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From the Authors' Preface The advancements of technology . . . and chemical engineering have brought about extensive use of a wide range of rheologically complex materials, e.g., polymeric solutions and melts, suspensions, mixtures, oil products, fibre-forming substances, etc. that are characterized by diverse and, every so often, significant deviations from classical Newtonian behavior. Such materials are often used in conditions where the formation of vapor-gas bubbles or two-phase flow regimes is possible. This necessitates deep investigations into the thermo-hydrodynamic problems of liquids with bubbles for the case of a continuous phase with anomalous rheological properties. These conditions are typical of a number of applications and manufacturing processes, e.g., gas removal from polymeric solutions or melts in production of film, chemical fibres and other polymeric materials. . . . The bubbles containing gas or vapor-gas mixtures are often present in polymeric systems. This is because of a number of reasons, e.g., a low wettability of solid surfaces by polymers, the use of volatile solvents, abundance of vapor-gas nuclei, the capture of gas by porous or fibre-like polymeric particles during the polymer dissolution or melting, etc. Spontaneous evacuation of bubbles in polymeric media is usually complicated by a high viscosity of the liquid; therefore two-phase polymeric systems possess a higher sedimentation and aggregation stability than bubble mixtures in low-molecular-weight liquids. One of the main problems in the dynamics of vapor-liquid and gas-liquid systems is the investigation of heat and mass transfer and phase interactions in a liquid with bubbles. The decisive importance of this problem in the analysis of various aspects of the bubbly fluid behavior under diverse conditions, in particular, during a sound wave propagation, has given impetus to numerous researches. The current state of art in the investigation of Newtonian liquids with bubbles is described in voluminous literature. However, these problems have been much less studied for non-Newtonian systems. Behavior of bubbles in polymeric liquids is of great interest because of wide application in chemical technology. . . . In a number of processes connected with the application of polymeric fluids, the dynamic interaction of bubbles with liquid phase plays the key role. Such interaction in the case of a polymeric liquid phase are essentially influenced by the specific properties of macromolecular fluids, including primarily the rheological effects. These effects in the bubble dynamics combined with heat and mass transfer between the bubble content and the ambient liquid constitute the main subject of the analysis presented in this book. Macrokinetics Laboratory, and Full Professor at the Byelorussian Polytechnic Institute, Department of Heat and Power Engineering. Dr. Schulman is recognized as a leading authority in his field of investigation. Extensive Bibliography: A valuable feature of this new book is its extensive international bibliography, with 393 references.
Volume 2 presents the fundamental principles related to polymer processign operations including the processing of thermoplastic polymers and thermosets. The objective of this volume is not to provide recipies that necessarily guarantee better product quality. Rather, emphasis is placed on presenting a fundamental approach to effectively analyze processing operations. The specific polymer processing operations for thermoplastics include plasticating single-screw extrusion, morphology evolution during compounding of polymer blends, compatibilization of immiscible polymer blends, wire coating extrusion, fiber spinning, tubular film blowing, coextrusion, and thermoplastic foam extrusion. The specific polymer processing operations for thermosets include reaction injection molding, pultrusion of fiber-reinforced thermosets, and compression molding of thermoset composites.
For phenomena involving bubble nucleation, the molecular cluster model is used to predict the tensile strength and superheat limit of liquids and the amount of decompression for gaseous bubble nucleation in supersaturated solutions. The book investigates various gaseous bubble nucleation events including the bubble formation in gas-water solutions, CO bubble formation in iron melts, the formation of microcellular foams in polymers, the nucleation of nano-sized H2O bubbles in rhyolite melts, and bubble nucleation in shear flow fields. The book also investigates vaporous bubble nucleation events such as bubble formation on a cavity-free surface and inside a solid nanopore in 3M NaCl solution, superheat limit of liquids, and bubble nucleation near the absolute zero temperature by quantum tunnelling in liquid helium. For bubble dynamics phenomena, a set of homologous solutions of the Navier-Stokes equations for evolving spherical bubbles are used to treat gaseous bubble growth in organic solutions, polymer solutions, and in viscous rhyolitic melts. The growth and collapse of laser-induced vapor bubbles in liquid, and on solid particles is discussed as an example of homologous motion of the spherical object. Sonoluminescence phenomena in water and in sulfuric acid solutions, the pressure and shock wave propagation in bubbly mixtures, the gravitational collapse of Newtonian stars, and the core collapse of supernovas are also treated using these homologous solutions. The motion of a fire-ball generated by a TNT explosion underwater is obtained using a zero gravitational constant in the equation of motion for Newtonian stars.
This work introduces the fundamental background necessary to understand polymer devolatilization. It elucidates the actual mechanisms by which the devolatilization of polymer melts progresses, and discusses virtually every type of devolatilization equipment available. The work also addresses devolatilization in various geometries and types of equipment, describing the use of falling strand, slit, single-screw, co-rotating and counter-rotating twin-screw devolatilization.
