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Explains the current state of the science and points the way to technological advances First developed in the late 1980s, lithium-ion batteries now power everything from tablet computers to power tools to electric cars. Despite tremendous progress in the last two decades in the engineering and manufacturing of lithium-ion batteries, they are currently unable to meet the energy and power demands of many new and emerging devices. This book sets the stage for the development of a new generation of higher-energy density, rechargeable lithium-ion batteries by advancing battery chemistry and identifying new electrode and electrolyte materials. The first chapter of Lithium Batteries sets the foundation for the rest of the book with a brief account of the history of lithium-ion battery development. Next, the book covers such topics as: Advanced organic and ionic liquid electrolytes for battery applications Advanced cathode materials for lithium-ion batteries Metal fluorosulphates capable of doubling the energy density of lithium-ion batteries Efforts to develop lithium-air batteries Alternative anode rechargeable batteries such as magnesium and sodium anode systems Each of the sixteen chapters has been contributed by one or more leading experts in electrochemistry and lithium battery technology. Their contributions are based on the latest published findings as well as their own firsthand laboratory experience. Figures throughout the book help readers understand the concepts underlying the latest efforts to advance the science of batteries and develop new materials. Readers will also find a bibliography at the end of each chapter to facilitate further research into individual topics. Lithium Batteries provides electrochemistry students and researchers with a snapshot of current efforts to improve battery performance as well as the tools needed to advance their own research efforts.
Rechargeable Lithium Batteries: From Fundamentals to Application provides an overview of rechargeable lithium batteries, from fundamental materials, though characterization and modeling, to applications. The market share of lithium ion batteries is fast increasing due to their high energy density and low maintenance requirements. Lithium air batteries have the potential for even higher energy densities, a requirement for the development of electric vehicles, and other types of rechargeable lithium battery are also in development. After an introductory chapter providing an overview of the main scientific and technological challenges posed by rechargeable Li batteries, Part One of this book reviews materials and characterization of rechargeable lithium batteries. Part Two covers performance and applications, discussing essential aspects such as battery management, battery safety and emerging rechargeable lithium battery technologies as well as medical and aerospace applications. - Expert overview of the main scientific and technological challenges posed by rechargeable lithium batteries - Address the important topics of analysis, characterization, and modeling in rechargeable lithium batteries - Key analysis of essential aspects such as battery management, battery safety, and emerging rechargeable lithium battery technologies
This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. The SEI film is due to electromechanical reduction of species present in the electrolyte. It is widely recognized that the presence of the film plays an essential role in the battery performance, and its very nature can determine an extended (or shorter) life for the battery. In spite of the numerous related research efforts, details on the stability of the SEI composition and its influence on the battery capacity are still controversial. This book carefully analyzes and discusses the most recent findings and advances on this topic.
Safety of Lithium Batteries describes how best to assure safety during all phases of the life of Lithium ion batteries (production, transport, use, and disposal). About 5 billion Li-ion cells are produced each year, predominantly for use in consumer electronics. This book describes how the high-energy density and outstanding performance of Li-ion batteries will result in a large increase in the production of Li-ion cells for electric drive train vehicle (xEV) and battery energy storage (BES or EES) purposes. The high-energy density of Li battery systems comes with special hazards related to the materials employed in these systems. The manufacturers of cells and batteries have strongly reduced the hazard probability by a number of measures. However, absolute safety of the Li system is not given as multiple incidents in consumer electronics have shown. - Presents the relationship between chemical and structure material properties and cell safety - Relates cell and battery design to safety as well as system operation parameters to safety - Outlines the influences of abuses on safety and the relationship to battery testing - Explores the limitations for transport and storage of cells and batteries - Includes recycling, disposal and second use of lithium ion batteries
This book provides comprehensive coverage of Lithium (Li) metal anodes for rechargeable batteries. Li is an ideal anode material for rechargeable batteries due to its extremely high theoretical specific capacity (3860 mAh g-1), low density (0.59 g cm-3), and the lowest negative electrochemical potential (−3.040 V vs. standard hydrogenelectrodes). Unfortunately, uncontrollable dendritic Li growth and limited Coulombic efficiency during Li deposition/stripping inherent in these batteries have prevented their practical applications over the past 40 years. With the emergence of post Liion batteries, safe and efficient operation of Li metal anodes has become an enabling technology which may determine the fate of several promising candidates for the next generation energy storage systems, including rechargeable Li-air batteries, Li-S batteries, and Li metal batteries which utilize intercalation compounds as cathodes. In this work, various factors that affect the morphology and Coulombic efficiency of Li anodes are analyzed. The authors also present the technologies utilized to characterize the morphology of Li deposition and the results obtained by modeling of Li dendrite growth. Finally, recent developments, especially the new approaches that enable safe and efficient operation of Li metal anodes at high current densities are reviewed. The urgent need and perspectives in this field are also discussed. The fundamental understanding and approaches presented in this work will be critical for the applicationof Li metal anodes. The general principles and approaches can also be used in other metal electrodes and general electrochemical deposition of metal films.
This book includes the original, peer-reviewed research papers from the 10th Frontier Academic Forum of Electrical Engineering (FAFEE 2022), held in Xi’an, China, in August 2022. It gathers the latest research, innovations, and applications in the fields of Electrical Engineering. The topics it covers include electrical materials and equipment, electrical energy storage and device, power electronics and drives, new energy electric power system equipment, IntelliSense and intelligent equipment, biological electromagnetism and its applications, and insulation and discharge computation for power equipment. Given its scope, the book benefits all researchers, engineers, and graduate students who want to learn about cutting-edge advances in Electrical Engineering.
The authors provide new insights into the theoretical and applied aspects of metal electrodeposition. The theory largely focuses on the electrochemistry of metals. Details on the practice discuss the selection and use of metal coatings, the technology of deposition of metals and alloys, including individual peculiarities, properties and structure of coatings, control and investigations. This book aims to acquaint advanced students and researchers with recent advances in electrodeposition while also being an excellent reference for the practical electrodeposition of metals and alloys.
Battery Management Systems - Design by Modelling describes the design of Battery Management Systems (BMS) with the aid of simulation methods. The basic tasks of BMS are to ensure optimum use of the energy stored in the battery (pack) that powers a portable device and to prevent damage inflicted on the battery (pack). This becomes increasingly important due to the larger power consumption associated with added features to portable devices on the one hand and the demand for longer run times on the other hand. In addition to explaining the general principles of BMS tasks such as charging algorithms and State-of-Charge (SoC) indication methods, the book also covers real-life examples of BMS functionality of practical portable devices such as shavers and cellular phones. Simulations offer the advantage over measurements that less time is needed to gain knowledge of a battery's behaviour in interaction with other parts in a portable device under a wide variety of conditions. This knowledge can be used to improve the design of a BMS, even before a prototype of the portable device has been built. The battery is the central part of a BMS and good simulation models that can be used to improve the BMS design were previously unavailable. Therefore, a large part of the book is devoted to the construction of simulation models for rechargeable batteries. With the aid of several illustrations it is shown that design improvements can indeed be realized with the presented battery models. Examples include an improved charging algorithm that was elaborated in simulations and verified in practice and a new SoC indication system that was developed showing promising results. The contents of Battery Management Systems - Design by Modelling is based on years of research performed at the Philips Research Laboratories. The combination of basic and detailed descriptions of battery behaviour both in chemical and electrical terms makes this book truly multidisciplinary. It can therefore be read both by people with an (electro)chemical and an electrical engineering background.