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A practical guidebook illustrating the applications of spectroelectrochemistry to the understanding of redox reactions through identification of their intermediaries and products.
This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. They can be readily modified sterically and electronically through appropriate substitution on the pyrazole ring and on boron, and have led to a number of firsts in coordination chemistry (first stable CuCO complex, first monomeric MgR complex, and many other such firsts). Their denticity can range from two to four, their “Bite” can be adjusted, and additional coordinating sites can be added to the pyrazolyl rings. Over 170 different scorpionate ligands are known today, and some are published for the first time in this book.The author, Swiatoslaw Trofimenko, discovered and developed this ligand system and has written several reviews on the subject. The book is intended as a reference work, placing at the researcher's command practically all of the over 1500 references on the subject up, and into 1999, organized both according to the ligand type and according to the metal or metalloid being coordinated. It acquaints the reader with the special features of this ligand system and permits an assessment of what has been done in a given sub-area, and of which areas remain relatively unexplored. It presents procedures for ligand synthesis, and also covers their use in catalysis and in the modelling of biologically active substances.
EPA's expanded interpretation of its permit veto authority under the Clean Water Act : hearing before the Subcommittee on Water Resources and Environment of the Committee on Transportation and Infrastructure, House of Representatives, One Hundred Thirteenth Congress, second session, July 15, 2014.
Describes over 200 laboratory and field chemical tests relevant to Australasia and beyond.
The interest in tetrathiafulvalene (TTF) chemistry has grown tremendously since the first successful synthesis of TTF in 1970. This is because TTFs serve as potent electron donors to obtain organic metals and organic superconductors. They continue to show great promise of development in molecular, supramolecular and materials chemistry in the future. This is the first book covering almost all the TTFs and related analogues so far synthesized by researchers worldwide. The volume comprises 17 chapters, each with the synthetic methods, structural characteristics, physical properties and applications of various TTFs.
Chemistry seeks to provide qualitative and quantitative explanations for the observed behaviour of elements and their compounds. Doing so involves making use of three types of representation: the macro (the empirical properties of substances); the sub-micro (the natures of the entities giving rise to those properties); and the symbolic (the number of entities involved in any changes that take place). Although understanding this triplet relationship is a key aspect of chemical education, there is considerable evidence that students find great difficulty in achieving mastery of the ideas involved. In bringing together the work of leading chemistry educators who are researching the triplet relationship at the secondary and university levels, the book discusses the learning involved, the problems that students encounter, and successful approaches to teaching. Based on the reported research, the editors argue for a coherent model for understanding the triplet relationship in chemical education.
This long-awaited reference source is the first book to focus on this important and hot topic. As such, it provides examples from a wide array of fields where catalyst design has been based on new insights and understanding, presenting such modern and important topics as self-assembly, nature-inspired catalysis, nano-scale architecture of surfaces and theoretical methods. With its inclusion of all the useful and powerful tools for the rational design of catalysts, this is a true "must have" book for every researcher in the field.
Wine chemistry inspires and challenges with its complexity, and while this is intriguing, it can also be a barrier to further understanding. The topic is demystified in Understanding Wine Chemistry, Special Mention awardee in the 2018 OIV awards, which explains the important chemistry of wine at the level of university education, and provides an accessible reference text for scientists and scientifically trained winemakers alike. Understanding Wine Chemistry: Summarizes the compounds found in wine, their basic chemical properties and their contribution to wine stability and sensory properties Focuses on chemical and biochemical reaction mechanisms that are critical to wine production processes such as fermentation, aging, physiochemical separations and additions Includes case studies showing how chemistry can be harnessed to enhance wine color, aroma, flavor, balance, stability and quality. This descriptive text provides an overview of wine components and explains the key chemical reactions they undergo, such as those controlling the transformation of grape components, those that arise during fermentation, and the evolution of wine flavor and color. The book aims to guide the reader, who perhaps only has a basic knowledge of chemistry, to rationally explain or predict the outcomes of chemical reactions that contribute to the diversity observed among wines. This will help students, winemakers and other interested individuals to anticipate the effects of wine treatments and processes, or interpret experimental results based on an understanding of the major chemical reactions that can occur in wine.
In this edited collection, the authors pick up the communities of practice (CoP) approach of sharing practice in their reflection on the experience of taking their CoP vision from a dream to reality. Their stories articulate the vision, the passion and the challenge of working within and/or changing existing institutional culture and practice. The book discusses strategies that worked and considers the lessons learnt to inspire future dreamers and schemers. The multiple perspectives provided in the case studies will assist higher education leaders, as well as academic and professional staff, in establishing or assessing CoPs. The book offers insights into implementation strategies, practical guidelines and ideas on how CoP theoretical underpinnings can be tailored to the higher education context.