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Illustrating developments in electrochemical nanotechnology, heterogeneous catalysis, surface science and theoretical modelling, this reference describes the manipulation, characterization, control, and application of nanoparticles for enhanced catalytic activity and selectivity. It also offers experimental and synthetic strategies in nanoscale surface science. This standard-setting work clariefies several practical methods used to control the size, shape, crystal structure, and composition of nanoparticles; simulate metal-support interactions; predict nanoparticle behavior; enhance catalytic rates in gas phases; and examine catalytic functions on wet and dry surfaces.
The basics and principles of new electrochemical methods and also their usage for fabrication and analysis of different nanostructures were discussed in this book. These methods consist of electrochemical methods in nanoscale (e.g. electrochemical atomic force microscopy and electrochemical scanning tunneling microscopy) and also electrochemical methods for fabrication of nanomaterials.
Nanoparticles in Catalysis Discover an essential overview of recent advances and trends in nanoparticle catalysis Catalysis in the presence of metal nanoparticles is an important and rapidly developing research field at the frontier of homogeneous and heterogeneous catalysis. In Nanoparticles in Catalysis, accomplished chemists and authors Karine Philippot and Alain Roucoux deliver a comprehensive guide to the key aspects of nanoparticle catalysis, ranging from synthesis, activation methodology, characterization, and theoretical modeling, to application in important catalytic reactions, like hydrogen production and biomass conversion. The book offers readers a review of modern and efficient tools for the synthesis of nanoparticles in solution or onto supports. It emphasizes the application of metal nanoparticles in important catalytic reactions and includes chapters on activation methodology and supported nanoclusters. Written by an international team of leading voices in the field, Nanoparticles in Catalysis is an indispensable resource for researchers and professionals in academia and industry alike. Readers will also benefit from the inclusion of: A thorough introduction to New Trends in the Design of Metal Nanoparticles and Derived Nanomaterials for Catalysis An exploration of Dynamic Catalysis and the Interface Between Molecular and Heterogeneous Catalysts A practical discussion of Metal Nanoparticles in Water: A Relevant Toolbox for Green Catalysis Organometallic Metal Nanoparticles for Catalysis A concise treatment of the opportunities and challenges of CO2 Hydrogenation to Oxygenated Chemicals Over Supported Nanoparticle Catalysts Perfect for catalytic, organic, inorganic, and physical chemists, Nanoparticles in Catalysis will also earn a place in the libraries of chemists working with organometallics and materials scientists seeking a one-stop resource with expert knowledge on the synthesis and characterization of nanoparticle catalysis.
Gold, considered catalytically inactive for a long time, is now a fascinating partner of modern chemistry, as scientists such as Bond, Teles, Haruta, Hutchings, Ito and Hayashi opened new perspectives for the whole synthetic chemist community. Recently gold has attracted significant attention due to its advantageous characteristics as a catalytic material and since it allows easy functionalization with biologically active molecules. In this context, when gold is prepared as very small particles, it turns out to be a highly active catalyst. However, such a phenomenon completely disappears when the gold particle size grows into the micrometer range. Therefore, the preparation for obtaining an active gold catalyst is so important. The primary objective of this book is to provide a comprehensive overview of gold metal nanoparticles and their application as promising catalysts.
Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry, Seven Volume Set summarizes current, fundamental knowledge of interfacial chemistry, bringing readers the latest developments in the field. As the chemical and physical properties and processes at solid and liquid interfaces are the scientific basis of so many technologies which enhance our lives and create new opportunities, its important to highlight how these technologies enable the design and optimization of functional materials for heterogeneous and electro-catalysts in food production, pollution control, energy conversion and storage, medical applications requiring biocompatibility, drug delivery, and more. This book provides an interdisciplinary view that lies at the intersection of these fields. Presents fundamental knowledge of interfacial chemistry, surface science and electrochemistry and provides cutting-edge research from academics and practitioners across various fields and global regions
This book presents a comprehensive review of the methods and approaches being adopted to push forward the boundaries of computational catalysis.
