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Advanced and Emerging Polybenzoxazine Science and Technology introduces advanced topics of benzoxazine resins and polybenzoxazines as presented through the collaboration of leading experts in the benzoxazine community, representing the authoritative introduction to the subjects. Broad topics covered include the recent development and improved understanding of the subjects, including low temperature cure, aerogels and carbon aerogels, smart chemistry in fire retarding materials and coatings, metal containing benzoxazines, rational design of advanced properties, and materials from natural renew. In the past twenty years, the number of papers on polybenzoxazine has continuously increased at an exponential rate. During the past three years, the number of papers published is more than the previous 17 years combined. The material is now part of only a few successfully commercialized polymers in the past 35 years. Therefore, interest in this material in both academia and industry is very strong. - Includes the latest advancements in benzoxazine chemistry - Describes advanced materials, such as aerogels, carbons, smart coatings, nanofibers, and shape memory materials - Includes additional characterization data and techniques, such as FT-IR, Raman, NMR, DSC, and TGA analyses
Innovative textile materials are used for numerous applications. Understanding the properties of such materials is imperative to ensure proper utilization. Emergent Research on Polymeric and Composite Materials is an essential reference work featuring the latest scholarly research on the synthesis, characterizations, and physico-chemical properties of textile materials. Including coverage on a range of topics such as nanomaterials, ceramics, and clays, this book is ideally designed for researchers, academicians, industries, and students seeking current research on emerging developments and applications of polymeric and composite materials.
APPLIED COATINGS An integrated collection of case studies providing a concise guide for professionals working with coatings materials in academia and industry In Applied Coatings: Chemistry, Formulation, and Performance, distinguished scientist Dr. Weih Q. Lee delivers an illuminating collection of case studies designed to connect various elements of applied coatings technology. Going beyond generic discussions, the author describes the fundamental chemistry, formulations, and properties of applied coating materials – including the structural and functional components of structure-property relationships – as well as the foundations of applied cure kinetics and the rheology of epoxy coatings. Each chapter is self-contained, comprehensive, and can be read individually, while the book remains technically and editorially integrated. Core themes include structure-performance relationships, formulation index driven experiment design, and consolidated thermal analysis. Readers will also find: A thorough introduction to epoxies and epoxy curing agents, including oxetanes, vinyl esters, glycidyl methacrylate (GMA), isocyanate and silicone crosslinkers, cationic catalysts, acrylate and phenol accelerators, and specialty derivatives Attentive descriptions of epoxy curing chemistry, including epoxy-phenolic, -polyamide, -active ester, and acid- or base-catalyzed systems in a broader scope Comprehensive explorations of cure kinetics and rheology, including model-free kinetics (MFK), the nth-order model covering Kissinger plots and the Borchardt—Daniels (BD) approach, the autocatalytic model, executive quantification via curve fitting of DSC (differential scanning calorimetry) exotherms, the rheology of non-reactive fluids, and the viscoelasticity of reactive coatings Practical discussions of C1S thick-film surface coatings, C2S structural lamination, liquid and powder epoxies, and phenolic coatings, including fluorene monomers, heterocyclic resins, and polymerizable derivatives Complete treatments of coating characterization, microencapsulation, epoxy hybrids and non-epoxy platforms, adhesion of applied coatings, and adhesion promotion, including reactive and functional silicones Perfect for formulation and research and development scientists and engineers at any technical level, Applied Coatings will also benefit research professors and students studying coatings, adhesives, composites, electronic materials, and more.
Handbook of Flame Retardants contains an extensive evaluation of the existing literature, products and patents related to flame retardance. As a perfect complement to The Databook of Flame Retardants, this book explains the roles, selection, mechanisms of action, use in different polymers and products, and health and environmental issues of over 350 different products. Chapters highlight the fundamentals of material burning and the associated stages of heat, flame and smoke, properties and mechanisms, and preventive, delaying and extinguishing attributes of 27 chemical groups of flame retardants. Examples of synergistic and antagonistic actions of various additives are discussed next, along with testing methods. The book concludes with chapters providing guidance on optimal selection of flame retardants for various polymers and information on the toxicity of flame retardants and their effects on the environment. - Evaluates the existing literature, products and patents related to flame retardance - Covers the fundamentals of material burning and associated stages of heat, flame and smoke - Outlines and evaluates the properties of 27 chemical groups of flame retardants - Provides examples of synergistic and antagonistic actions of various additives - Looks at methods of testing flame retardants and quantifies their effect on products
The use of nanotechnologies continues to grow, as nanomaterials have proven their versatility and use in many different fields and industries within the scientific profession. Using nanotechnology, materials can be made lighter, more durable, more reactive, and more efficient leading nanoscale materials to enhance many everyday products and processes. With many different sizes, shapes, and internal structures, the applications are endless. These uses range from pharmaceutics to materials such as cement or cloth, electronics, environmental sustainability, and more. Therefore, there has been a recent surge of research focused on the synthesis and characterizations of these nanomaterials to better understand how they can be used, their applications, and the many different types. The Research Anthology on Synthesis, Characterization, and Applications of Nanomaterials seeks to address not only how nanomaterials are created, used, or characterized, but also to apply this knowledge to the multidimensional industries, fields, and applications of nanomaterials and nanoscience. This includes topics such as both natural and manmade nanomaterials; the size, shape, reactivity, and other essential characteristics of nanomaterials; challenges and potential effects of using nanomaterials; and the advantages of nanomaterials with multidisciplinary uses. This book is ideally designed for researchers, engineers, practitioners, industrialists, educators, strategists, policymakers, scientists, and students working in fields that include materials engineering, engineering science, nanotechnology, biotechnology, microbiology, drug design and delivery, medicine, and more.
