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Biomass conversion into drop-in chemicals using novel heterogeneous bulk- and nano-scale catalysts is currently a hot research topic with the aim of replacing petrochemicals in the chemical industry. Considering the importance of this subject to the scientific community, Advanced Catalysis for Drop-in Chemicals provides the latest developments in the catalytic synthesis of drop-in chemicals mainly from lignocellulose, carbohydrates (cellulose, hemicellulose, C6 and C5 sugars, and their derivatives), lignin, and glycerol. The role of both heterogeneous bulk solid and nanostructured catalysts, along with their advantages and disadvantages for drop-in chemicals synthesis are critically summarized. Addressing the frontiers and prospects for using drop-in chemicals in place of petrochemicals in the chemical industry is also a key topic of this book. - Describes fossil fuels, biomass, drop-in chemicals, catalysis, and nano- and atomic-scale catalysts - Includes pre- and post-treatment strategies for biomass upgrading - Provides green catalytic processes for drop-in chemicals synthesis - Outlines stabilization of nano- and atomic-scale catalysts - Examines using drop-in chemicals in place of petrochemicals in the chemical industry
This book covers advances in the methods of catalytic asymmetric synthesis and their applications. Coverage moves from new materials and technologies to homogeneous metal-free catalysts and homogeneous metal catalysts. The applications of several methodologies for the synthesis of biologically active molecules are discussed. Part I addresses recent advances in new materials and technologies such as supported catalysts, supports, self-supported catalysts, chiral ionic liquids, supercritical fluids, flow reactors and microwaves related to asymmetric catalysis. Part II covers advances and milestones in organocatalytic, enzymatic and metal-based mediated asymmetric synthesis, including applications for the synthesis of biologically active molecules. Written by leading international experts, this book consists of 16 chapters with 2000 References and illustrations of 560 schemes and figures.
"Aimed at master's and Ph. D. students with a limited background in chemistry."--Back cover.
This first of its kind text enables today’s students to understand current and future energy challenges, to acquire skills for selecting and using materials and manufacturing processes in the design of energy systems, and to develop a cross-functional approach to materials, mechanics, electronics and processes of energy production. While taking economic and regulatory aspects into account, this textbook provides a comprehensive introduction to the range of materials used for advanced energy systems, including fossil, nuclear, solar, bio, wind, geothermal, ocean and hydropower, hydrogen, and nuclear, as well as thermal energy storage and electrochemical storage in fuel cells. A separate chapter is devoted to emerging energy harvesting systems. Integrated coverage includes the application of scientific and engineering principles to materials that enable different types of energy systems. Properties, performance, modeling, fabrication, characterization and application of structural, functional and hybrid materials are described for each energy system. Readers will appreciate the complex relationships among materials selection, optimizing design, and component operating conditions in each energy system. Research and development trends of novel emerging materials for future hybrid energy systems are also considered. Each chapter is basically a self-contained unit, easily enabling instructors to adapt the book for coursework. This textbook is suitable for students in science and engineering who seek to obtain a comprehensive understanding of different energy processes, and how materials enable energy harvesting, conversion, and storage. In setting forth the latest advances and new frontiers of research, the text also serves as a comprehensive reference on energy materials for experienced materials scientists, engineers, and physicists. Includes pedagogical features such as in-depth side bars, worked-out and end-of- chapter exercises, and many references to further reading Provides comprehensive coverage of materials-based solutions for major and emerging energy systems Brings together diverse subject matter by integrating theory with engaging insights
This volume looks at modern approaches to catalysis and reviews the extensive literature. Chapters highlight application of 2D materials in biomass conversion catalysis, plasmonic photocatalysis, catalytic demonstration of mesoporosity in the hierarchical zeolite and the effect of surface phase oxides on supported metals and catalysis. Looking to the future a chapter on ab initio machine learning for accelerating catalytic materials discovery is included. Appealing broadly to researchers in academia and industry, these illustrative chapters bridge the gap from academic studies in the laboratory to practical applications in industry not only for catalysis field but also for environmental protection. Other chapters with an industrial perspective include heterogeneous and homogeneous catalytic routes for vinyl acetate synthesis, catalysis for production of jet fuel from renewable sources by HDO/HDC and microwave-assisted catalysis for fuel conversion. Chemical reactions in ball mills is also explored. The book will be of great benefit to any researcher wanting a succinct reference on developments in this area now and looking to the future.
