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Amorphous and nanocrystalline materials are a class of their own. Their properties are quite different to those of the corresponding crystalline materials. This book gives systematic insight into their physical properties, structure, behaviour, and design for special advanced applications.
Amorphous-nanocrystalline alloys are a new class of materials born at the turn of the 20th and 21st centuries as a result of the rapid development of new technologies and, in particular, nanotechnology They arose at the intersection of intensive research and development of promising amorphous and nanocrystalline materials. In terms of the level of physical and mechanical properties, two-phase amorphous-nanocrystalline materials in some cases exceed the properties of both nanocrystalline and amorphous materials, thereby creating a noticeable synergistic effect. In this book, the methods of obtaining amorphous-crystalline materials (quenching from a melt, controlled crystallization, deformation effect, pulsed [photon, laser and ultrasonic] treatment thin film deposition, and ion implantation) are considered successively. Detailed information is then given on the structural features of the transition from the amorphous phase state to the nanocrystalline state under thermal and deformation effects. Theoretical and experimental studies are analyzed in which the mechanisms of plastic deformation and the features of the emerging physico-mechanical properties are described. The authors then go on to describe areas of practical application of amorphous-nanocrystalline alloys. This book is a comprehensive resource for specialists in materials, science and nanotechnology, specifically researchers studying crystalline and amorphous materials as it highlights the various properties that are important for practical use. Book jacket.
Amorphous-nanocrystalline alloys are a relatively new class of materials born from the rapid development of new technologies and different methods of producing amorphous and nanocrystalline powders and films, compacting, melt quenching, megaplastic deformation, implantation, laser, plasma, and other high-energy methods. This book considers methods of producing these materials (melt quenching, controlled crystallization, deformation effect, and pulse treatments (photon, laser and ultrasound), spraying thin films, and ion implantation). Theoretical and experimental studies describe plastic deformation mechanisms and physico-mechanical properties. Practical applications are also presented.
Reflecting the fast pace of research in the field, the Second Edition of Bulk Metallic Glasses has been thoroughly updated and remains essential reading on the subject. It incorporates major advances in glass forming ability, corrosion behavior, and mechanical properties. Several of the newly proposed criteria to predict the glass-forming ability of alloys have been discussed. All other areas covered in this book have been updated, with special emphasis on topics where significant advances have occurred. These include processing of hierarchical surface structures and synthesis of nanophase composites using the chemical behavior of bulk metallic glasses and the development of novel bulk metallic glasses with high-strength and high-ductility and superelastic behavior. New topics such as high-entropy bulk metallic glasses, nanoporous alloys, novel nanocrystalline alloys, and soft magnetic glassy alloys with high saturation magnetization have also been discussed. Novel applications, such as metallic glassy screw bolts, surface coatings, hyperthermia glasses, ultra-thin mirrors and pressure sensors, mobile phone casing, and degradable biomedical materials, are described. Authored by the world’s foremost experts on bulk metallic glasses, this new edition endures as an indispensable reference and continues to be a one-stop resource on all aspects of bulk metallic glasses.
Index of amorphous alloys
A detailed presentation of the physics of the various hysteresis models that are currently used to explain the magnetization reversal process, including coherent and incoherent magnetization processes, micromagnetism and its application in thin films, multilayers, nanowires, particles and bulk magnets, domain wall pinning and domain wall dynamics, and Preisach modelling. Some of the faulty concepts and interpretations that still exist in the literature are rectified. Magnetic imaging techniques are reviewed, including TEM, SEM, magnetic force microscopy, and optical microscopy. Temperature, field and angular dependence of coercivity, magnetic interactions and magnetic phenomena are reviewed and their effect on magnetic hysteresis is discussed. The magnetic properties of novel materials are discussed, including nanoparticles, nanocrystalline granular solids, particulate media, thin films, and bulk magnets. Finally, present and future applications of novel materials are presented, including magnetic and magneto-optic recording media, magneto-electronics, sensors, magnetic circuit design, and novel structures created from rigid, high-energy permanent magnets.
The aim of this NATO ASI has been to present an up-to-date overview of current areas of interest in amorphous materials, with particular emphasis on electronic properties and device applications. In order to limit the material to a manageable amount, the meeting was concerned almost exclusively with semiconducting materials. This volume should be regarded as a follow-on to the NATO ASI held in Sozopol, Bulgaria in 1996 and published as "Amorphous Insulators and Semiconductors" edited by M.F. Thorpe and M.1. Mitkova (Kluwer Academic Publishers, NATO ASI series, 3 High Technology - Vol. 23). The lectures and seminars fill the gap between graduate courses and research seminars. The lecturers and seminar speakers were chosen as experts in their respective areas, and the lectures and seminars that were given are presented in this volume. During the first week of the meeting, an emphasis was placed on introductory lectures while the second week focused more on research seminars. There were two very good poster sessions that generated a lot of discussion, but these are not reproduced in this volume as the editors wanted to have only larger contributions to make the proceedings more coherent.
This book concentrates on both understanding and development of nanocrystalline materials. The original relation that connects grain size and strength, known as the Hall-Petch relation, is studied in the nanometer grain size region. The breakdown of such a relation is a challenge. Why and how to overcome it? Is the dislocation mechanism still operating when the grain size is very small, approaching the amorphous limit? How do we go from the microstructure information to the continuum description of the mechanical properties?
This highly readable, popular textbook for upper undergraduates and graduates comprehensively covers the fundamentals of crystallography and symmetry, applying these concepts to a large range of materials. New to this edition are more streamlined coverage of crystallography, additional coverage of magnetic point group symmetry and updated material on extraterrestrial minerals and rocks. New exercises at the end of chapters, plus over 500 additional exercises available online, allow students to check their understanding of key concepts and put into practice what they have learnt. Over 400 illustrations within the text help students visualise crystal structures and more abstract mathematical objects, supporting more difficult topics like point group symmetries. Historical and biographical sections add colour and interest by giving an insight into those who have contributed significantly to the field. Supplementary online material includes password-protected solutions, over 100 crystal structure data files, and Powerpoints of figures from the book.
Due to a great chemical similarity with the biological calcified tissues, many calcium orthophosphates possess remarkable biocompatibility and bioactivity. Materials scientists use this property extensively to construct artificial bone grafts that are either entirely made of or only surface-coated with the biologically relevant calcium orthophospha