This book covers the recent advances in electrode materials and their novel applications at the cross-section of advanced materials. The book is divided into two sections: State-of-the-art electrode materials; and engineering of applied electrode materials. The chapters deal with electrocatalysis for energy conversion in view of bionanotechnology; surfactant-free materials and polyoxometalates through the concepts of biosensors to renewable energy applications; mesoporous carbon, diamond, conducting polymers and tungsten oxide/conducting polymer-based electrodes and hybrid systems. Numerous approaches are reviewed for lithium batteries, fuel cells, the design and construction of anode for microbial fuel cells including phosphate polyanion electrodes, electrocatalytic materials, fuel cell reactions, conducting polymer based hybrid nanocomposites and advanced nanomaterials.
A comprehensive survey of theoretical andexperimental concepts in fuel cell chemistry Fuel cell science is undergoing significant development, thanks, in part, to a spectacular evolution of the electrocatalysis concepts, and both new theoretical and experimental methods. Responding to the need for a definitive guide to the field, Fuel Cell Science provides an up-to-date, comprehensive compendium of both theoretical and experimental aspects of the field. Designed to inspire scientists to think about the future of fuel cell technology, Fuel Cell Science addresses the emerging field of bio-electrocatalysis and the theory of heterogeneous reactions in fuel cell science and proposes potential applications for electrochemical energy production. The book is thorough in its coverage of the electron transfer process and structure of the electric double layer, as well as the development of operando measurements. Among other subjects, chapters describe: Recently developed strategies for the design, preparation, and characterization of catalytic materials for fuel cell electrodes, especially for new fuel cell cathodes A wide spectrum of theoretical and computational methods, with?the aim of?developing?new fuel cell catalysis concepts and improving existing designs to increase their performance.? Edited by two leading faculty, the book: Addresses the emerging fields of bio-electrocatalysis for fuel cells and theory of heterogeneous reactions for use in fuel cell catalysis Provides a survey of experimental and theoretical concepts in these new fields Shows the evolution of electrocatalysis concepts Describes the chemical physics of fuel cell reactions Forecasts future developments in electrochemical energy production and conversion Written for electrochemists and electrochemistry graduate students, electrocatalysis researchers, surface and physical chemists, chemical engineers, automotive engineers, and fuel cell and energy-related researchers, this modern compendium can help today's best minds meet the challenges in fuel science technology.
Wiley Series on Electrocatalysis and Electrochemistry Fuel Cell Catalysis A Surface Science Approach A Core reference on fuel cell catalysis Fuel cells represent an important alternative energy source and a very active area of research. Fuel Cell Catalysis brings together world leaders in this field, providing a unique combination of state-of-the-art theory and computational and experimental methods. With an emphasis on understanding fuel cell catalysis at the molecular level, this text covers fundamental principles, future challenges, and important current research themes. Fuel Cell Catalysis: Provides a molecular-level description of catalysis for low-temperature polymer-electrolyte membrane fuel cells, including both hydrogen-oxygen cells and direct alcohol cells Examines catalysis issues of both anode and cathode such as oxygen reduction, alcohol oxidation, and CO tolerance Features a timely and forward-looking approach through emphasis on novel aspects such as computation and bio-inspiration Reviews the use and potential of surface-sensitive techniques like vibrational spectroscopy (IR, Raman, nonlinear spectroscopy, laser), scanning tunneling microscopy, X-ray scattering, NMR, electrochemical techniques, and more Reviews the use and potential of such modern computational techniques as DFT, ab initio MD, kinetic Monte Carlo simulations, and more Surveys important trends in reactivity and structure sensitivity, nanoparticles, "dynamic" catalysis, electrocatalysis vs. gas-phase catalysis, new experimental techniques, and nontraditional catalysts This cutting-edge collection offers a core reference for electrochemists, electrocatalysis researchers, surface and physical chemists, chemical and automotive engineers, and researchers in academia, research institutes, and industry.
This book focuses on the recent research progress on the fundamental understanding of the materials degradation phenomena in PEFC, for automotive applications. On a multidisciplinary basis, through contributions of internationally recognized researchers in the field, this book provides a complete critical review on crucial scientific topics related