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The literature on cavitation chemistry is ripe with conjectures, possibilities, heuris tic arguments, and intelligent guesses. The chemical effects of cavitation have been explained by means of many theories, consisting of empirical constants, adjustable parameters, and the like. The chemists working with cavitation chemistry agree that the phenomenon is very complex and system specific. Mathematicians and physi cists have offered partial solutions to the observed phenomena on the basis of cavitation parameters, whereas chemists have attempted explanations based on the modes of reaction and the detection of intermediate chemical species. Nevertheless, no one has been able to formulate a unified theme, however crude, for its effects on the basis of the known parameters, such as cavitation and transient chemistry involving extremely high temperatures of nanosecond durations. When one surveys the literature on cavitation-assisted reactions, it is clear that the approach so far has been "Edisonian" in nature. While a large number of reactions have showed either enhanced yields or reduced reaction times, many reactions have remained unaffected in the presence of cavitation. The success or failure of cavitation reactions ultimately depends on the collapse of the cavity. Cavitation chemistry is based on the principles of the formation of small transient cavities, their growth and implosion, which produce chemical reactions caused by the generation of extreme pressures and temperatures and a high degree of micro turbulence.
Containing the state-of-the-art in hydrodynamic cavitation, the book consists of two parts. The first part presents the physical basis of cavitation and a systematic classification of various kinds of cavitation and their formation sources. Special attention is paid to a group of factors that promote cavitation formation in natural liquids. A general model of cavitation is formulated as well as a sub-model describing dynamics of the formation, development and collapse of cavitation bubbles. The sub-model also includes effects of cavitation bubble occurrence on the liquid in the direct vicinity of bubbles. Finally, part one also includes a thermodynamic hydrocavitation model of water containing cavitation nuclei (natural waters). The second part deals with the application of hydrodynamic cavitation effects to advanced oxidation of substances that pollute the natural environment. Results of laboratory experiments on the application of cavitation effects to decompose selected organic compounds which hardly undergo biodegradation are presented, as well as a concept of the cavitation phenomenon application on an industrial scale. Application of Hydrodynamic Cavitation in Environmental Engineering will be useful to professionals dealing with the design and practical application of hydrocavitation reactors, and to academics in environmental engineering.
Hydrodynamic Cavitation A systematic introduction to critical technologies and applications of hydrodynamic cavitation In Hydrodynamic Cavitation: Devices, Design, and Applications, a distinguished team of researchers delivers an authoritative discussion of key aspects of hydrodynamic cavitation, including the design, characterization, and modeling of the devices. The book offers discussions of state-of-the-art applications of the technology, including the disinfection of water, wastewater treatment, biomass processing, and many other industrial applications. In addition to expansive case studies, the book provides an up-to-date exploration of emerging innovations and future applications of the technology. Readers will also find: A thorough introduction to hydrodynamic cavitation devices, including those based on axial and rotational flows An in-depth examination of the experimental characterization of cavitation devices and computational models Comprehensive explorations of the applications of hydrodynamic cavitation, including the disinfection of water and wastewater treatment Accessible discussions of industrial applications of hydrodynamic cavitation Perfect for chemical and process engineers, water chemists, mechanical engineers, and food chemists, Hydrodynamic Cavitation will also earn a place in the libraries of food and environmental technologists.
The role of the chemical reactor is crucial for the industrial conversion of raw materials into products and numerous factors must be considered when selecting an appropriate and efficient chemical reactor. Chemical Reaction Engineering and Reactor Technology defines the qualitative aspects that affect the selection of an industrial chemical reactor and couples various reactor models to case-specific kinetic expressions for chemical processes. Thoroughly revised and updated, this much-anticipated Second Edition addresses the rapid academic and industrial development of chemical reaction engineering. Offering a systematic development of the chemical reaction engineering concept, this volume explores: essential stoichiometric, kinetic, and thermodynamic terms needed in the analysis of chemical reactors homogeneous and heterogeneous reactors reactor optimization aspects residence time distributions and non-ideal flow conditions in industrial reactors solutions of algebraic and ordinary differential equation systems gas- and liquid-phase diffusion coefficients and gas-film coefficients correlations for gas-liquid systems solubilities of gases in liquids guidelines for laboratory reactors and the estimation of kinetic parameters The authors pay special attention to the exact formulations and derivations of mass energy balances and their numerical solutions. Richly illustrated and containing exercises and solutions covering a number of processes, from oil refining to the development of specialty and fine chemicals, the text provides a clear understanding of chemical reactor analysis and design.
