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Analysis of rocks and minerals often requires a specific approach, especially when determining rare and scattered elements, the content of which can be extremely low. This volume presents the main principles of analytical techniques most commonly used in the determination of the chemical composition of minerals and rocks. Special attention is given to methodological features and analytical schemes of various minerals, methods of mineral stripping and use of hybrid methods of analysis.
Analytical Chemistry in the Exploration, Mining and Processing of Materials is a collection of plenary lectures presented at the International Symposium on Analytical Chemistry in the Exploration, Mining, and Processing of Materials, held in Johannesburg, South Africa, on August 23-27, 1976. Contributors explore the applications of analytical chemistry in the exploration, mining, and processing of materials and cover topics ranging from the role of reference materials in analytical chemistry to analytical requirements in exploration geochemistry, along with activation analysis of ores and minerals. This book is comprised of 15 chapters and begins with a discussion on the analytical needs for primary coal covering three sets of parameters associated with chemical quality, physical nature and condition, and rank fundamental properties. The reader is then introduced to coal products (coke, tar, gas) and their analysis; analytical chemistry of the noble metals; use of chromatography in the analysis of inorganic materials; and developments in wavelength and energy dispersive spectrometry, Subsequent chapters deal with optical emission spectrochemical analysis; automated on-line analysis for controlling industrial processes; and atomic absorption spectroscopy and its applications. This monograph will be a useful resource for chemists, metallurgists, materials scientists, and mining engineers.
This book has developed from a short residential course organised by the Department of Minerals Engineering and the Department of Extra Mural Studies of the University of Birmingham. The course was concerned mainly with physical methods of analysis of minerals and mineral products, and particular regard was given to 'non-destructive' methods, with special emphasis on newly available techniques but with a review of older methods and their recent developments included therein. Mineral analysis is obviously of great importance in all the stages of mineral exploration, processing, and utilisation. Selection of a method for a particular mineral or mineral product will depend upon a number of factors, primarily whether an elementary analysis or a phase or structure analysis is required. It will also depend upon the accuracy required. The chapters in the book covering the different methods show the range of useful applicability of the methods considered and should prove valuable as an aid or methods for a given set of circumstances. in selecting a suitable method The book, referring as it does to the majority of the instrumental methods available today (as well as, for comparison, a useful contribution on the place of classical wet chemical analysis) will be valuable to the student as well as to those analysts, research workers, and process engineers who are concerned with the winning, processing, and utilisation of minerals and mineral products.
Reagents in Mineral Technology provides comprehensive coverage of both basic as well asapplied aspects of reagents utilized in the minerals industry.This outstanding, single-source reference opens with an explicit account of flotation fundamentals,including coverage of wetting phenomena, mineral/water interfacial phenomena, flo tationchemistry, and flocculation and dispersion of mineral suspensions.It then discusses flotation of sulfide and nonsulfide minerals, with attention to formation ofclithiolates, formation of metal thiol compounds, application of fatty acids, sulfosuccinic acids,amines, and other collectors.Reagents in Mineral Technology also reviews adsorption of surfactants on minerals .. .details adsorption of polymers .. . and considers the chemistry and application of chelation agentsin minerals separations.Additional chapters consider grinding aids, frothers, inorganic and polymeric depressants,dewatering and filtering aids, analytical techniques, and much more.Unique in its depth of coverage, Reagents in Mineral Technology will prove an invaluablereference for mineral engineers and processors; analytical, surface, colloid, and physical chemists;petroleum, petrochemical, metallurgical, and mining engineers; and for use in advancedundergraduate- and graduate-level courses in these and related fields.
A practical guide to the methods in general use for the complete analysis of silicate rock material and for the determination of all those elements present in major, minor or trace amounts in silicate and other rocks that are routinely, commonly or occasionally determined by methods that are considered to be essentially chemical in character. Such methods include those based upon spectrophotometry, flame emission spectrometry and atomic absorption spectroscopy, as well as gravimetry, titrimetry and the use of ion-selective electrodes. Separation stages are described in full, using precipitation, solvent extraction, distillation, and ion-ex procedures as appropriate. The third edition has been fully revised and updated.
Volume 31 of Reviews in Mineralogy reviews current thinking on the fundamental processes that control chemical weathering of silicates, including the physical chemistry of reactions at mineral surfaces, the role of experimental design in isolating and quantifying these reactions, and the complex roles that water chemistry, hydrology, biology, and climate play in weathering of natural systems. The chapters in this volume are arranged to parallel this order of development from theoretical considerations to experimental studies to characterization of natural systems. Secondly, the book is meant to serve as a reference from which researchers can readily retrieve quantitative weathering rate data for specific minerals under detailed experimental controls or for natural weathering conditions. Toward this objective, the authors were encouraged to tabulate available weathering rate data for their specific topics. Finally this volume serves as a forum in which suggestions and speculations concerning the direction of future weathering research are discussed.
International Series of Monographs on Analytical Chemistry, Volume 10: The Analytical Chemistry of Thorium focuses on the composition, properties, and reactions of thorium. The book first discusses the occurrence of thorium and its properties. Topics include the position of thorium in the periodic system; methods of preparation for metallic thorium; and radioactivity of thorium isotopes. The text surveys the chemical and physical methods in identifying thorium. Gravimetric and fluorescence methods; detection and estimation of thorium by spectroscopic and X-ray analysis; and colorimetric and spectrophotometric methods are discussed. The text also examines the methods of separating thorium from associated elements. The separation of thorium from rare earths, scandium, titanium, uranium, lead, alkali metals, gallium, and beryllium is underscored. The text also discusses the determination of thorium in natural and industrial materials. Regeneration of thorium from industrial waste; isolation of thorium from ores and minerals; and analysis of alloys containing thorium are explained. The book is a valuable source of data for students and chemists wanting to study thorium.
Surface and Interface Chemistry of Clay Minerals, Volume 9, delivers a fundamental understanding of the surface and interface chemistry of clay minerals, thus serving as a valuable resource for researchers active in the fields of materials chemistry and sustainable chemistry. Clay minerals, with surfaces ranging from hydrophilic, to hydrophobic, are widely studied and used as adsorbents. Adsorption can occur at the edges and surfaces of clay mineral layers and particles, and in the interlayer region. This diversity in properties and the possibility to tune the surface properties of clay minerals to match the properties of adsorbed molecules is the basis for study. This book requires a fundamental understanding of the surface and interface chemistry of clay minerals, and of the interaction between adsorbate and adsorbent. It is an essential resource for clay scientists, geologists, chemists, physicists, material scientists, researchers, and students. - Presents scientists and engineers with a resource they can rely on for their own research and work involving clay minerals - Includes an in-depth look at ion exchange, adsorption of inorganic and organic molecules, including polymers and proteins, and catalysis occurring at the surfaces of clay minerals - Includes materials chemistry of clay minerals with chiral clay minerals, optical materials and functional films
This book covers the entire spectrum of mineralogy and consolidates its applications in different fields. Part I starts with the very basic concept of mineralogy describing in detail the implications of the various aspects of mineral chemistry, crystallographic structures and their effects producing different mineral properties. Part II of the book describes different aspects of mineralogy like geothermobarometry, mineral thermodynamics and phase diagrams, mineral exploration and analysis, and marine minerals. Finally Part III handles the applications in industrial, medicinal and environmental mineralogy along with precious and semiprecious stone studies. The various analytical techniques and their significance in handling specific types of mineralogical problems are also covered.