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This comprehensive reference describes investigations of the fate of toxic chemicals emanating from hazardous waste sites and contaminating groundwater, discussing the hydrogeochemistry at US, Canadian, Australian, and German sites to reflect the different approaches used around the world.;Written by over 30 international experts in the field, Groundwater Contamination and Analysis at Hazardous Waste Sites: presents case histories spanning 30 years of activities by the United States Geological Survey's Organics in Water project, including studies of pesticide, munition, and wood preservative residues contaminating groundwater; outlines the U.S. Environmental Protection Agency's SW-846 methods of analysis for groundwater samples taken at hazardous waste sites; details the analytical requirements for qualitative surveys, regulatory compliance, and research programs; examines the use of statistics at site investigations and waste disposal facilities as well as data interpretation techniques such as multivariate plots; covers the application of a portable gas chromatograph in studying a vapor-phase plume of trichloroethylene, giving tips about problems that may lead to variability in the data; and explores dense nonaqueous-phase liquid dissolution using Raoult's law, biotransformation of the dissolved constituents, and their sorption to aquifer materials.;Extensively illustrated with more than 250 figures, tables, and display equations, Groundwater Contamination and Analysis at Hazardous Waste Sites is a practical tool for pollution control and environmental engineers, hydrogeologists, analytical chemists, and upper-level undergraduate and graduate students in these disciplines.
Fractured rock is the host or foundation for innumerable engineered structures related to energy, water, waste, and transportation. Characterizing, modeling, and monitoring fractured rock sites is critical to the functioning of those infrastructure, as well as to optimizing resource recovery and contaminant management. Characterization, Modeling, Monitoring, and Remediation of Fractured Rock examines the state of practice and state of art in the characterization of fractured rock and the chemical and biological processes related to subsurface contaminant fate and transport. This report examines new developments, knowledge, and approaches to engineering at fractured rock sites since the publication of the 1996 National Research Council report Rock Fractures and Fluid Flow: Contemporary Understanding and Fluid Flow. Fundamental understanding of the physical nature of fractured rock has changed little since 1996, but many new characterization tools have been developed, and there is now greater appreciation for the importance of chemical and biological processes that can occur in the fractured rock environment. The findings of Characterization, Modeling, Monitoring, and Remediation of Fractured Rock can be applied to all types of engineered infrastructure, but especially to engineered repositories for buried or stored waste and to fractured rock sites that have been contaminated as a result of past disposal or other practices. The recommendations of this report are intended to help the practitioner, researcher, and decision maker take a more interdisciplinary approach to engineering in the fractured rock environment. This report describes how existing tools-some only recently developed-can be used to increase the accuracy and reliability of engineering design and management given the interacting forces of nature. With an interdisciplinary approach, it is possible to conceptualize and model the fractured rock environment with acceptable levels of uncertainty and reliability, and to design systems that maximize remediation and long-term performance. Better scientific understanding could inform regulations, policies, and implementation guidelines related to infrastructure development and operations. The recommendations for research and applications to enhance practice of this book make it a valuable resource for students and practitioners in this field.
Sponsored by the Natural Attenuation Task Committee of the Environmental and Multi-Media Council of the Environmental and Water Resources Institute of ASCE. This report provides the regulatory framework, scientific and engineering principles, and applications of natural attenuation for the remediation of contaminated sites. Natural attenuation is a process that relies on the natural assimilative capacity of a site to reduce or stabilize contaminates to desirable levels. It is becoming an increasingly popular, cost-effective remedial alternative for many contaminated sites. The report describes in detail sites contaminated with petroleum hydrocarbons and MTBE, chlorinated solvents, polycyclic aromatic hydrocarbons, metals, and radioactive wastes. Topics include: Ømajor pollutants; Øextensive review of literature; Øexamples of applications of natural attenuation; Øsite characterization and monitoring requirements and procedures; and Øbasic scientific principles on physical, chemical, and biological processes. Environmental engineers and scientists will find this book full of information on basic principles to summaries of natural attenuation applications.
Provides a detailed background of the technologies available for the bioremediation of contaminated soil & ground water. Prepared for scientists, consultants, regulatory personnel, & others who are associated in some way with the restoration of soil & ground water at hazardous waste sites. Also provides insights to emerging technologies which are at the research level of formation, ranging from theoretical concepts, through bench scale inquiries, to limited field-scale investigations. 95 tables & figures.
The 52nd Purdue Industrial Waste Conference showcased 18 sessions on subjects such as biological aspects, physical-chemical aspects, oil and petroleum wastes, management and reuse strategies, international activities, and pollution prevention. This book compiles the work of nearly 200 international experts, covering the latest practical techniques, advanced research, new methods, actual operating data, and important case studies.
The introduction of synthetic organic chemicals into the environment during the last few decades has given rise to major concern about the ecotoxicological effects and ultimate fate of these compounds. The pollutants that are considered to be most hazardous because of their intrinsic toxicity, high exposure level, or recalcitrant behavior in the environment have been placed on blacklists and other policy priority lists. The fate of synthetic compounds that enter the environment is mainly determined by their rate of biodegradation, which therefore also has a major effect on the degree of bioaccumulation and the risk of ecotoxicological effects. The degree and rate of biodegradation is also of critical importance for the feasibility of biological techniques to clean up contaminated sites and waste streams. The biodegradation of xenobiotics has thus been the subject of numerous studies, which resulted in thousands of publications in scientific journals, books, and conference proceedings. These studies led to a deeper understanding of the diversity of biodegradation processes. As a result, it has become possible to enhance the rate of degradation of recalcitrant pollutants during biological treatment and to design completely new treatment processes. At present, much work is being done to expand the range of pollutants to which biodegradation can be applied, and to make treatment techniques less expensive and better applicable for waste streams which are difficult to handle.