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Here is the most comprehensive and up-to-date treatment of one of the hottest areas of chemical research. The treatment of fundamental kinetics and photochemistry will be highly useful to chemistry students and their instructors at the graduate level, as well as postdoctoral fellows entering this new, exciting, and well-funded field with a Ph.D. in a related discipline (e.g., analytical, organic, or physical chemistry, chemical physics, etc.). Chemistry of the Upper and Lower Atmosphere provides postgraduate researchers and teachers with a uniquely detailed, comprehensive, and authoritative resource. The text bridges the "gap" between the fundamental chemistry of the earth's atmosphere and "real world" examples of its application to the development of sound scientific risk assessments and associated risk management control strategies for both tropospheric and stratospheric pollutants. - Serves as a graduate textbook and "must have" reference for all atmospheric scientists - Provides more than 5000 references to the literature through the end of 1998 - Presents tables of new actinic flux data for the troposphere and stratospher (0-40km) - Summarizes kinetic and photochemical date for the troposphere and stratosphere - Features problems at the end of most chapters to enhance the book's use in teaching - Includes applications of the OZIPR box model with comprehensive chemistry for student use
Mathematical modeling of atmospheric composition is a formidable scientific and computational challenge. This comprehensive presentation of the modeling methods used in atmospheric chemistry focuses on both theory and practice, from the fundamental principles behind models, through to their applications in interpreting observations. An encyclopaedic coverage of methods used in atmospheric modeling, including their advantages and disadvantages, makes this a one-stop resource with a large scope. Particular emphasis is given to the mathematical formulation of chemical, radiative, and aerosol processes; advection and turbulent transport; emission and deposition processes; as well as major chapters on model evaluation and inverse modeling. The modeling of atmospheric chemistry is an intrinsically interdisciplinary endeavour, bringing together meteorology, radiative transfer, physical chemistry and biogeochemistry, making the book of value to a broad readership. Introductory chapters and a review of the relevant mathematics make this book instantly accessible to graduate students and researchers in the atmospheric sciences.
This volume reviews all aspects of Mars atmospheric science from the surface to space, and from now and into the past.
A set of individual data sheets for gas phase chemical reactions and photochemistry of neutral species is presented. These data sheets give preferred values for reaction rate constants, photoabsorption cross sections and quantum yields with a brief statement discussing the basis for the preferred value. Recent experimental results are also given. The coverage of this initial set of data sheets issued in February 1980 corresponds to the approximately 400 reactions listed in NBS Special Publication 513, R.F. Hampson and D. Garvin, May 1978. For approximately one quarter of these reactions the data entry has been updated to include the 1979 recommendations of the NASA Panel for Data Evaluation and the CODATA Task Group on Chemical Kinetics. They are intended to provide the basic physical chemical data needed as input data for calculations modeling atmospheric chemistry. Revisions and additions for specific reactions will be published as new information becomes available.
Finishing this book is giving me a mixture of relief, satisfaction and frus tration. Relief, for the completion of a project that has taken too many of my evenings and weekends and that, in the last several months, has become almost an obsession. Satisfaction, for the optimistic feeling that this book, in spite of its many shortcomings and imbalances, will be of some help to the air pollution scientific community. Frustration, for the impossibility of incorporating newly available material that would require another major review of several key chap ters - an effort that is currently beyond my energies but not beyond my desires. The first canovaccio of this book came out in 1980 when I was invited by Computational Mechanics in the United Kingdom to give my first Air Pollution Modeling course. The course material, in the form of transparencies, expanded, year after year, thus providing a growing working basis. In 1985, the ECC Joint Research Center in Ispra, Italy, asked me to prepare a critical survey of mathe matical models of atmospheric pollution, transport and deposition. This support gave me the opportunity to prepare a sort of "first draft" of the book, which I expanded in the following years.
Sulfur in the Atmosphere covers the proceedings of the International Symposium held in Dubrovnik, Yugoslavia on September 7-14, 1977. The text focuses on the processes involved in the transfer of sulfur through the atmospheric environment, particularly noting its distribution in space in gas, liquid, and solid phases. The book first offers information on the properties of sulfur and the processes involved in its determination, as well as measurement methods, chemical transformations, dry and wet deposition, and aerosol dynamics. The publication also looks at water-soluble sulfur compounds in aerosols, chemical properties of tropospheric sulfur aerosols, and sampling and analysis of atmospheric sulfates and related species. The text examines the techniques involved in the identification of chemical composition of aerosol sulfur compounds. Topics include thermal volatilization, thermometric methods, wet chemical identification, and laser Raman spectroscopy. The publication also reviews the calculation of long term sulfur deposition in Europe; transmission of sulfur dioxide on local, regional, and continental scale; and airborne sampling system for the monitoring of plume. The book is a dependable source of data for readers interested in the transfer of sulfur through the atmospheric environment.