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This book presents a detailed study of different approaches to synthesis for 2D Borophene, its peculiar properties, and its use in different applications such as energy storage, catalysis, hydrogen evolution reactions, supercapacitors, optoelectronics, sensors, diagnostics, bioimaging, drug delivery, cancer therapy, and various other practical applications. This book integrates and sets the evolving knowledge and approaches to utilizing Borophene as an alternative 2D nanomaterial for commercialization in real-life applications. The book covers emerging innovative topics of relevance to scientists, academicians, and innovators in the field of energy storage, sensing, optoelectronics, nanoelectronics, and biomedical applications for further research and development.
Ever since the discovery of graphene, two-dimensional layered materials (2DLMs) have been the central tool of the materials research community. The reason behind their importance is their superlative and unique electronic, optical, physical, chemical and mechanical properties in layered form rather than in bulk form. The 2DLMs have been applied to electronics, catalysis, energy, environment, and biomedical applications. The following topics are discussed in the book’s fifteen chapters: • The research status of the 2D metal-organic frameworks and the different techniques used to synthesize them. • 2D black phosphorus (BP) and its practical application in various fields. • Reviews the synthesis methods of MXenes and provides a detailed discussion of their structural characterization and physical, electrochemical and optical properties, as well as applications in catalysis, energy storage, environmental management, biomedicine, and gas sensing. • The carbon-based materials and their potential applications via the photocatalytic process using visible light irradiation. • 2D materials like graphene, TMDCs, few-layer phosphorene, MXene in layered form and their heterostructures. • The structure and applications of 2D perovskites. • The physical parameters of pristine layered materials, ZnO, transition metal dichalcogenides, and heterostructures of layered materials are discussed. • The coupling of graphitic carbon nitride with various metal sulfides and oxides to form efficient heterojunction for water purification. • The structural features, synthetic methods, properties, and different applications and properties of 2D zeolites. • The methods for synthesizing 2D hollow nanostructures are featured and their structural aspects and potential in medical and non-medical applications. • The characteristics and structural aspects of 2D layered double hydroxides (LDHs) and the various synthesis methods and role of LDH in non-medical applications as adsorbent, sensor, catalyst, etc. • The synthesis of graphene-based 2D layered materials synthesized by using top-down and bottom-up approaches where the main emphasis is on the hot-filament thermal chemical vapor deposition (HFTCVD) method. • The different properties of 2D h-BN and borophene and the various methods being used for the synthesis of 2D h-BN, along with their growth mechanism and transfer techniques. • The physical properties and current progress of various transition metal dichalcogenides (TMDC) based on photoactive materials for photoelectrochemical (PEC) hydrogen evolution reaction. • The state-of-the-art of 2D layered materials and associated devices, such as electronic, biosensing, optoelectronic, and energy storage applications.
A hexagonal boron nitride nanosheet (BNNS) is an atomic-thick 2D material that exhibits many interesting properties such as high chemical stability and excellent mechanical and thermal properties. In Chapter One, the authors introduce two methods for the exfoliation of BNNS from hexagonal boron nitride (hBN). Then, methodologies for the surface functionalisation and nanocomposite construction are demonstrated by two BNNS based nanocomposites. The catalytic performance of the BNNS based nanocomposites is also evaluated and discussed in detail. Chapter two evaluates the formation of rolled hexagonal boron nitride nano-sheets (h-BN nanoscrolls) on their unique morphology, magnetic properties and applications. Due to the high chemical and thermal stabilities, as well as atomically smooth surfaces with free of dangling bonds, hBN has been used as barriers, passivation and support layers in 2D electronic devices, to maximise the electrical and optical characterisation of 2D materials. However, there still remains a challenge in obtaining large-area and high-quality hBN film for real 2D electronic devices. Chapter Three focuses on chemical vapor deposition (CVD), a promising method to overcome these limitations. Chapter Four discusses how a boron doped armchair graphene ribbon has been shown by cyclic voltammetry to be a potential catalyst to replace platinum, however the reaction catalysed was not identified. The authors use density functional calculations to show the reaction catalysed is likely dissociation of HO2. Chapter Five reveals a novel and industrially feasible route to incorporate boron nitride nanoparticles (BNNPs) in radiation-shielding aerospace structural materials. Chapter Six deals with the preparation and characterisation of boron nitride nanotube (BNNT)-reinforced biopolyester matrices. The morphology, hydrophilicity, biodegradability, cytotoxicity, thermal, mechanical, tribological and antibacterial properties of the resulting nanocomposites are discussed in detail. Chapter Seven presents theoretical estimations regarding the compressive buckling response of single walled boron nitride nanotubes (SWBNNTs), which have a similar crystal structure as single walled carbon nanotubes (SWCNTs). Moreover, SWBNNTs have excellent mechanical, insulating and dielectric properties. Finally, Chapter Eight shows how the different exchange mechanisms can be distinguished and measured by studying solid films where part of the 3He is replaced by immobile Ne atoms. The authors also show how the formation energy of vacancies and vacancy tunneling frequency can be obtained from NMR studies at high temperature.