Polymer-based fibre-reinforced composites FRC's have now come out as a major class of structural materials being used or regarded as substituent's for metals in several critical components in space, automotive and other industries (marine, and sports goods) owing to their low density, strength-weight ratio, and fatigue strength. FRC's have several commercial as well as industrial applications ranging from aircraft, space, automotive, sporting goods, marine, and infrastructure. The above-mentioned applications of FRC's clearly reveal that FRC's have the potential to be used in a broad range of different engineering fields with the added advantages of low density, and resistance to corrosion compared to conventional metallic and ceramic composites. However, for scientists/researchers/R&D's to fabricate FRC's with such potential there should be careful and precise design followed by suitable process development based on properties like mechanical, physical, and thermal that are unique to each application. Hence the last few decades have witnessed considerable research on fibre reinforced composites. Fibre Reinforced Composites: Constituents, Compatibility, Perspectives and Applications presents a widespread all-inclusive review on fibre-reinforced composites ranging from the different types of processing techniques to chemical modification of the fibre surface to enhance the interfacial adhesion between the matrix and fibre and the structure-property relationship. It illustrates how high value composites can be produced by efficient and sustainable processing methods by selecting different constituents [fibres and resins]. Researchers in academia working in composites and accompanying areas [materials characterisation] and industrial manufacturers who need information on composite constituents and how they relate to each other for a certain application will find the book extremely useful when they need to make decisions about materials selection for their products. - Focuses on the different types of FRC's that are currently available (e.g. from polymeric matrices to metallic and ceramic matrices, from carbon fibre to different types of natural fibres and from short to long fibre reinforced), their processing techniques, characterization of different properties, and how to improve the interfacial adhesion between an incompatible fibre and matrix and their applications - Looks at crisis areas such as how to incorporate incompatible fibres and matrices together (e.g. Non-polar polypropylene matrix is not compatible with that of polar natural fibres and hence suitable surface modifications are required to make them compatible with each other) along with low cost processing methods, low density and high strength - Uncovers clarifications to both elementary and practical problems related to the fabrication of FRCs - Schematic representations depicting the interaction between different fibre types and matrices will be provided in some chapters
Smart Polymer Catalysts and Tunable Catalysis describes the latest advances in smart polymer catalysts and tunable catalysis. This book will serve as an ideal reference for scientists, students and researchers working in the fields of catalysis, chemical engineering, chemistry, materials science, biotechnology and nanotechnology. Users will find this to be a distinct, systematic and comprehensive body of knowledge on the field with its compilation of essential knowledge and discussions of extensive potential in both social and commercial impacts. - Provides a single-source summary of the emerging frontiers in scientific research in smart polymer catalysts and tunable catalysis - Includes very well-organized chapters that are illustrated with over 130 illustrations and figures - Written by scientists from prestigious universities and industries across the world - Edited by veteran researchers in the field of smart polymers and catalysis
This book covers synthesis, characterization, and applications of diverse types of nanomaterials. Specifically, it describes carbon, graphene, and graphene oxide-based nanomaterials and their use for environmental remediation; rare-earth ions-activated nanophosphors and their application; lanthanide-based oxides as advanced nanostructured materials for organic decontamination; and advanced functional nanomaterials for pollutant sensing and water remediation. The chapters explore the use of nanomaterials in solid-phase extraction technique, design of colorimetric sensor based on gold nanoparticles, optical sources and waveguides based on flexible 1D nanomaterials, synthesis and property characterization of 2D materials with applications, and the scale effects on the value of the surface energy of a solid. The developments of some nanomaterials such as zinc and nickel sulfides as photocatalysts and electrocatalysts, effects of reducing size and incorporation of nanoadditives, advanced carbon nanomaterials such as carbon nanotubes, carbon nanofibers, and graphene and its derivations as adsorbents, and carbon spheres and carbon soot for tribological applications are also presented in this book. In addition, nanomaterials for concrete coating applications and advances in the processing of high-entropy alloys by means of mechanical alloying are also covered. Subsequently, the use of nanomaterials in endodontics and the use of nanotechnology strategies to enhance restorative resin-based dental nanomaterials are reported.
Some of the futuristic applications are nanotubes for electrically conductive coatings and to increase the rate of reaction of thermoset resins; organosilane dendrimer coatings; buckyball coatings for machine parts; and metals for conductive coatings in inks. The technology is limited to substantially specialized applications due to the high cost per unit volume needed to reduce the size of the particles and the need to add surface modifiers to prevent the particles from agglomerating. Recent research efforts focus primarily on the functionalization of the particle surface of the nanoparticles to make them more compatible with the coating resin systems, so that easy dispersion, low viscosity, and covalent bonding are provided between the particles and the resins.