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Adsorption on Ordered Surfaces of Ionic Solids and Thin Films introduces to a new and topical field of surface science for which rather little experience is available at present. It reviews the recent results of the employed analytical methods comprising all modern surface techniques including scanning tunneling microscopy and various kinds of electron spectroscopies. The present status of this new, clearly defined field of surface science is nearly completely overviewed by contributions from most of the research groups active in this field. The book is meant as a basis for the expected rapid development in this area with applications in catalysis, thin-film and semiconductor technology, sensors, electrochemistry, controlled preparation of ultrathin epitaxial surfaces, and interfaces of insultors as well as future molecular electronics.
The preparation and characterization of monolayer and multilayer films of organic molecules, physically and chemically absorbed on surfaces are discussed with special attention paid to the remarkable properties of Langmuir-Blodgett films. Dynamics of reactions at surfaces and details of the potential energy hypersurface (enabling absorption and reaction of molecules) are explored. A variety of techniques sensitive to local adsorbate structure are covered and compared with techniques which probe long-range order. Adsorption and reactions at semiconductor surfaces emphasizing fundamental studies using surface and/or gas analysis methods are covered. The relevance of this work to etching, chemical vapour and other deposition processes is highlighted. New techniques permitting the study of structure at the atomic level at condensed interfaces, as well as single molecular events are detailed.