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Offering a comprehensive narrative of the early history of stereochemistry, Dr Ramberg explores the reasons for and the consequences of the fundamental change in the meaning of chemical formulas with the emergence of stereochemistry during the last quarter of the nineteenth century. As yet relatively unexplored by historians, the development of stereochemistry - the study of the three-dimensional properties of molecules - provides a superb case study for exploring the meaning and purpose of chemical formulas, as it entailed a significant change in the meaning of chemical formulas from the purely chemical conception of 'structure' to the physico-chemical conception of molecules provided by the tetrahedral carbon atom. This study is the first to treat the emergence of the unique visual language of organic chemistry between 1830 and 1874 to place in context the near simultaneous proposal of the tetrahedral carbon atom by J.H. van 't Hoff and J.A. Le Bel in 1874. Dr Ramberg then examines the research programs in stereochemistry by Johannes Wislicenus, Arthur Hantzsch, Victor Meyer, Carl Bischoff, Emil Fischer and Alfred Werner, showing how the emergence of stereochemistry was a logical continuation of established research traditions in chemistry. In so doing, he also illustrates the novel and controversial characteristics of stereochemical ideas, especially the unprecedented use of mechanistic and dynamic principles in chemical explanation.
Offering a comprehensive narrative of the early history of stereochemistry, Dr Ramberg explores the reasons for and the consequences of the fundamental change in the meaning of chemical formulas with the emergence of stereochemistry during the last quarter of the nineteenth century. As yet relatively unexplored by historians, the development of stereochemistry - the study of the three-dimensional properties of molecules - provides a superb case study for exploring the meaning and purpose of chemical formulas, as it entailed a significant change in the meaning of chemical formulas from the purely chemical conception of 'structure' to the physico-chemical conception of molecules provided by the tetrahedral carbon atom. This study is the first to treat the emergence of the unique visual language of organic chemistry between 1830 and 1874 to place in context the near simultaneous proposal of the tetrahedral carbon atom by J.H. van 't Hoff and J.A. Le Bel in 1874. Dr Ramberg then examines the research programs in stereochemistry by Johannes Wislicenus, Arthur Hantzsch, Victor Meyer, Carl Bischoff, Emil Fischer and Alfred Werner, showing how the emergence of stereochemistry was a logical continuation of established research traditions in chemistry. In so doing, he also illustrates the novel and controversial characteristics of stereochemical ideas, especially the unprecedented use of mechanistic and dynamic principles in chemical explanation.
Philosophical Chemistry furthers Manuel DeLanda's revolutionary intervention in the philosophy of science and science studies. Against a monadic and totalizing understanding of science, DeLanda's historicizing investigation traces the centrality of divergence, specialization and hybridization through the fields and subfields of chemistry. The strategy followed uses a series of chemical textbooks, separated from each other by fifty year periods (1750, 1800, 1850, and 1900), to follow the historical formation of consensus practices. The three chapters deal with one subfield of chemistry in the century in which it was developed: eighteenth-century inorganic chemistry, nineteenth-century organic chemistry, and nineteenth-century physical chemistry. This book creates a model of a scientific field capable of accommodating the variation and differentiation evident in the history of scientific practice. DeLanda proposes a model that is made of three components: a domain of phenomena, a community of practitioners, and a set of instruments and techniques connecting the community to the domain. Philosophical Chemistry will be essential reading for those engaged in emergent, radical and contemporary strands of thought in the philosophy of science and for those scholars and students who strive to practice a productive dialogue between the two disciplines.
