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Biomass pyrolysis has been practised for centuries in the manufacture of charcoal for industry and leisure. Only in the last two decades, however, has attention focussed on a better understanding of the science and technology, with the resultant benefits of better designed and controlled processes that give high yields of liquid products. These liquids, or 'bio-oil' as it is referred to, can be used in a variety of ways: -combustion to replace conventional fuel oil in boilers, process equipment such as kilns and in gas turbines for power generation; -upgrading by hydrotreating or with zeolites to gasoline, diesel and other hydrocarbon fuels, of chemicals; --extraction and upgrading to fuel additives and chemical specialities. Any charcoal produced can also be utilised to form char- water slurries, analogous to coal-water slurries, or bioi-oil slurries which may be used as liquid fuels in many combustion applications. A group of experts was set up in the EC Energy from Biomass programme to evaluate the status and opportunities for deriving useful liquid products from biomass pyrolysis. This book is a report of their findings and conclusions. It forms an authoritative guide to the wide range of technologies employed in biomass pyrolysis, and product upgrading, utilisation and characterisation. Recommendations and conclusions are included to identify promising areas of research and development that will be of value to researchers, planners and companies throughout the world.
This conference is the second such meeting under the auspices of the International Energy Agency's Bioenergy Agreement. The first lEA sponsored Fundamentals of Thermochemical Biomass Conversion Conference was held in Estes Park in 1982 and attracted 153 delegates from 13 countries around the world at a time when interest in biomass derived energy was at a peak. Since then oil prices have fallen considerably and with most prognoses for level prices until the end of the century, there has been a significant downturn in support for biomass conversion technologies. It has been particularly encouraging, therefore, to have received such an excellent response to this meeting. A total of 122 papers were offered, and 135 delegates registered for the conference from 19 countries. The theme of this meeting was Research in Thermochemical Biomass Conversion to reflect the advances made in research, development, demonstration and com mercialisation since the Fundamentals meeting in 1982. The programme was divided into sections on fundamental research, applied research, and demonstration and commercial activities to emphasise the interaction and roles of all levels of research in supporting the eventual commercial implementation. The layout of the pro ceedings reflects this same pattern, with an introductory section on status and technoeconomics to identify opportunities and constraints in different parts of the world. All the papers included in these proceedings have been subjected to the usual peer review process to ensure the highest standards.
A comprehensive examination of the large number of possible pathways for converting biomass into fuels and power through thermochemical processes Bringing together a widely scattered body of information into a single volume, this book provides complete coverage of the many ways that thermochemical processes are used to transform biomass into fuels, chemicals and power. Fully revised and updated, this new edition highlights the substantial progress and recent developments that have been made in this rapidly growing field since publication of the first edition and incorporates up-to-date information in each chapter. Thermochemical Processing of Biomass: Conversion into Fuels, Chemicals and Power, 2nd Edition incorporates two new chapters covering: condensed phased reactions of thermal deconstruction of biomass and life cycle analysis of thermochemical processing systems. It offers a new introductory chapter that provides a more comprehensive overview of thermochemical technologies. The book also features fresh perspectives from new authors covering such evolving areas as solvent liquefaction and hybrid processing. Other chapters cover combustion, gasification, fast pyrolysis, upgrading of syngas and bio-oil to liquid transportation fuels, and the economics of thermochemically producing fuels and power, and more. Features contributions by a distinguished group of European and American researchers offering a broad and unified description of thermochemical processing options for biomass Combines an overview of the current status of thermochemical biomass conversion as well as engineering aspects to appeal to the broadest audience Edited by one of Biofuels Digest’s "Top 100 People" in bioenergy for six consecutive years Thermochemical Processing of Biomass: Conversion into Fuels, Chemicals and Power, 2nd Edition will appeal to all academic researchers, process chemists, and engineers working in the field of biomass conversion to fuels and chemicals. It is also an excellent book for graduate and advanced undergraduate students studying biomass, biofuels, renewable resources, and energy and power generation.
