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The need for a broad development of the production of polymer ma terials has become evident. All these materials are subject to various types of aging (destruction); hence, stabilizers which permit the stor age, reprocessing, and use of polymer materials without any appreci able change in their properties must be introduced into them. In recent years, this problem of stabilizing polymers has attracted the attention of many scientists and technologists, both in the USSR and abroad. The scientific basis of the foreign studies will be found in a number of theo retical premises, but chiefly the theory of chain reactions with un branched chains. In the Soviet Union, the concepts of Academician N. N. Semenov on chain reactions with degenerate branches have become the starting point of theoretical studies of the stabilization and destruction of polymers. Soviet scientists have developed a theory of critical concentrations of antioxidants and have shown that the processes of stabilization have a very complex chemical character. The nature of the polymers them selves greatly affects these processes and consequently, different stabil izers are required for polymers of different structures. In addition, it has been shown that the antioxidants used thus far can not only cause chain termination, but can also initiate oxidation and give rise to de generate branches.
Provides a comprehensive overview of the science of polymer durability. Discusses the molecular mechanisms of polymer aging and deterioration, emphasizing UV and thermal exposure environments. Describes a variety of analytical techniques for studying degradation, with special emphasis on chemiluminescence. Covers advances in the use of additives and other approaches for enhancing polymer stability. Reviews mechanisms and applications of major classes of stabilizers, and discusses the problem of stabilizer migration and loss. Examines new methods for predicting the aging rate and lifetime of a material.
The second edition of this textbook is identical with its fourth German edi tion and it thus has the same goals: precise definition of basic phenomena, a broad survey of the whole field, integrated representation of chemistry, physics, and technology, and a balanced treatment of facts and comprehen sion. The book thus intends to bridge the gap between the often oversimpli fied introductory textbooks and the highly specialized texts and monographs that cover only parts of macromolecular science. The text intends to survey the whole field of macromolecular science. Its organization results from the following considerations. The chemical structure of macromolecular compounds should be inde pendent of the method of synthesis, at least in the ideal case. Part I is thus concerned with the chemical and physical structure of polymers. Properties depend on structure. Solution properties are thus discussed in Part 11, solid state properties in Part Ill. There are other reasons for dis cussing properties before synthesis: For example, it is difficult to understand equilibrium polymerization without knowledge of solution thermodynamics, the gel effect without knowledge of the glass transition temperature, etc. Part IV treats the principles of macromolecular syntheses and reactions.
Accelerated Aging: Photochemical and Thermal Aspects represents the culmination of more than 40 years of research by noted scientist Robert L. Feller. The book focuses on the long-term performance of materials such as wool, dyes, and organic compounds; their resistance to change when exposed to environmental factors such as oxygen, ozone, moisture, heat, and light; and their physical durability with handling and use over time. Processes of deterioration are discussed based on speeded-up laboratory studies designed to clarify the chemical reactions involved and their physical consequences.
Plastics are used worldwide in everyday life, e.g. as food packaging, electronics, construction, automotive parts, and household appliances. To produce these products with the desired service lifetimes the use of suitable stabilizers is necessary. This book provides a concise and comprehensive overview of the basic mechanisms of plastic degradation processes caused by heat and light. At its core is a detailed description of the stabilization of different polymers, including an explanation of stabilization mechanisms and the influence of commonly used additives such as fillers, flame retardents and pigments on the stability of plastic. Every polymer scientist, material technologist, or application engineer dealing with the design of the properties of plastics will benefit from this new overview.
The stability and resistance of polymeric materials determine whether they can be utilized in a given application. Authoritative and reliable material information is needed during the material selection process and this information must consider the influences of material manufacturing, compounding and stabilization, processing, part design, use and subsequent disposal/recycling. This book is based on the review of more than 1200 literature sources and represents a comprehensive overview of the current know-how regarding the stability and resistance of thermoplastics, thermosets, elastomers as well as the most commonly used reinforcements and additives. Extensive tables document material resistance to given media, facilitating appropriate material selection or stabilization for a given application. Contents Volume 1: Principles of Aging Testing Methods Stabilization Influence of Processing and Use Resistance to Thermal and Thermal-Oxidative Loads, Weathering, Chemicals, Ionizing Radiation, Microorganisms, Biological Influences, and Mechanical Loads Creep and Fatigue of Reinforced Polymers Contents Volume 2: Chemical Resistance Tables White Lists of Media Influence (According to DIBt) References Index
This collection focuses on the characterization of minerals, metals, and materials as well as the application of characterization results on the processing of these materials. Papers cover topics such as clays, ceramics, composites, ferrous metals, non-ferrous metals, minerals, electronic materials, magnetic materials, environmental materials, advanced materials, and soft materials. In addition, papers covering materials extraction, materials processing, corrosion, welding, solidification, and method development are included. This book provides a current snapshot of characterization in materials science and its role in validating, informing, and driving current theories in the field of materials science. This volume will serve the dual purpose of furnishing a broad introduction of the field to novices while simultaneously serving to keep subject matter experts up-to-date.
Service Life Prediction of Polymers and Plastics Exposed to Outdoor Weathering discusses plastics and polymers and their unique applications, from sealants used in construction, to polymer composites used in planes. While these materials are important enablers for advanced technologies, exposure to weather changes the very properties of plastics that make them so useful. This book reviews current research needs and provides a consensus roadmap of the scientific barriers to validated predictive models for the response of polymers and plastics to outdoor exposure. Despite extensive efforts over the past 20-30 years, testing of polymeric materials in accelerated or natural weathering conditions and the interpretation of the weathering results still require substantial improvements. This book represents the state-of-the-art in the prediction techniques available and in development. Engineers and materials scientists working in this field will be able to use the content of this book to assess the strengths and challenges of a range of different methods and approaches. - Enables engineers and scientists in a range of industries to more successfully predict the durability of polymers, paints and coatings when exposed to weather - Provides the latest information to help determine the sustainability of polymeric materials - Reviews the current state-of-the-art in this area and identifies research needs that are followed by more detailed discussions of specific polymers and applications