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This review volume contains the most up-to-date articles on the chemical aspects of high temperature oxide superconductors. These articles are written by some of the leading scientists in the field and includes a comprehensive list of references. This is an essential volume for researchers working in the fields of ceramics, materials science and chemistry.
The recent discovery of high-temperature superconductivity in copper based oxides is an event of major importance not only with respect to the physical phenomenon itself but also because it definitely shows that solid state chemistry, and especially the crystal chemistry of oxides, has a crucial place in the synthesis and understanding of new materials for future appli cations. The numerous papers published in the field of high Tc supercon ductors in the last five years demonstrate that the great complexity of these materials necessitates a close collaboration between physicists and solid state chemists. This book is based to a large extent on our experience of the crystal chemistry of copper oxides, which we have been studying in the laboratory for more than twelve years, but it also summarizes the main results which have been obtained for these compounds in the last five years relating to their spectacular superconducting properties. We have focused on the struc ture, chemical bonding and nonstoichiometry of these materials, bearing in mind that redox reactions are the key to the optimization of their supercon ducting properties, owing to the importance of the mixed valence of copper and its Jahn-Teller effect. We have also drawn on studies of extended defects by high-resolution electron microscopy and on their creation by ir radiation effects.
The discovery by J. G. Bednorz and K. A. Mtllier in 1986 that the superconducting state can exist in oxides at temperatures above 30 K stimulated research in the field of superconductivity and opened up a new field of research. Within a few years a large number of cuprate superconductors with transition temperatures well above the boiling point of liquid nitrogen have been found. The possibility of using liquid nitrogen as coolant re-stimulated interest in power applications of supercon ductivity. In this book an overview of the known high-Te superconductors and their physical properties is presented. Aspects related to conductor fabrication and high-current applications are emphasised. The material should be suitable for use in graduate level courses on superconductivity. Researchers in the field may profit from the large number of tables and references describing its status at the end of 1997. An introduction to high-To superconductivity must be based on the fundamental physical principles of normal-state electrical conductivity and the well-known characteristics of conventional superconductors. In Chapter 2 this background is provided. Crystal structures, anisotropic properties and general trends of the critical temperatures of the cuprate superconductors are described in Chapters 3 and 4. The processing of superconductor powders addressed in Chapter 5 affects considerably the current-carrying capacity of high-T. wires. In Chapter 6 several fabrication techniques for superconducting wires are described. In addition, the factors limiting the transport critical currents ofhigh-Te wires are discussed.
Prof. CNR Rao is a living legend. Einstein paid a compliment to Mahatma Gandhi on his 70th birthday. He said, “Generations to come, it may well be, will scarce believe that such a man as this one ever in flesh and blood walked upon this earth”. On Prof. Rao’s birthday, I would repeat these words. Prof. Rao is not an individual, he is an institution, he is a phenomenon. I feel lucky that our generations could see him, touch him, feel him, experience him, learn from him and get inspired by him. I have watched Prof. Rao as a scientist, as a science leader, as a science institution builder and indeed as a leader of leaders of science. I have also watched him as a wonderful, warm-hearted human being with abundant empathy. I have seen his childlike enthusiasm. I have watched him as `courage personified’. What follows is more anecdotal but solely based on my personal viewpoint. Professor Rao has had a tremendous influence on my life. He has been my guru, guide, friend and philosopher. I met him for the first time when he was the Chairman of the Research Advisory Council of the National Chemical Laboratory (NCL) in the nineteen eighties. I was then in my late thirties. Professor Rao has an uncanny ability to spot talent among the young. He was the President of the Indian Science Congress in the year 1988, which was held in Pune University. Mr. Rajiv Gandhi was the Prime Minister and he inaugurated the Science Congress. Later on, during the lunch that followed, Prof. Rao made a special point to introduce me to Rajiv Gandhi. I still remember his words. He said, `Mr. Prime Minister, meet a rising young star of Indian science’. Little did I then know that within the next couple of months, he would make me a member of the Science Advisory Council to the Prime Minister, which he was chairing. At 42, I was the youngest member and I remember people calling me the `baby’ of the team. Getting that huge exposure at such a young age was something very special for me – I got a helicopter view of India at large. It helped me enormously as I moved on in life. 'Padma Vibhushan' Dr. Raghunath Anant Mashelkar
Superconductivity in Highly Correlated Fermion Systems documents the proceedings of the Yamada Conference XVIII on Superconductivity in Highly Correlated Fermion Systems held in Sendai, Japan, from August 31 to September 3, 1987. This book compiles selected papers on the experimental and theoretical advances in the study of superconductivity. The topics include the superconductivity and magnetism in heavy-electron materials, magneto-resistance of heavy-fermion compounds, and magnetic fluctuations and order in exotic superconductors. The fabrication and properties of thin superconducting oxide films, bipolaron models of superconductors, superconducting properties of superlattices, and flux quantization on quasi-crystalline networks are also covered. This publication is recommended for physicists and students researching on the superconductivity in highly correlated fermion systems.
Key discoveries concerning the different biological functions of microglia in health and disease have attracted scientists from various fields. In Microglia: Methods and Protocols, expert researchers in the field detail methods for selection of the key cellular, molecular and biochemical techniques that are used in studying the many and varied functions of this fascinating cell. These methods and techniques include microglia cell culture for studying microglia activation and functions, as well as their interaction with other cell types both in vitro and in vivo. Written in the highly successful Methods in Molecular Biology series format, chapters include introductions to their respective topics, lists of the necessary materials and reagents, step-by-step, readily reproducible laboratory protocols, and key tips on troubleshooting and avoiding known pitfalls. Authoritative and practical, Microglia: Methods and Protocols is a useful resource for cell biologists, molecular biologists, immunologists, oncologist and neuroscientists.
Superconductivity, 2E is an encyclopedic treatment of all aspects of the subject, from classic materials to fullerenes. Emphasis is on balanced coverage, with a comprehensive reference list and significant graphicsfrom all areas of the published literature. Widely used theoretical approaches are explained in detail. Topics of special interest include high temperature superconductors, spectroscopy, critical states, transport properties, and tunneling.This book covers the whole field of superconductivity from both the theoretical and the experimental point of view. - Comprehensive coverage of the field of superconductivity - Very up-to date on magnetic properties, fluxons, anisotropies, etc. - Over 2500 references to the literature - Long lists of data on the various types of superconductors