Foaming with Supercritical Fluids, Volume Nine provides a comprehensive description of the use of supercritical fluids as blowing agents in polymer foaming. To this aim, the fundamental issues on which the proper design and control of this process are rooted are discussed in detail, with specific attention devoted to the theoretical and experimental aspects of sorption thermodynamics of a blowing agent within a polymer, the effect of the absorbed blowing agent on the thermal, interfacial and rheological properties of the expanding matter, and the phase separation of the gaseous phase, and of the related bubble nucleation and growth phenomena. Several foaming technologies based on the use of supercritical blowing agents are then described, addressing the main issues in the light of the underlying chemical-physical phenomena. - Offers strong fundamentals on polymer properties important on foaming - Outlines the use of supercritical fluids for foaming - Covers theoretical points-of-view, including foam formation of the polymer/gas solution to the setting of the final foam - Discusses the several processing technologies and applications
This book is the inaugural volume a series entitled Polymeric Foams: Technology and Applications. Generally, thermoplastic and thermoset foams have been treated as two separate practices in industry. Polymeric Foams: Mechanisms and Materials presents the basics of foaming in general build a strong foundation to those working in both thermoplastic a
Combining the science of foam with the engineering of extrusion processes, Foam Extrusion: Principles and Practice delivers a detailed discussion of the theory, design, processing, and application of degradable foam extraction. In one comprehensive volume, the editors present the collective expertise of leading academic, research, and industry specialists while laying the scientific foundation in such a manner that the microscopic transition from a nucleus to a void (nucleation) and macroscopic movement from a void to an object (formation) are plausibly addressed. To keep pace with significant improvements in foam extrusion technology, this Second Edition: Includes new chapters on the latest developments in processing/thermal management, rheology/melt strength, and biodegradable and sustainable foams Features extensive updates to chapters on extrusion equipment, blowing agents, polyethylene terephthalate (PET) foam, and microcellular innovation Contains new coverage of cutting-edge foaming mechanisms and technology, as well as new case studies, examples, and figures Capturing the interesting evolution of the field, Foam Extrusion: Principles and Practice, Second Edition provides scientists, engineers, and product development professionals with a modern, holistic view of foam extrusion to enhance research and development and aid in the selection of the optimal screw, die design, and foaming system.
Polymeric Foams Structure–Property–Performance: A Design Guide is a response to the design challenges faced by engineers in a growing market with evolving standards, new regulations, and an ever-increasing variety of application types for polymeric foam. Bernard Obi, an author with wide experience in testing, characterizing, and applying polymer foams, approaches this emerging complexity with a practical design methodology that focuses on understanding the relationship between structure–properties of polymeric foams and their performance attributes. The book not only introduces the fundamentals of polymer and foam science and engineering, but also goes more in-depth, covering foam processing, properties, and uses for a variety of applications. By connecting the diverse technologies of polymer science to those from foam science, and by linking both micro- and macrostructure–property relationships to key performance attributes, the book gives engineers the information required to solve pressing design problems involving the use of polymeric foams and to optimize foam performance. With a focus on applications in the automotive and transportation industries, as well as uses of foams in structural composites for lightweight applications, the author provides numerous case studies and design examples of real-life industrial problems from various industries and their solutions. Provides the science and engineering fundamentals relevant for solving polymer foam application problems Offers an exceptionally practical methodology to tackle the increasing complexity of real-world design challenges faced by engineers working with foams Discusses numerous case studies and design examples, with a focus on automotive and transportation Utilizes a practical design methodology focused on understanding the relationship between structure-properties of polymeric foams and their performance attributes
Foamability of Thermoplastic Polymeric Materials presents a cutting-edge approach to thermoplastic polymeric foams, drawing on the latest research and guiding the reader through the fundamental science, foamability, structure-property-processing relationship, multi-phase polymeric materials, degradation characteristics of biodegradable foams and advanced applications. Sections provide detailed information on foam manufacturing technologies and the fundamental science behind foaming, present insights on the factors affecting foamability, cover ways of enhancing the foamability of various polymeric materials, with special focus on multi-phase systems, discuss the degradation of biodegradable foams and special morphology development for scaffolds, packaging, acoustic and super-insulation applications, as well as cell seeding studies in scaffolds. Each application has specific requirements in terms of desired properties. This in-depth coverage and analysis helps those looking to move forward with microcellular processing and polymer foaming. This is an ideal resource for researchers, advanced students and professionals interested in the microcellular processing of polymeric materials in the areas of polymer foaming, polymer processing, plastics engineering and materials science. - Offers in-depth coverage of factors affecting foamability and methods for enhancing the foamability of polymeric materials - Explores innovative applications in a range of areas, including scaffolds, acoustic applications, packaging and super-insulation - Provides a comprehensive, critical overview of the state-of-the-art, possible future research directions, and opportunities for industrial application