes and failures. Hydrologic modeling is also included because mining contaminants most often migrate by surface water and groundwater transport, and contaminant concentrations are a function of water residence time as well as pathways. This is an indispensable resource for mine planners and engineers, environmental managers, land managers, consultants, researchers, government regulators, nongovernmental organizations, students, stakeholders, and anyone with an interest in mining influenced water. The other handbooks in the series are Basics of Metal Mining Influenced Water; Mitigation of Metal Mining Influenced Water; Mine Pit Lakes: Characteristics, Predictive Modeling, and Sustainability; Techniques for Predicting Metal Mining Influenced Water; and Sampling and Monitoring for the Mine Life Cycle.
An excellent one-volume resource for understanding the most important current issues in the research and advances in materials science for environmental and energy technologies This proceedings volume contains a collection of 20 papers from the 2016 Materials Science and Technology (MS&T'16) meeting held in Salt Lake City, UT, from October 24-27 of that year. These conference symposia provided a forum for scientists, engineers, and technologists to discuss and exchange state-of-the-art ideas, information, and technology on advanced methods and approaches for processing, synthesis, characterization, and applications of ceramics, glasses, and composites. Topics covered include: the 8th International Symposium on Green and Sustainable Technologies for Materials Manufacturing Processing; Materials Issues in Nuclear Waste Management in the 21st Century; Construction and Building Materials for a Better Environment; Materials for Nuclear Applications and Extreme Environments; Nanotechnology for Energy, Healthcare, and Industry; and Materials for Processes for CO2 Capture, Conversion and Sequestration. Logically organized and carefully selected articles give insight into advances in materials science for environmental and energy technologies. Incorporates the latest developments related to advances in materials science for environmental and energy technologies Advances in Materials Science for Environmental and Energy Technologies VI: Ceramic Transactions Volume 262 is ideal for academics in mechanical and chemical engineering, materials and or ceramics, chemistry departments and for those working in government laboratories.
Emerging Technologies for Sustainable Desalination Handbook provides professionals and researchers with the latest treatment activities in the advancement of desalination technology. The book enables municipalities and private companies to custom-design sustainable desalination plants that will minimize discharge, energy costs and environmental footprint. Individual case studies are included to illustrate the benefits and drawback of each technique. Sections discuss a multitude of recently developed, advanced processes, along with notable advances made in existing technologies. These processes include adsorption, forward osmosis, humidification and dehumidification, membrane distillation, pervaporation and spray type thermal processes. In addition, theoretical membrane materials, such as nanocomposite and carbon nanotube membranes are also explored. Other chapters cover the desalination of shale gas, produced water, forward osmosis for agriculture, desalination for crop irrigation, and seawater for sustainable agriculture. International in its coverage, the chapters of this handbook are contributed by leading authors and researchers in all relevant fields. - Expertly explains recent advances in sustainable desalination technology, including nanocomposite membranes, carbon nanotube membranes, forward reverse osmosis and desalination by pervaporation - Provides state-of-the-art techniques for minimizing system discharge, energy cost and environmental footprint - Includes individual case studies to illustrate the benefits and drawbacks of each technique - Discusses techniques for the custom-design of sustainable desalination plants for municipalities, private companies and industrial operations
This book gives background information why shale formations in the world are important both for storage capacity and enhanced gas recovery (EGR). Part of this book investigates the sequestration capacity in geological formations and the mechanisms for the enhanced storage rate of CO2 in an underlying saline aquifer. The growing concern about global warming has increased interest in geological storage of carbon dioxide (CO2). The main mechanism of the enhancement, viz., the occurrence of gravity fingers, which are the vehicles of enhanced transport in saline aquifers, can be visualized using the Schlieren technique. In addition high pressure experiments confirmed that the storage rate is indeed enhanced in porous media. The book is appropriate for graduate students, researchers and advanced professionals in petroleum and chemical engineering. It provides the interested reader with in-depth insights into the possibilities and challenges of CO2 storage and the EGR prospect.
Electrokinetic Remediation for Environmental Security and Sustainability Explore this comprehensive reference on the remediation of contaminated substrates, filled with cutting-edge research and practical case studies Electrokinetic Remediation for Environmental Security and Sustainability delivers a thorough review of electrokinetic remediation (EKR) for the treatment of inorganic and organic contaminants in contaminated substrates. The book highlights recent progress and developments in EKR in the areas of resource recovery, the removal of pollutants, and environmental remediation. It also discusses the use of EKR in conjunction with nanotechnology and phytoremediation. Throughout the book, case studies are presented that involve the field implementation of EKR technologies. The book also includes discussions of enhanced electrokinetic remediation of dredged co-contaminated sediments, solar-powered bioelectrokinetics for the mitigation of contaminated agricultural soil, advanced electro-fenton for remediation of organics, electrokinetic remediation for PPCPs in contaminated substrates, and the electrokinetic remediation of agrochemicals such as organochlorine compounds. Other topics include: A thorough introduction to the modelling of electrokinetic remediation An exploration of the electrokinetic recovery of tungsten and removal of arsenic from mining secondary resources An analysis of pharmaceutically active compounds in wastewater treatment plants with a discussion of electrochemical advanced oxidation as an on-site treatment A review of rare earth elements, including general concepts and recovery techniques, like electrodialytic extraction A treatment of hydrocarbon-contaminated soil in cold climate conditions Perfect for environmental engineers and scientists, geologists, chemical engineers, biochemical engineers, and scientists working with green technology, Electrokinetic Remediation for Environmental Security and Sustainability will also earn a place in the libraries of academic and industry researchers, engineers, regulators, and policy makers with an interest in the remediation of contaminated natural resources.
Metallurgical slags are generated as a by-product of smelting during ironmaking, steelmaking, and the production of ferroalloys and non-ferrous metals. The formation conditions result in complex chemical and mineralogical characteristics unique to slags alone. Historically slags have been discarded as a waste product and, through release of potentially toxic trace elements, represent a hazard to the environment and human health. However, increasingly we are realizing the resource potential of what was previously thought of as waste, thus reducing the environmental impact and taking a step closer to a circular economy. This book is a definitive reference on the environmental geochemistry and resource potential of metallurgical slags by summarizing processes for the generation of slags, describing their chemical and mineralogical characteristics, outlining the fundamental geochemistry that propels slag weathering, and illustrating the utilization of slags. Particular attention is given to the value of slags in modern society as they are widely used as construction materials in civil engineering, and as an irreplaceable filter in sequestering excess nutrients, pathogens, metal and/or organic contaminants, and even greenhouse gases. The latest developments on recovering residual valuable metals in slags, including new techniques for extracting by-product elements needed for green and frontier technologies, are revealed. This book is essential reading for environmental geochemists, geologists, metallurgists, mining and civil engineers, waste and resource managers, and all those interested and inspired by a circular economy and minimizing our environmental footprint on planet Earth.