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This proceedings volume represents the culmination of nearly three years of planning, organizing and carrying out of a NATO Ad vanced Study Institute on Biomass Utilization. The effort was initi ated by Dr. Harry Sobel, then Editor of Biosources Digest, and a steering committee representing the many disciplines that this field brings together. . When the fiscal and logistical details of the original plan could not be worked out, the idea was temporarily suspended. In the spring of 1982, the Renewable Materials Institute of the State University of New York at the College of Environmental Science and Forestry in Syracuse, New York revived the plan. A number of modifications had to be made, including the venue which was changed from the U.S.A. to Portugal. Additional funding beyond the basic support provided by the Scientific Affairs Division of NATO had to be obtained. Ul timately there were supplementary grants from the Foundation for Microbiology and the Anne S. Richardson Fund to assist student participants. The New York State College of Forestry Foundation, Inc. provided major support through the Renewable Ma terials Institute. The ASI was held in Alcabideche, Portugal from September 26 to October 9, 1982. Eighty participants including fifteen principal lecturers were assembled at the Hotel Sintra Estoril for the program that was organized as a comprehensive course on biomass utilization. The main lectures were supplemented by relevant short papers offered by the participants.
Energy and the environment are inextricably linked to the economy. Thermodynamics therefore seems to be a privileged tool in overcoming the constraints associated with optimization.This first volume reports on an original, contemporary approach leading to optimal solutions in the form of trend models, proving the existence of solutions which can then be refined in a more complete and sophisticated manner.The validation of the proposed methodology is realized through real-life examples (engines, heat pumps, refrigeration systems, etc.). However, the more fundamental aspects linked to the dynamics of the transfer and conversion of energy and matter are also explored, as well as the evolution which characterizes the second law of thermodynamics.This book presents recent advances, often still undergoing research, as well as structured exercises, and is therefore aimed at both students and researchers in the field of energetics. - It proposes a view of the evolution of knowledge regarding the thermodynamics modeling of systems and processes - It shows results and also the existence of optimum all and along the development - It focuses on multidisciplinary approach that characterizes thermodynamics
Bioethanol is one of the main biofuels currently used as a petroleum-substitute in transport applications. However, conflicts over food supply and land use have made its production and utilisation a controversial topic. Second generation bioalcohol production technology, based on (bio)chemical conversion of non-food lignocellulose, offers potential advantages over existing, energy-intensive bioethanol production processes. Food vs. fuel pressures may be reduced by utilising a wider range of lignocellulosic biomass feedstocks, including energy crops, cellulosic residues, and, particularly, wastes.Bioalcohol production covers the process engineering, technology, modelling and integration of the entire production chain for second generation bioalcohol production from lignocellulosic biomass. Primarily reviewing bioethanol production, the book's coverage extends to the production of longer-chain bioalcohols which will be elemental to the future of the industry.Part one reviews the key features and processes involved in the pretreatment and fractionation of lignocellulosic biomass for bioalcohol production, including hydrothermal and thermochemical pretreatment, and fractionation to separate out valuable process feedstocks. Part two covers the hydrolysis (saccharification) processes applicable to pretreated feedstocks. This includes both acid and enzymatic approaches and also importantly covers the development of particular enzymes to improve this conversion step. This coverage is extended in Part three, with chapters reviewing integrated hydrolysis and fermentation processes, and fermentation and co-fermentation challenges of lignocellulose-derived sugars, as well as separation and purification processes for bioalcohol extraction.Part four examines the analysis, monitoring and modelling approaches relating to process and quality control in the pretreatment, hydrolysis and fermentation steps of lignocellulose-to-bioalcohol production. Finally, Part five discusses the life-cycle assessment of lignocellulose-to-bioalcohol production, as well as the production of valuable chemicals and longer-chain alcohols from lignocellulosic biomass.With its distinguished international team of contributors, Bioalcohol production is a standard reference for fuel engineers, industrial chemists and biochemists, plant scientists and researchers in this area. - Provides an overview of the life-cycle assessment of lignocelluloses-to-bioalcohol production - Reviews the key features and processes involved in the pre-treatment and fractionation of lignocellulosic biomass for bioalcohol production - Examines the analysis, monitoring and modelling approaches relating to process and quality control in pre-treatment, hydrolysis and fermentation
Decision to produce; Markets and uses; Market assessment; Prodution potential; Equipment selection; Financial requirements; Decision and planning workssheets; Basic ethanol production; Preparation of feedstocks, Fermentation; Distillation; Types of feedstocks; Coproduct yields; Agronomic considerations; Plant design; Overall plant considerations; Process control; Representative ethanol plant; Maintenance checklist; Business plan; Analysis of financial requirements; Organizational form; Financing; Case study; Summary of legislation; Bureau of alcohol, tabacco, and firearms permit information; Enviromental considerations.
