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Research for the development of more efficient photocatalysts has experienced an almost exponential growth since its popularization in early 1970’s. Despite the advantages of the widely used TiO2, the yield of the conversion of sun power into chemical energy that can be achieved with this material is limited prompting the research and development of a number of structural, morphological and chemical modifications of TiO2 , as well as a number of novel photocatalysts with very different composition. Design of Advanced Photocatalytic Materials for Energy and Environmental Applications provides a systematic account of the current understanding of the relationships between the physicochemical properties of the catalysts and photoactivity. The already long list of photocatalysts phases and their modifications is increasing day by day. By approaching this field from a material sciences angle, an integrated view allows readers to consider the diversity of photocatalysts globally and in connection with other technologies. Design of Advanced Photocatalytic Materials for Energy and Environmental Applications provides a valuable road-map, outlining the common principles lying behind the diversity of materials, but also delimiting the imprecise border between the contrasted results and the most speculative studies. This broad approach makes it ideal for specialist but also for engineers, researchers and students in related fields.
Semiconductor photocatalysts have attracted a great amount of multidiscipline research due to their high potential for solar-to-chemical-energy conversion applications, ranging from water and air purification to hydrogen and chemical fuel production. This unique diversity of photoinduced applications has spurred major research efforts on the rational design and development of photocatalytic materials with tailored structural, morphological, and optoelectronic properties in order to promote solar-light harvesting, easy photogenerated electron-hole recombination and the concomitant low quantum efficiency. This book presents a collection of original research articles on advanced photocatalytic materials, synthesized by novel fabrication approaches and/or innovative modifications that improve their performance in target photocatalytic applications such as water (cyanobacterial toxins, antibiotics, phenols, and dyes) and air (NOx and volatile organic compounds) pollutant degradation, hydrogen evolution, and hydrogen peroxide production by photoelectrochemical cells.
This book serves the environmentalists to track the development of photocatalytic materials and technology in the present context and to explore future trends. Photocatalysis is the most influential greener technology being researched, developed and adopted for the treatment of wastewater. The technological advancements in the area of smart hybrid photocatalytic materials have gained momentum in the present era. The rational designing of photocatalytic materials with a multi-pronged approach opens a new chapter for environmental detoxification. Other important aspects relate to the transfer of this nanostructured photocatalytic technology to real backdrops. Harnessing natural solar energy for energy and environmental roles is another crucial criterion in designing photocatalysts.
Surface Science of Photocatalysis, Volume 32, summarizes significant findings on the surface science behind various classic and novel photocatalysts for energy and environmental applications, with special emphasis on important surface/interface processes in photocatalysis, such as interfacial charge transfer, function of co-catalysts, and adsorption over photocatalyst surface. This book timely and systematically reviews the state-of-the-art of the surface science in semiconductor-based photocatalysis, serving as a useful reference book for both new and experienced researchers in this field.
A comprehensive volume on photocatalytic functional materials for environmental remediation As the need for removing large amounts of pollution and contamination in air, soil, and water grows, emerging technologies in the field of environmental remediation are of increasing importance. The use of photocatalysis—a green technology with enormous potential to resolve the issues related to environmental pollution—breaks down toxic organic compounds to mineralized products such as carbon dioxide and water. Due to their high performance, ease of fabrication, long-term stability, and low manufacturing costs, photofunctional materials constructed from nanocomposite materials hold great potential for environmental remediation. Photocatalytic Functional Materials for Environmental Remediation examines the development of high performance photofunctional materials for the treatment of environmental pollutants. This timely volume assembles and reviews a broad range of ideas from leading experts in fields of chemistry, physics, nanotechnology, materials science, and engineering. Precise, up-to-date chapters cover both the fundamentals and applications of photocatalytic functional materials. Semiconductor-metal nanocomposites, layered double hydroxides, metal-organic frameworks, polymer nanocomposites, and other photofunctional materials are examined in applications such as carbon dioxide reduction and organic pollutant degradation. Providing interdisciplinary focus to green technology materials for the treatment of environmental pollutants, this important work: Provides comprehensive coverage of various photocatalytic materials for environmental remediation useful for researchers and developers Encompasses both fundamental concepts and applied technology in the field Focuses on novel design and application of photocatalytic materials used for the removal of environmental contaminates and pollution Offers in-depth examination of highly topical green-technology solutions Presents an interdisciplinary approach to environmental remediation Photocatalytic Functional Materials for Environmental Remediation is a vital resource for researchers, engineers, and graduate students in the multi-disciplinary areas of chemistry, physics, nanotechnology, environmental science, materials science, and engineering related to photocatalytic environmental remediation.