Energy Aspects of Acoustic Cavitation and Sonochemistry: Fundamentals and Engineering covers topics ranging from fundamental modeling to up-scaled experiments. The book relates acoustic cavitation and its intrinsic energy balance to macroscopic physical and chemical events that are analyzed from an energetic perspective. Outcomes are directly projected into practical applications and technological assessments covering energy consumption, thermal dissipation, and energy efficiency of a diverse set of applications in mixed phase synthesis, environmental remediation and materials chemistry. Special interest is dedicated to the sonochemical production of hydrogen and its energetic dimensions. Due to the sensitive energy balance that governs this process, this is seen as a "green process" for the production of future energy carriers. Provides a concise and detailed description of energy conversion and exchange within the single acoustic cavitation bubble and bubble population, accompanying physical and chemical effects Features a comprehensive approach that is supported by experiments and the modeling of energy concentration within the sonochemical reactor, jointly with energy dissipation and damping phenomenon Gives a clear definition of energy efficiency metrics of industrial sono-processes and their application to the main emergent industrial fields harnessing acoustic cavitation and sonochemistry, notably for the production of hydrogen
Cavitation and Bubble Dynamics deals with fundamental physical processes of bubble dynamics and cavitation for graduate students and researchers.
The role of the chemical reactor is crucial for the industrial conversion of raw materials into products and numerous factors must be considered when selecting an appropriate and efficient chemical reactor. Chemical Reaction Engineering and Reactor Technology defines the qualitative aspects that affect the selection of an industrial chemical reactor and couples various reactor models to case-specific kinetic expressions for chemical processes. Offering a systematic development of the chemical reaction engineering concept, this volume explores: Essential stoichiometric, kinetic, and thermodynamic terms needed in the analysis of chemical reactors Homogeneous and heterogeneous reactors Residence time distributions and non-ideal flow conditions in industrial reactors Solutions of algebraic and ordinary differential equation systems Gas- and liquid-phase diffusion coefficients and gas-film coefficients Correlations for gas-liquid systems Solubilities of gases in liquids Guidelines for laboratory reactors and the estimation of kinetic parameters The authors pay special attention to the exact formulations and derivations of mass energy balances and their numerical solutions. Richly illustrated and containing exercises and solutions covering a number of processes, from oil refining to the development of specialty and fine chemicals, the text provides a clear understanding of chemical reactor analysis and design.
The second edition of Comprehensive Biotechnology, Six Volume Set continues the tradition of the first inclusive work on this dynamic field with up-to-date and essential entries on the principles and practice of biotechnology. The integration of the latest relevant science and industry practice with fundamental biotechnology concepts is presented with entries from internationally recognized world leaders in their given fields. With two volumes covering basic fundamentals, and four volumes of applications, from environmental biotechnology and safety to medical biotechnology and healthcare, this work serves the needs of newcomers as well as established experts combining the latest relevant science and industry practice in a manageable format. It is a multi-authored work, written by experts and vetted by a prestigious advisory board and group of volume editors who are biotechnology innovators and educators with international influence. All six volumes are published at the same time, not as a series; this is not a conventional encyclopedia but a symbiotic integration of brief articles on established topics and longer chapters on new emerging areas. Hyperlinks provide sources of extensive additional related information; material authored and edited by world-renown experts in all aspects of the broad multidisciplinary field of biotechnology Scope and nature of the work are vetted by a prestigious International Advisory Board including three Nobel laureates Each article carries a glossary and a professional summary of the authors indicating their appropriate credentials An extensive index for the entire publication gives a complete list of the many topics treated in the increasingly expanding field
Renewable fuel research and process development requires interdisciplinary approaches involving chemists and physicists from both scientific and engineering backgrounds. Here is an important volume that emphasizes green chemistry and green engineering principles for sustainable process development from an interdisciplinary point of view. It creates an enriching knowledge base on green chemistry of biofuel production, sustainable process development, and green engineering principles for renewable fuel production. This book includes chapters contributed by both research scientists and research engineers with significant experience in biofuel chemistry and processes. The book offers an abundance of scientific experimental methods and analytical procedures and interpretation of the results that capture the state-of-the-art knowledge in this field. The wide range of topics make this book a valuable resource for academicians, researchers, industrial practitioners and scientists, and engineers in various renewable energy fields. Key features: • Emphasizes green chemistry and green engineering principles for sustainable process development for biofuel production • Discusses a wide array of biofuels from algal biomass to waste-to-energy technologies and wastewater treatment and activated sludge processes • Presents advances and developments in biofuel green chemistry and green engineering, including process intensification (microwaves/ultrasound), ionic liquids, and green catalysis • Looks at environmental assessment and economic impact of biofuel production
These are the proceedings of the 2012 International Conference on Chemical Engineering and Advanced Materials (CEAM 2012). The conference provided a forum for the discussion of new developments, recent progress and innovations in chemical engineering and advanced materials, and addressed all aspects of these fields. Emphasis was placed on current and future challenges in research and development for both academia and industry; especially long-term fundamental research aimed at discovering novel phenomena, processes and tools.