Direct Alcohol Fuel Cells for Portable Applications: Fundamentals, Engineering and Advances presents the fundamental concepts, technological advances and challenges in developing, modeling and deploying fuel cells and fuel cell systems for portable devices, including micro and mini fuel cells. The authors review the fundamental science of direct alcohol fuel cells, covering, in detail, thermodynamics, electrode kinetics and electrocatalysis of charge-transfer reactions, mass and heat transfer phenomena, and basic modeling aspects. In addition, the book examines other fuels in DAFCs, such as formic acid, ethylene glycol and glycerol, along with technological aspects and applications, including case studies and cost analysis. Researchers, engineering professionals, fuel cell developers, policymakers and senior graduate students will find this a valuable resource. The book's comprehensive coverage of fundamentals is especially useful for graduate students, advanced undergraduate students and those new to the field. - Provides a comprehensive understanding of the fundamentals of DAFCs and their basic components, design and performance - Presents current and complete information on the state-of-the-art of DAFC technology and its most relevant challenges for commercial deployment - Includes practical application examples, problems and case studies - Covers the use of other fuels, such as formic acid, ethylene glycol and glycerol
In the United States, we have come to depend on plentiful and inexpensive energy to support our economy and lifestyles. In recent years, many questions have been raised regarding the sustainability of our current pattern of high consumption of nonrenewable energy and its environmental consequences. Further, because the United States imports about 55 percent of the nation's consumption of crude oil, there are additional concerns about the security of supply. Hence, efforts are being made to find alternatives to our current pathway, including greater energy efficiency and use of energy sources that could lower greenhouse gas (GHG) emissions such as nuclear and renewable sources, including solar, wind, geothermal, and biofuels. The United States has a long history with biofuels and the nation is on a course charted to achieve a substantial increase in biofuels. Renewable Fuel Standard evaluates the economic and environmental consequences of increasing biofuels production as a result of Renewable Fuels Standard, as amended by EISA (RFS2). The report describes biofuels produced in 2010 and those projected to be produced and consumed by 2022, reviews model projections and other estimates of the relative impact on the prices of land, and discusses the potential environmental harm and benefits of biofuels production and the barriers to achieving the RFS2 consumption mandate. Policy makers, investors, leaders in the transportation sector, and others with concerns for the environment, economy, and energy security can rely on the recommendations provided in this report.
The first two editions of this title, published by SAE International in 1990 and 1995, have been best-selling definitive references for those needing technical information about automotive fuels. This long-awaited new edition has been thoroughly revised and updated, yet retains the original fundamental fuels information that readers find so useful. This book is written for those with an interest in or a need to understand automotive fuels. Because automotive fuels can no longer be developed in isolation from the engines that will convert the fuel into the power necessary to drive our automobiles, knowledge of automotive fuels will also be essential to those working with automotive engines. Small quantities of fuel additives increasingly play an important role in bridging the gap that often exists between fuel that can easily be produced and fuel that is needed by the ever-more sophisticated automotive engine. This book pulls together in a single, extensively referenced volume, the three different but related topics of automotive fuels, fuel additives, and engines, and shows how all three areas work together. It includes a brief history of automotive fuels development, followed by chapters on automotive fuels manufacture from crude oil and other fossil sources. One chapter is dedicated to the manufacture of automotive fuels and fuel blending components from renewable sources. The safe handling, transport, and storage of fuels, from all sources, are covered. New combustion systems to achieve reduced emissions and increased efficiency are discussed, and the way in which the fuels’ physical and chemical characteristics affect these combustion processes and the emissions produced are included. There is also discussion on engine fuel system development and how these different systems affect the corresponding fuel requirements. Because the book is for a global market, fuel system technologies that only exist in the legacy fleet in some markets are included. The way in which fuel requirements are developed and specified is discussed. This covers test methods from simple laboratory bench tests, through engine testing, and long-term test procedures.