This book describes the photocatalytic mechanism, factors affecting photocatalytic activity, design and preparation of different kinds of nanostructured photocatalysts, and their applications in the environmental and energy fields. Further, it illustrates a broad range of modification methods including ion-doping, heterojunction, noble metal deposition, morphological control and sensitizations, which are used to extend the light absorption range of photocatalysts and reduce recombination between electrons and holes. Promising applications include water splitting, contaminant decomposition and photocatalytic reduction of CO2, which are closely related to environmental redemption and new energy development. The book offers an intriguing and useful guide for a broad readership in various fields of catalysis, material sciences, environment and energy.
Nanotechnology and Photocatalysis for Environmental Applications focuses on nanostructured control, synthesis methods, activity enhancement strategies, environmental applications, and perspectives of semiconductor-based nanostructures. The book offers future guidelines for designing new semiconductor-based photocatalysts, with low cost and high efficiency, for a range of products aimed at environmental protection. The book covers the fundamentals of nanotechnology, the synthesis of nanotechnology, and the use of metal oxide, metal sulfide, and carbon-based nanomaterials in photocatalysis. The book also discusses the major challenges of using photocatalytic nanomaterials on a broad scale. The book then explores how photocatalytic nanomaterials and nanocomposites are being used for sustainable development applications, including environmental protection, pharmaceuticals, and air purification. The final chapter considers the recent advances in the field and outlines future perspectives on the technology. This is an important reference for materials scientists, chemical engineers, energy scientists, and anyone looking to understand more about the photocatalytic potential of nanomaterials, and their possible environmental applications. - Explains why the properties of semiconductor-based nanomaterials make them particularly good for environmental applications - Explores how photocatalytic nanomaterials and nanocomposites are being used for sustainable development applications, including environmental protection, pharmaceuticals, and air purification - Discusses the major challenges of using photocatalytic nanomaterials on a broad scale
With the development of modern society, environmental pollution and energy shortages have become the focus of attention worldwide. Most of the global energy supplies are generated from fossil fuel, which gives rise to environmental pollution and climate change. Photocatalysis technology, which can directly convert solar energy into high value-added fuel and chemical materials or degrade a wide range of organic pollutants into easily degradable intermediates or less toxic small molecular substances, is regarded as one of the most important ways to solve the global energy shortage and environmental pollution problem. This Special Issue focuses on advanced photocatalytic materials, including but not limited to photocatalytic materials for the treatment of indoor air, photocatalytic bacterial inactivation, photocatalytic hydrogen evolution, photocatalytic oxygen evolution, photocatalytic CO2 reduction, photocatalytic hazardous pollutant removal, the photothermal decomposition of pollutants, photoelectrochemical water splitting, etc. This Special Issue provides a platform for scientists to present their original research on "Advanced Photocatalytic Materials for Environmental and Energy Applications".
This critical volume examines the different methods used for the synthesis of a great number of photocatalysts, including TiO2, ZnO and other modified semiconductors, as well as characterization techniques used for determining the optical, structural and morphological properties of the semiconducting materials. Additionally, the authors discuss photoelectrochemical methods for determining the light activity of the photocatalytic semiconductors by means of measurement of properties such as band gap energy, flat band potential and kinetics of hole and electron transfer. Photocatalytic Semiconductors: Synthesis, Characterization and Environmental Applications provide an overview of the semiconductor materials from first- to third-generation photocatalysts and their applications in wastewater treatment and water disinfection. The book further presents economic and toxicological aspects in the production and application of photocatalytic materials.
Photocatalytic nanomaterials have a great potential in such applications as reduction of carbon dioxide and degradation of various pollutants. They are equally important in the production and storage of energy, e.g. in the conversion of solar energy to electricity, and the production of hydrogen in photoelectrochemical cells. Research on synthesis, characterization and specific applications is reported for titanium oxide and a number of other promising catalysts, such as silver phosphate, cerium oxide, zinc oxide and zinc sulfide.