There are only a few discoveries and new technologies in materials science that have the potential to dramatically alter and revolutionize our material world. Discovery of two-dimensional (2D) materials, the thinnest form of materials to ever occur in nature, is one of them. After isolation of graphene from graphite in 2004, a whole other class of atomically thin materials, dominated by surface effects and showing completely unexpected and extraordinary properties, has been created. This book provides a comprehensive view and state-of-the-art knowledge about 2D materials such as graphene, hexagonal boron nitride (h-BN), transition metal dichalcogenides (TMD) and so on. It consists of 11 chapters contributed by a team of experts in this exciting field and provides latest synthesis techniques of 2D materials, characterization and their potential applications in energy conservation, electronics, optoelectronics and biotechnology.
This book addresses the development, properties, and applications of atomic-layered boron, or, borophene. The authors explain how borophene was predicted and created before investigating the properties that make it a desirable and useful material. The material is extremely thin and possesses exotic quantum states of new Dirac physics. Applications in superconductivity, plasmonics, and industrial chemical catalysis are examined, along with an examination of the material’s unique hydrogen boride and boron nitride forms. Given the varied potential uses for the new-developed borophene, this timely book will be useful to researchers in academia and industry.
Membranes already have important applications in artificial organs, the processing of biotechnological products, food manufacture, waste water treatment, and seawater desalination. Their uses in gaseous mixture separations are, however, far from achieving their full potential. Separation of air components, natural gas dehumidification and sweeting, separation and recovery of CO2 from biogas, and H2 from refinery gases are all examples of current industrial applications. The use of membranes for reducing the greenhouse effect and improving energy efficiency has also been suggested. New process intensification strategies in the petrochemical industry have opened up another growth area for gas separation membrane systems and membrane reactors. This two volume set presents the state-of-the-art in membrane engineering for the separation of gases. It addresses future developments in carbon capture and utilization, H2 production and purification, and O2/N2 separation. Topics covered include the: applications of membrane gas separation in the petrochemical industry; implementation of membrane processes for post-combustion capture; commercial applications of membranes in gas separations; simulation of membrane systems for CO2 capture; design and development of membrane reactors for industrial applications; Pd-based membranes in hydrogen production; modelling and simulation of membrane reactors for hydrogen production and purification; novel hybrid membrane/pressure swing adsorption process for gas separation; molecular dynamics as a new tool for membrane design, and physical aging of membranes for gas separations. Volume 2 looks at problems combined with membrane reactors.
Comprehensive Nanoscience and Technology, Second Edition, Five Volume Set allows researchers to navigate a very diverse, interdisciplinary and rapidly-changing field with up-to-date, comprehensive and authoritative coverage of every aspect of modern nanoscience and nanotechnology. Presents new chapters on the latest developments in the field Covers topics not discussed to this degree of detail in other works, such as biological devices and applications of nanotechnology Compiled and written by top international authorities in the field
Since the discovery of graphene, two-dimensional nanomaterials including Transition metal dichalcogenides (TMDCs), Hexagonal Boron Nitride (hBN), non-layered compounds, black phosphorous, and Xenes with large lateral dimensions, have emerged as promising candidates for heterogenous electrocatalysis owing to their exceptional physical, chemical, and electronic properties. The tremendous opportunities of using 2D nanomaterials in electrochemical CO2 reduction arises from their unique properties and vast number of applications. Covering the fundamentals, properties, and applications, all aspects of 2D nanomaterial composites within carbon dioxide conversion are discussed. The industrial scale-up and new challenges that exist in the field of electrochemical reduction of carbon dioxide will also be presented. With chapters written by internationally recognized researchers, this state-of-the-art overview will serve the growing interest amongst academic and industrial researchers in understanding 2D nanomaterials composites, their hidden interfaces and nanoscale dispersion of the metal oxide with nanocomposites for specific uses in carbon dioxide conversion to chemicals for fuel applications. This book will be of interest to graduate students and researchers in materials science, energy, and environmental science, as well as those in industry.
This book details 2D nanomaterials, and their important applications—including recent developments and related scalable technologies crucial to addressing strong societal demands of energy, environmental protection, and worldwide health concerns—are systematically documented. It covers syntheses and structures of various 2D materials, electrical transport in graphene, and different properties in detail. Applications in important areas of energy harvesting, energy storage, environmental monitoring, and biosensing and health care are elaborated. Features: Facilitates good understanding of concepts of emerging 2D materials and its applications. Covers details of highly sensitive sensors using 2D materials for environmental monitoring. Outlines the role of 2D materials in improvement of energy harvesting and storage. Details application in biosensing and health care for the realization of next-generation biotechnologies for personalized health monitoring and so forth. Provides exclusive coverage of inorganic 2D MXenes compounds. This book is aimed at graduate students and researchers in materials science and engineering, nanoscience and nanotechnology, and electrical engineering.