A comprehensive reference to the use of innovative catalysts and processes to turn biomass into value-added chemicals Chemical Catalysts for Biomass Upgrading offers detailed descriptions of catalysts and catalytic processes employed in the synthesis of chemicals and fuels from the most abundant and important biomass types. The contributors?noted experts on the topic?focus on the application of catalysts to the pyrolysis of whole biomass and to the upgrading of bio-oils. The authors discuss catalytic approaches to the processing of biomass-derived oxygenates, as exemplified by sugars, via reactions such as reforming, hydrogenation, oxidation, and condensation reactions. Additionally, the book provides an overview of catalysts for lignin valorization via oxidative and reductive methods and considers the conversion of fats and oils to fuels and terminal olefins by means of esterification/transesterification, hydrodeoxygenation, and decarboxylation/decarbonylation processes. The authors also provide an overview of conversion processes based on terpenes and chitin, two emerging feedstocks with a rich chemistry, and summarize some of the emerging trends in the field. This important book: -Provides a comprehensive review of innovative catalysts, catalytic processes, and catalyst design -Offers a guide to one of the most promising ways to find useful alternatives for fossil fuel resources -Includes information on the most abundant and important types of biomass feedstocks -Examines fields such as catalytic cracking, pyrolysis, depolymerization, and many more Written for catalytic chemists, process engineers, environmental chemists, bioengineers, organic chemists, and polymer chemists, Chemical Catalysts for Biomass Upgrading presents deep insights on the most important aspects of biomass upgrading and their various types.
This edited and updated version of the final report of the IEA Bioenergy Pyrolysis Task, is useful both to newcomers to the subject area and those already involved in research, development, and implementation.
This book provides an account of the state-of-the-art in thermochemical biomass conversion and arises from the third conference in a series sponsored by the International Energy Agency's Bioenergy Agreement. Fundamental and applied research topics are included, reflecting recent advances as well as demonstration and commercial innovation.
While strides are being made in the research and development of environmentally acceptable and more sustainable alternative fuels—including efforts to reduce emissions of air pollutants associated with combustion processes from electric power generation and vehicular transportation—fossil fuel resources are limited and may soon be on the verge of depletion in the near future. Measuring the correlation between quality of life, energy consumption, and the efficient utilization of energy, the Handbook of Alternative Fuel Technologies, Second Edition thoroughly examines the science and technology of alternative fuels and their processing technologies. It focuses specifically on environmental, technoeconomic, and socioeconomic issues associated with the use of alternative energy sources, such as sustainability, applicable technologies, modes of utilization, and impacts on society. Written with research and development scientists and engineers in mind, the material in this handbook provides a detailed description and an assessment of available and feasible technologies, environmental health and safety issues, governmental regulations, and issues and agendas for R&D. It also includes alternative energy networks for production, distribution, and consumption. What’s New in This Edition: Contains several new chapters of emerging interest and updates various chapters throughout Includes coverage of coal gasification and liquefaction, hydrogen technology and safety, shale fuel by hydraulic fracturing, ethanol from lignocellulosics, biodiesel, algae fuels, and energy from waste products Covers statistics, current concerns, and future trends A single-volume complete reference, the Handbook of Alternative Fuel Technologies, Second Edition contains relevant information on chemistry, technology, and novel approaches, as well as scientific foundations for further enhancements and breakthroughs. In addition to its purposes as a handbook for practicing scientists and engineers, it can also be used as a textbook or as a reference book on fuel science and engineering, energy and environment, chemical process design, and energy and environmental policy.
There have been many developments in the science and technology of thermo chemical biomass conversion since the previous conference on Advances in Thermochemical Biomass Conversion in Interlaken, Switzerland, in 1992. This fourth conference again covers all aspects of thermal biomass conversion systems from fundamental research through applied research and development to demon stration and commercial applications to reflect the progress made in the last four years. All aspects of bioenergy systems are covered from pretreatment through to end-user applications with increased consideration paid to the environmental benefits and problems of implementing bio-energy systems. There was an excellent response with over 200 papers offered and over 180 delegates from 29 countries attending the conference. The programme was divided into five main areas covering pyrolysis, pretreatment, gasification, combustion and system studies and this division is reflected in the structure of these conference proceedings. Each main section was preceded by a state-of-the-art review to provide a focus for the ensuing presentations and an authoritative reference. All the papers included have been subject to a full peer review process. As with any international conference, an important aim was to exchange ideas and discuss problems with fellow researchers, as well as to hear about the latest research and development and applications. A workshop programme was included to encourage this interaction in areas of interest selected by participants. The resul tant workshop reports provide a summary of topical problems and opportunities.
Algae offer potential to produce renewable chemicals and fuels using solar energy and carbon dioxide from atmosphere or in flue gases while simultaneously reducing the generation of greenhouse gases. Since these can be grown on marginal lands with micronutrients and macronutrients often present in waste streams, algae-based chemicals and fuels do not compete with foods. Still large-scale production of algae-based fuels and chemicals faces considerable technological and economical challenges and it would by necessity require a biorefinery approach wherein all the possible algal components are converted into value-added compounds. The present series on algal biorefineries represents a forum for reporting the state of the art of different technologies as well as the latest advances in this field. The volume II of this series complements the volume I in terms of the current state of the art. Different chapters in this volume address diverse issues ranging from genetically modifies algae to new products to life-cycle analysis of algal products.