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Multivalent-ion batteries, as promising alternative or supplementary technologies to lithium-ion batteries, have increasingly attracted attention recently. Various advanced materials have been presented to pursue potential breakthroughs in energy and power. Among them, vanadium (V)-based materials benefiting from abundant resources, various polymorphs and valences, especially most with large interlayer spacings, are good candidates for multivalent-ion storage. However, limited by multiple inherent issues, e.g., strong electrostatic interactions, poor electronic conductivity, structure collapse or materials dissolution under battery operation, etc., various strategies have sprung many advanced materials and applications and also brought about new challenges that are in urgent need to clarify and summarize. Hence, advanced V-based compounds developed for multivalent-ion storage in the past few years are selectively summarized and systematically analyzed, including vanadium oxides and sulfides, vanadates, and V-based MXenes and phosphates. Not only crystal structures and electrochemical properties but also mainstream ion storage mechanisms are critically reviewed. Through analyzing the challenges accompanying multivalent-ion storage, potential opportunities are anticipated.
The Li-ion battery market is growing fast due to its ever increasing number of applications, from electric vehicles to portable devices. These devices are in demand due to safety reasons, energy efficiency, high power density and long life duration, which drive the need for more efficient electrochemical energy storage systems. The aim of this book is to provide the challenges and perspectives for Li-ion batteries (chapters 1 and 2), at the negative electrode as well as at the positive electrode, and for technologies beyond the Li-ion with the emerging Na-ion batteries and multivalent (Mg, Al, Ca, etc) systems (chapters 4 and 5). The aim is also to alert on the necessity to develop the recycling methods of the millions of produced batteries which are going to further flood our societies (chapter 3), and also to continuously increase the safety of the energy storage systems. For the latter challenge, it is interesting to seriously consider polymer electrolytes and batteries as an alternative (chapter 6).This book will take readers inside recent breakthroughs made in the electrochemical energy systems. It is a collaborative work of experts from the most known teams in the batteries field in Europe and beyond, from academics as well as from manufacturers.
Aqueous Zinc Ion Batteries Pioneering reference book providing the latest developments and experimental results of aqueous zinc ion batteries Aqueous Zinc Ion Batteries comprehensively reviews latest advances in aqueous zinc ion batteries and clarifies the relationships between issues and solutions for the emerging battery technology. Starting with the history, the text covers essentials of each component of aqueous zinc ion batteries, including cathodes, anodes, and electrolytes, helping readers quickly attain a foundational understanding of the subject. Written by three highly qualified authors with significant experience in the field, Aqueous Zinc Ion Batteries provides in-depth coverage of sample topics such as: History, main challenges, and zinc metal anodes for aqueous zinc ion batteries Electrochemical reaction mechanism of aqueous zinc ion batteries and interfacial plating and stripping on zinc anodes Cathode materials for aqueous zinc ion batteries, covering manganese-based materials, vanadium-based materials, Prussian blue analogs, and other cathode materials Development of electrolytes, issues, and corresponding solutions for aqueous zinc ion batteries Separators for aqueous zinc ion batteries, development of full zinc ion batteries, and future perspectives on the technology A detailed resource on a promising alternative to current lithium-ion battery systems, Aqueous Zinc Ion Batteries is an essential read for materials scientists, electrochemists, inorganic chemists, surface chemists, catalytic chemists, and surface physicists who want to be on the cutting edge of a promising new type of battery technology.
This book focusses on the current research on materials for advanced battery technologies and proposes future directions for different types of batteries to meet the current challenges associated with the fuel cell. Furthermore, it provides insights into scientific and practical issues in the development of various batteries like sodium, potassium, zinc, magnesium, aluminum, calcium, and dual metal ion, to bring a new perspective to storage technologies beyond lithium-ion batteries. It introduces different themes of batteries to evaluate the opportunities and challenges of these battery systems from a commercial aspect. Key features: Deals with different potential rechargeable battery systems as suitable substitutes for LIBs Discusses different investigated materials as anode, cathode, and electrolytes for different energy storage systems Provides a complete and comprehensive review of all the existing metal-ion batteries Includes practical challenges and future opportunities of each battery category Reviews commercial aspects of different battery systems This book is aimed at researchers, graduate students, and professionals in industrial and applied chemistry, renewable energy, clean and sustainable processes, chemical engineering, materials science, nanotechnology, and battery chemistry.
