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The debt of modern chemistry to Antoine Lavoisier (1743–1794) is incalculable. With Lavoisier's discoveries of the compositions of air and water (he gave the world the term 'oxygen') and his analysis of the process of combustion, he was able to bury once and for all the then prevalent phlogiston doctrine. He also recognized chemical elements as the ultimate residues of chemical analysis and, with others, worked out the beginnings of the modern system of nomenclature. His premature death at the hands of a Revolutionary tribunal is undoubtedly one of the saddest losses in the history of science. Lavoisier's theories were promulgated widely by a work he published in 1789: Traité élémentairede Chimie. The famous English translation by Robert Kerr was issued a year later. Incorporating the notions of the "new chemistry," the book carefully describes the experiments and reasoning which led Lavoisier to his conclusions, conclusions which were generally accepted by the scientific community almost immediately. It is not too much to claim that Lavoisier's Traité did for chemistry what Newton's Principia did for physics, and that Lavoisier founded modern chemistry. Part One of the Traité covers the composition of the atmosphere and water, and related experiments, one of which (on vinous fermentation) permits Lavoisier to make the first explicit statement of the law of the conservation of matter in chemical change. The second part deals with the compounds of acids with various bases, giving extensive tables of compounds. Its most significant item, however, is the table of simple substances or elements — the first modern list of the chemical elements. The third section of the book reviews in minute detail the apparatus and instruments of chemistry and their uses. Some of these instruments, etc. are illustrated in the section of plates at the end. This new facsimile edition is enhanced by an introductory essay by Douglas McKie, University College London, one of the world's most eminent historians of science. Prof. McKie gives an excellent survey of historical developments in chemistry leading up to the Traité, Lavoisier's major contributions, his work in other fields, and offers a critical evaluation of the importance of this book and Lavoisier's role in the history of chemistry. This new essay helps to make this an authoritative, contemporary English-language edition of one of the supreme classics of science.
The book is a treatise on solid propellants in nine chapters, covering the history, chemistry, energetics, processing and characterization aspects of composite solid propellants, internal ballistics, advanced solid propellants, safety, quality and reliability and homogenous or double base propellants. The book also traces the evolution of solid propellant technology in ISRO for launch vehicles and sounding rockets. There is a detailed table of contents, expanded index, glossary, exhaustive references and questions in each chapter. It can be used as a textbook for science and engineering students, as a reference book for researchers and as a companion to scientists and engineers working in the research, development and production areas of solid propellants.
Volume two begins with Goethe's theories of affinities, i.e. the chemical reaction view of human life in 1809. This is followed by the history of how the thermodynamic (1876) and quantum (1905) revolutions modernized chemistry such that affinity (the 'force' of reaction) is now viewed as a function of thermodynamic 'free energy' (reaction spontaneity) and quantum 'valency' (bond stabilities). The composition, energetic state, dynamics, and evolution of the human chemical bond A?B is the centerpiece of this process. The human bond is what gives (yields) and takes (absorbs) energy in life. The coupling of this bond energy, driven by periodic inputs of solar photons, thus triggering activation energies and entropies, connected to the dynamical work of life, is what quantifies the human reaction process. This is followed by topics including mental crystallization, template theory, LGBT chemistry, chemical potential, Le Chatelier's principle, Muller dispersion forces, and human thermodynamics.
The last quarter-century has been marked by the extremely rapid growth of the solid-state sciences. They include what is now the largest subfield of physics, and the materials engineering sciences have likewise flourished. And, playing an active role throughout this vast area of science and engineer ing have been very large numbers of chemists. Yet, even though the role of chemistry in the solid-state sciences has been a vital one and the solid-state sciences have, in turn, made enormous contributions to chemical thought, solid-state chemistry has not been recognized by the general body of chemists as a major subfield of chemistry. Solid-state chemistry is not even well defined as to content. Some, for example, would have it include only the quantum chemistry of solids and would reject thermodynamics and phase equilibria; this is nonsense. Solid-state chemistry has many facets, and one of the purposes of this Treatise is to help define the field. Perhaps the most general characteristic of solid-state chemistry, and one which helps differentiate it from solid-state physics, is its focus on the chemical composition and atomic configuration of real solids and on the relationship of composition and structure to the chemical and physical properties of the solid. Real solids are usually extremely complex and exhibit almost infinite variety in their compositional and structural features.
In A Tale of Seven Elements, Eric Scerri presents the fascinating history of those seven elements discovered to be mysteriously "missing" from the periodic table in 1913.
Biographies of more than 100 Irish scientists (or those with strong Irish connections), in the disciplines of Chemistry and Physics, including Astronomy, Mathematics etc., describing them in their Irish and international scientific, social, educational and political context. Written in an attractive informal style for the hypothetical 'educated layman' who does not need to have studied science. Well received in Irish and international reviews.
V.4 Aqueous solutions of amphiphiles and macromolecules. Author, subject and compound indexes.