Fundamentals and applications of single-atom catalysts Over the last five years, tremendous advances have been made in heterogeneous catalysis. In particular, catalysts' design from the bulk to single-atom scale (0.1-0.9 nm), with desirable active sites, has received great attention in current catalysis research with the aim to fill the gap between homogeneous and heterogeneous catalysis. This volume focuses on applications of single-atom catalysts. Articles describe principles of single-atom catalysts as well as applications in biomass conversion, water purification, CO2 upgrading, and other specific reactions. Readers will find examples of catalysts designed to be tunable for specific outcomes, inspiring their research. Scientists and engineers in chemistry, materials science, nanotechnology, and chemical engineering will find this volume useful.
Exciting results are still emerging from the many research groups working in this fertile area and the book is an excellent stimulus to researchers at the start of the 21st century."--BOOK JACKET.
The subject of advanced materials in catalysisbrings together recent advancements in materials synthesis and technologies to the design of novel and smart catalysts used in the field of catalysis. Nanomaterials in general show an important role in chemical processing as adsorbents, catalysts, catalyst supports and membranes, and form the basis of cutting-edge technology because of their unique structural and surface properties. Advanced Catalytic Materials is written by a distinguished group of contributors and the chapters provide comprehensive coverage of the current literature, up-to-date overviews of all aspects of advanced materials in catalysis, and present the skills needed for designing and synthesizing advanced materials. The book also showcases many topics concerning the fast-developing area of materials for catalysis and their emerging applications. The book is divided into three parts: Nanocatalysts – Architecture and Design; Organic and Inorganic Catalytic Transformations; and Functional Catalysis: Fundamentals and Applications. Specifically, the chapters discuss the following subjects: Environmental applications of multifunctional nanocomposite catalytic materials Transformation of nanostructured functional precursors using soft chemistry Graphenes in heterogeneous catalysis Gold nanoparticles-graphene composites material for catalytic application Hydrogen generation from chemical hydrides Ring-opening polymerization of poly(lactic acid) Catalytic performance of metal alkoxides Cycloaddition of CO2 and epoxides over reusable solid catalysts Biomass derived fine chemicals using catalytic metal bio-composites Homoleptic metal carbonyls in organic transformation Zeolites: smart materials for novel, efficient, and versatile catalysis Optimizing zeolitic catalysis for environmental remediation
A comprehensive reference to the use of innovative catalysts and processes to turn biomass into value-added chemicals Chemical Catalysts for Biomass Upgrading offers detailed descriptions of catalysts and catalytic processes employed in the synthesis of chemicals and fuels from the most abundant and important biomass types. The contributors?noted experts on the topic?focus on the application of catalysts to the pyrolysis of whole biomass and to the upgrading of bio-oils. The authors discuss catalytic approaches to the processing of biomass-derived oxygenates, as exemplified by sugars, via reactions such as reforming, hydrogenation, oxidation, and condensation reactions. Additionally, the book provides an overview of catalysts for lignin valorization via oxidative and reductive methods and considers the conversion of fats and oils to fuels and terminal olefins by means of esterification/transesterification, hydrodeoxygenation, and decarboxylation/decarbonylation processes. The authors also provide an overview of conversion processes based on terpenes and chitin, two emerging feedstocks with a rich chemistry, and summarize some of the emerging trends in the field. This important book: -Provides a comprehensive review of innovative catalysts, catalytic processes, and catalyst design -Offers a guide to one of the most promising ways to find useful alternatives for fossil fuel resources -Includes information on the most abundant and important types of biomass feedstocks -Examines fields such as catalytic cracking, pyrolysis, depolymerization, and many more Written for catalytic chemists, process engineers, environmental chemists, bioengineers, organic chemists, and polymer chemists, Chemical Catalysts for Biomass Upgrading presents deep insights on the most important aspects of biomass upgrading and their various types.
Horizons in Sustainable Industrial Chemistry and Catalysis, Volume 178, presents a comprehensive picture of recent developments in terms of sustainable industrial processes and the catalytic needs and opportunities to develop these novel routes. Each chapter includes an introduction and state-of-the-art in the field, along with a series of specific aspects and examples. The book identifies new opportunities for research that will help us transition to low carbon and sustainable energy and chemical production. Users will find an integrated view of the new possibilities in this area that unleashes new possibilities in energy and chemistry. - Combines an analysis of each scenario, the state-of-the art, and specific examples to help users better understand needs, opportunities, gaps and challenges - Offers an integrated view of new catalytic technologies that are needed for future use - Presents an interdisciplinary approach that combines broad expertise - Brings together experts in the area of sustainable industrial chemistry