The electrochemical storage of energy has become essential in assisting the development of electrical transport and use of renewable energies. French researchers have played a key role in this domain but Asia is currently the market leader. Not wanting to see history repeat itself, France created the research network on electrochemical energy storage (RS2E) in 2011. This book discusses the launch of RS2E, its stakeholders, objectives, and integrated structure that assures a continuum between basic research, technological research and industries. Here, the authors will cover the technological advances as well as the challenges that must still be resolved in the field of electrochemical storage, taking into account sustainable development and the limited time available to us.
Renewable and Clean Energy Systems Based on Advanced Nanomaterials: Basis, Preparation and Applications describes the fundamental aspects of a diverse range of nanomaterials used in the fields of renewable and clean energy. Various methods of preparing several different nanomaterials for green energy systems, such as advanced nanomaterials for solar cells, mixed metal oxide-based nanomaterials for hydrogen storage, and active nanomaterials for Li ion batteries are presented along with their advantages, disadvantages, and applications. Chapters also discuss novel methods of power analysis, frequency regulation methods, practical applications of solar panels, economic efficiency of solar energy, solar physics, and much more.This is a valuable resource on the basic science, preparation methods, and practical applications of advanced nanomaterials for green energy systems. - Features recent advances on nanomaterials preparation methods and their applications in photovoltaic technology - Discusses sustainable strategies for producing large-scale nanomaterials, focusing on preparation techniques that are cost-effective and eco-friendly - Reviews the efficiency of nanomaterials used in solar energy storage and conversion
This is the first comprehensive book covering all aspects of the use of carbonaceous materials in heterogeneous catalysis. It covers the preparation and characterization of carbon supports and carbon-supported catalysts; carbon surface chemistry in catalysis; the description of catalytic, photo-catalytic, or electro-catalytic reactions, including the development of new carbon materials such as carbon xerogels, aerogels, or carbon nanotubes; and new carbon-based materials in catalytic or adsorption processes. This is a premier reference for carbon, inorganic, and physical chemists, materials scientists and engineers, chemical engineers, and others.
This book describes the rapidly expanding field of two-dimensional (2D) transition metal carbides and nitrides (MXenes). It covers fundamental knowledge on synthesis, structure, and properties of these new materials, and a description of their processing, scale-up and emerging applications. The ways in which the quickly expanding family of MXenes can outperform other novel nanomaterials in a variety of applications, spanning from energy storage and conversion to electronics; from water science to transportation; and in defense and medical applications, are discussed in detail.
An examination of applications of electrochemical techniques to many organic and inorganic compounds that are either unstable or insoluble in water. It focuses on the continuing drive toward miniaturization in electronics met by designs for high-energy density batteries (based on nonaqueous systems). It addresses applications to nonaqueous batteries, supercapacitators, highly sensitive reagents, and electroorganic and electroinorganic synthesis.
This volume focuses on alkaline metal-ion, redox flow, and metal sulfur batteries and provides details about the various kinds of advanced rechargeable batteries. It explains magnesium-ion batteries, sodium-ion batteries, metal sulfur batteries, and redox flow batteries with an introduction to rechargeable batteries and major upcoming batteries (magnesium-/sodium-ion batteries). Various kinds of redox flow batteries from introduction extending to the recent progress in redox flow batteries have been extensively discussed. Features: Covers recent battery technologies in detail, from chemistry to advances in post-lithium-ion batteries. Reviews magnesium-ion batteries, sodium-ion batteries, metal sulfur batteries, and redox flow batteries. Explains various metal sulfur batteries. Explores different types of redox flow batteries for large-scale energy storage application. Provides authoritative coverage of scientific contents via global contributing experts. This book is aimed at graduate students, researchers, and professionals in materials science, chemical and electrical engineering, and electrochemistry.