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The Sixth Edition of a classic in organic chemistry continues its tradition of excellence Now in its sixth edition, March's Advanced Organic Chemistry remains the gold standard in organic chemistry. Throughout its six editions, students and chemists from around the world have relied on it as an essential resource for planning and executing synthetic reactions. The Sixth Edition brings the text completely current with the most recent organic reactions. In addition, the references have been updated to enable readers to find the latest primary and review literature with ease. New features include: More than 25,000 references to the literature to facilitate further research Revised mechanisms, where required, that explain concepts in clear modern terms Revisions and updates to each chapter to bring them all fully up to date with the latest reactions and discoveries A revised Appendix B to facilitate correlating chapter sections with synthetic transformations
The physics of atomic inner shells has undergone significant advances in recent years. Fast computers and new experimental tools, notably syn chrotron-radiation sources and heavy-ion accelerators, have greatly enhan ced the scope of problems that are accessible. The level of research activity is growing substantially; added incentives are provided by the importance of inner-shell processes in such diverse areas as plasma studies, astrophysics, laser technology, biology, medicine, and materials science. The main reason for all this exciting activity in atomic inner-shell physics, to be sure, lies in the significance of the fundamental problems that are coming within grasp. The large energies of many inner-shell processes cause relativistic and quantum-electrodynamic effects to become strong. Unique opportunities exist for delicate tests of such phenomena as the screening of the electron self-energy and the limits of validity of the present form of the frequency-dependent Breit interaction, to name but two. The many-body problem, which pervades virtually all of physics, presents somewhat less intractable aspects in the atomic inner-shell regime: correlations are relatively weak so that they can be treated perturbatively, and the basic potential is simple and known! The dynamics of inner-shell processes are characterized by exceedingly short lifetimes and high transition rates that strain perturbation theory to its limits and obliterate the traditional separation of excitation and deexcitation. These factors are only now being explored, as are interference phenomena between the various channels.
The workshop on "Antennas and Reaction Centers of Photosynthetic Bac teria" was held at Feldafing, Bavaria (F. R. G. )' March 23-25, 1985. This workshop focussed on primary processes with emphasis on structure, inter actions and dynamics. It assessed structural, spectroscopic and dynamic data which have accumulated recently, providing an overview of the mech anism of the acquisition, storage and useful disposal of energy in bacterial photosynthesis. This volume is a record of the invited papers presented at the workshop. The material was organized into five sections: I. Antennas: Structure and Energy Transfer II. Reaction Centers: Structure and Interactions III. Electron Transfer: Theory and Model Systems IV. Reaction Cen,ters: Structure and Dynamics V. Model Systems on Function of Antennas and Reaction Centers I would like to express my gratitude to all the participants in the work shop for their contributions, and to the authors for the timely preparation of their manuscripts. I am indebted to the members of the organizing committee, Professors Sighart F. Fischer and Hugo Scheer for their most valuable assistance and advice. The workshop would not have been so successful without the help of my secretary, Frau Petra KahlfuB, and my coworkers in its organization. I thank Frau KahlfuB particularly also for her assistance in the preparation of these proceedings. The workshop was organized under the auspices of the Technical Uni versity of Munich, the Max-Planck-Society and the University of Munich.
This volume contains the contributions from the speakers at the NATO Advanced Research Workshop on "Structure of the Photosynthetic Bacterial Reaction Center X-ray Crystallography and Optical Spectroscopy with Polarized Light" which was held at the "Maison d'Hotes" of the Centre d'Etudes Nucleaires de Cadarache in the South of France, 20-25 September, 1987. This meeting continued in the spirit of a previous workshop which took place in Feldafing (FRG), March 1985. Photosynthetic reaction centers are intrinsic membrane proteins which, by performing a photoinduced transmembrane charge separation, are responsible for the conversion and storage of solar energy. Since the pioneering work of Reed and Clayton (1968) on the isolation of the reaction center from photosynthetic bacteria, optical spectroscopy with polarized light has been one of the main tools used to investigate the geometrical arrangement of the various chromophores in these systems. The recent elucidation by X-ray crystallography of the structure of several bacterial reaction centers, a breakthrough initiated by Michel and Deisenhofer, has provided us with the atomic coordinates of the pigments and some details about their interactions with neighboring aminoacid residues. This essential step has given a large impetus both to experimentalists and to theoreticians who are now attempting to relate the X-ray structural model to the optical properties of the reaction center and ultimately to its primary biological function.
Anoxygenic Photosynthetic Bacteria is a comprehensive volume describing all aspects of non-oxygen-evolving photosynthetic bacteria. The 62 chapters are organized into themes of: Taxonomy, physiology and ecology; Molecular structure of pigments and cofactors; Membrane and cell wall structure: Antenna structure and function; Reaction center structure and electron/proton pathways; Cyclic electron transfer; Metabolic processes; Genetics; Regulation of gene expression, and applications. The chapters have all been written by leading experts and present in detail the current understanding of these versatile microorganisms. The book is intended for use by advanced undergraduate and graduate students and senior researchers in the areas of microbiology, genetics, biochemistry, biophysics and biotechnology.