From the Atom to Living Systems represents an original historico-epistemological approach to follow the passage, in the microscopic analysis of reality, from the atomic to the molecular to the macromolecular levels and then to the threshold of life itself. Naturally, some parts of this journey have been developed in other works, some highly specialized and others of a more general nature. However, although this journey has often been traced in specialized scientific detail, the philosophical implications of the journey have not been discussed to any satisfactory degree. This scientific journey does have important philosophical consequences that constitute an integral part of this book, which is framed within the perspective of systems science and the so-called sciences of complexity, which are areas fundamental to 21st century science. In fact, the possibility of studying and understanding the material world through levels of complexity opens a great philosophical space that proposes to provide systemic and complex explanations, rather than reductive accounts that pretend to explain all phenomena through the interactions of elementary particles while considering all phenomena implicit and deterministic. The systemic and complex approach implies substituting unique bottom-up explanations, which move exclusively from the microscopically simple to the macroscopically complex, with a series of explanations that are horizontal within planes of complexity, vertically bottom up between various levels of complexity, vertically top-down, as well as circular in a manner that renders all levels of reality and the disciplines that study them as both autonomous and interconnected.
Today modern materials science is a vibrant, emerging scientific discipline at the forefront of physics, chemistry, engineering, biology and medicine, and is becoming increasingly international in scope as demonstrated by emerging international and intercontinental collaborations and exchanges. The overall purpose of this book is to provide timely and in-depth coverage of selected advanced topics in materials science. Divided into five sections, this book provides the latest research developments in many aspects of materials science. This book is of interest to both fundamental research and also to practicing scientists and will prove invaluable to all chemical engineers, industrial chemists and students in industry and academia.
When the German chemist Emil Fischer presented his lock-and-key hypothesis in 1899, his analogy to describe the molecular relationship between enzymes and substrates quickly gained vast influence and provided future generations of scientists with a tool to investigate the relation between chemical structure and biological specificity. Rebecca Mertens explains the appeal of the lock-and-key analogy by its role in model building and in the construction of long-term, cross-generational research programs. She argues that a crucial feature of these research programs, namely ascertaining the continuity of core ideas and concepts, is provided by a certain way of analogy-based modelling.
Drawing on alchemical theory, Édouard Laugier and Auguste Laurent set out to find the vital essence of life through the craft of perfumes. While drawing the ire of enlightened Bohemian Paris, they discovered fundamental differences in the structures of naturally occurring and synthetic molecules, inaugurating a persistent scientific mystery.
Molecular structure is something taken for granted by chemists. Together with elements, atoms and bonds, it is the basis for talking about organic chemistry. Given molecular structure, chemists are engaged in designing molecules and performing chemical syntheses of a variety of compounds. The structure-activity relationship in drug research is an illuminating example. However, of course, nobody has ever seen molecular structure. Molecules are too small to see. Moreover, molecular structure cannot be derived a priori from fundamental principles of quantum mechanics. This book explores why this is the case. Is what chemists take to be molecular structure real? This book addresses head-on the ontological, as well as epistemological, grounds of one of the most fundamental concepts of chemistry. Its arguments are grounded on the learning of the history of chemistry, philosophy (Kant in particular), quantum mechanics and organic chemistry. The book will serve as a good introduction to the philosophy of chemistry.
Edited by world-famous pioneers in chemoinformatics, this is a clearly structured and applications-oriented approach to the topic, providing up-to-date and focused information on the wide range of applications in this exciting field. The authors explain methods and software tools, such that the reader will not only learn the basics but also how to use the different software packages available. Experts describe applications in such different fields as structure-spectra correlations, virtual screening, prediction of active sites, library design, the prediction of the properties of chemicals, the development of new cosmetics products, quality control in food, the design of new materials with improved properties, toxicity modeling, assessment of the risk of chemicals, and the control of chemical processes. The book is aimed at advanced students as well as lectures but also at scientists that want to learn how chemoinformatics could assist them in solving their daily scientific tasks. Together with the corresponding textbook Chemoinformatics - Basic Concepts and Methods (ISBN 9783527331093) on the fundamentals of chemoinformatics readers will have a comprehensive overview of the field.
Presents a history of chemistry, providing definitions and explanations of related topics, plus brief biographies of scientists of the 20th century.