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Corrosion and scaling problems have a significant impact on geothermal plant economics. A power plant must amortize the capital investment over a 20-year period and achieve satisfactory operating efficiency to achieve financial success. Corrosion and scale incrustations have been encountered in all geothermal plants, and to various degrees, adversely affected plant life times and power output. Using published data this report analyzes known geothermal corrosion and scaling phenomena for significant cost impacts on plant design and operation. It has been necessary to speculate about causes and mechanisms in order to estimate impacts on conceptual geothermal plants. Silica is highly soluble in hot geothermal water and solubility decreases as water is cooled in a geothermal power plant. Calculations indicate as much as 30,000 tons/year could pass through a 100 MWe water cycle plant. The major cost impact will be on the reinjection well system where costs of 1 to 10 mills/kwhr of power produced could accrue to waste handling alone. On the other hand, steam cycle geothermal plants have a definite advantage in that significant silica problems will probably only occur in hot dry rock concepts, where steam above 250 C is produced. Calculation methods are given for estimating the required size and cost impact of a silica filtration plant and for sizing scrubbers. The choice of materials is significantly affected by the pH of the geothermal water, temperature, chloride, and H{sub s} contents. Plant concepts which attempt to handle acid waters above 180 C will be forced to use expensive corrosion resistant alloys or develop specialized materials. On the other hand, handling steam up to 500 C, and pH 9 water up to 180 C appears feasible using nominal cost steels, typical of today's geothermal plants. A number of factors affecting plant or component availability have been identified. The most significant is a corrosion fatigue problem in geothermal turbines at the Geyser's geothermal plant which is presently reducing plant output by about 10%. This is equivalent to over $3 million per year in increased oil consumption to replace the power. In the course of assessing the cost implications of corrosion and scaling problems, a number of areas of technological uncertainty were identified which should be considered in R and D planning in support of geothermal energy. Materials development with both laboratory and field testing will be necessary. The economic analysis on which this report is based was done in support of an AEC Division of Applied Technology program to assess the factors affecting geothermal plant economics. The results of this report are to be used to develop computer models of overall plant economics, of which corrosion and scaling problems are only a part. The translation of the economic analysis to the report which appears here, was done on AEC Special Studies Funds.
It is generally recognized that corrosion and scaling problems could seriously affect the operation and electric power production from a geothermal power plant. The Electric Power Research Institute (EPRI) has sponsored a study at Battelle-Northwest (BNW) to develop a brine chemistry data base and analytical tools to analyze how corrosion and scaling affect the degradation of the power output of a geothermal plant. The GEOSCALE computer model is a steady-state thermal hydraulics code that describes the process parameters of the power plant. At present the multistage flash and binary cycle plants are being analyzed. Initially the code computes the power output from a given geothermal brine flow and provides flow rates, temperature, velocities at points from the bottom of the production wells through the plant to the waste injection system. Based on the starting brine chemistry and these process parameters, corrosion and scaling rates will be estimated at points throughout the system. The amount of scale formation in a time interval will be calculated and the impact on brine flows and heat transfer calculated, resulting in a new set of plant process parameters for the next iteration. The iterations continue until some portion of the plant is degraded to a process limit or a plant life of 20 to 30 years is reached. Obviously the most difficult part of this analysis is the lack of valid analytical expressions and supporting rate data to calculate scaling. The general approach to the scaling rate equations is that the rate of buildup is proportional to the degree of insolubility of a mineral minus the rate of mechanical removal. They are very interested in all current scaling work that could help in providing scaling kinetics data related to process parameters so they can test these analytical expressions. The program includes a computer subroutine for calculating mineral insolubilities as brines cool, a chemical and structural analysis of several actual scale samples and a laboratory experimental program to examine scaling kinetics.