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The Science and Technology of Rubber, Third Edition provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity. As in the 2nd edition, the emphasis remains on a unified treatment of the material; exploring topics from the chemical aspects such as elastomer synthesis and curing, through recent theoretical developments and characterization of equilibrium and dynamic properties, to the final applications of rubber, including tire engineering and manufacturing. Many advances have been made in polymer and elastomers research over the past ten years since the 2nd edition was published. Updated material stresses the continuous relationship between the ongoing research in synthesis, physics, structure and mechanics of rubber technology and industrial applications. Special attention is paid to recent advances in rubber-like elasticity theory and new processing techniques for elastomers. This new edition is comprised of 20% new material, including a new chapter on environmental issues and tire recycling.
In recent years organic sulfur chemistry has been growing at an even faster pace than the very rapid development in other fields of chemistry. This phenomenal growth is undoubtedly a reflection of industrial and public demands: not only was sulfur recently in overall surplus for the first time in the history of the chemical industry but it has now become a prin cipal environmental hazard in the form of sulfur dioxide, sulfuric acid and hydrogen sulfide. Another reason, discernible in the last fifteen years, has been the desire, on the part of individual chemists and all types of research managers, to move away from the established chemistry of carbon into the less well understood and sometimes virgin chemistries of the other elements which form covalent bonds. As a result of this movement the last decade has seen the development of sulfur chemistry into a well-organized and now much better understood branch of organic chemistry. Enough of the detail has become clear to see mechanistic interrelationships between previously unconnected reactions and with this clarification the whole subject has in tum become systema tized and subdivided. The divalent sulfur chemistry of thiols, monosulfides, disulfides and polysulfides is a large area in itself, much of it devoted to oxidation-reduction and the breakage and formation of sulfur-sulfur bonds, although interesting discoveries are now being made about the reac tivity of certain sulfur-carbon bonds. Of course, this area has its own mas sive biochemical branch involving enzymes and proteins.
About ten years after the publication of the Second Edition (1973), it became apparent that it was time for an up-date of this book. This was especially true in this case, since the subject matter has traditionally dealt mainly with the structure, properties, and technology of the various elastomers used in industry, and these are bound to undergo significant changes over the period of a decade. In revising the contents of this volume, it was thought best to keep the orig inal format. Hence the first five chapters discuss the same general subject matter as before. The chapters dealing with natural rubber and the synthetic elastomers are up-dated, and an entirely new chapter has been added on the thermoplastic elastomers, which have, of course, grown tremendously in importance. Another innovation is the addition of a new chapter, "Miscellaneous Elastomers," to take care of "old" elastomers, e.g., polysulfides, which have decreased some what in importance, as well as to introduce some of the newly-developed syn thetic rubbers which have not yet reached high production levels. The editor wishes to express his sincere appreciation to all the contributors, without whose close cooperation this task would have been impossible. He would especially like to acknowledge the invaluable assistance of Dr. Howard Stephens in the planning of this book, and for his suggestion of suitable authors.
Elastomers and Rubber Compounding Materials reviews the properties of elastomers and particular groups of ingredients and chemicals mixed into the basic elastomer to form a rubber compound. After introducing the history of rubber industry and the general properties of rubber, the book discusses the properties, classification, concentration, stabilization, modification, application, transport, and storage of latex. It presents as well the methods of production, composition, physical properties, and chemical reactions of dry rubber. The book then focuses on the production and classification of different synthetic rubbers, such as styrene-butadiene, isoprene, butadiene, ethylene-propylene, and chloroprene. It also discusses the production, properties, and applications of elastomers, vulcanization chemicals, fillers, stabilizers, plasticizers, blowing agents, and textile reinforcing materials used in formulating rubber compounds. This book will be of great value not only to those who are in the rubber industry, but also to students of polymer science and rubber technology.
Chemistry, Manufacture and Applications of Natural Rubber, Second Edition presents the latest advances in the processing, properties and advanced applications of natural rubber (NR), drawing on state-of-the-art research in the field. Chapters cover manufacturing, processing and properties of natural rubber, describing biosynthesis, vulcanization for improved performance, strain-induced crystallization, self-reinforcement, rheology and mechanochemistry for processing, computer simulation of properties, scattering techniques and stabilizing agents. Applications covered include natural rubber, carbon allotropes, eco-friendly soft bio-composites using NR matrices and marine products, the use of NR for high functionality such as shape memory, NR for the tire industry, and natural rubber latex with advanced applications. This is an essential resource for academic researchers, scientists and (post)graduate students in rubber science, polymer science, materials science and engineering, and chemistry. In industry, this book enables professionals, R&D, and producers across the natural rubber, tire, rubber and elastomer industries, as well as across industries looking to use natural rubber products, to understand and utilize natural rubber for cutting-edge applications. - Explains the latest manufacture and processing techniques for natural rubber (NR) with enhanced properties - Explores novel applications of natural rubber across a range of industries, including current and potential uses - Discusses resources and utilization, and considers sustainable future development of natural rubber
Written and edited by experts on specialty elastomers applications in the mechanical and automotive products industries, the Handbook of Specialty Elastomers provides a single source reference for the design of compounds using specialty elastomers. This book defines specialty elastomers as heat-, oil-, fuel-, and solvent-resistant polymer
Distinguishing among blends, alloys and other types of combinations, clarifying terminology and presenting data on new processes and materials, this work present up-to-date and effective compounding techniques for polymers. It offers extensive analyses on the challenging questions that surround miscibility, compatibility, dynamic processing, interaction/phase behaviour, and computer simulations for predicting behaviours of polymer mixture and interaction.
This book provides an extensive overview of current trends in the area of elastomers and their composites from the chapters contributed by internationally recognized specialists. The book deals with novel synthesis, modelling and experimental methods in elastomers. Contents include: new approach to crosslinking, liquid crystal elastomers, nanocomposites, smart elastomers, elastomers in microelectronics and microfluidics, elastomers in cement concrete and mortar, experimental testing and modelling. Each section demonstrates how enhancements in materials, processes and characterization techniques can improve performance in the field of engineering. The book provides a unique opportunity to discover the latest research on elastomer advances from laboratories around the world. This book addresses to industrial and academic researchers in the fields of physical, chemical, biological sciences and engineering.
This is the first volume of a two-volume work which summarizes in an edited format and in a fairly comprehensive manner many of the recent technical research accomplishments in the area of Elastomers. “Advances in Elastomers” discusses the various attempts reported on solving these problems from the point of view of the chemistry and the structure of elastomers, highlighting the drawbacks and advantages of each method. It summarize the importance of elastomers and their multiphase systems in human life and industry, and covers all the topics related to recent advances in elastomers, their blends, IPNs, composites and nanocomposites. This first volume focuses on advances on the blends and interpenetrating networks (IPNs) of elastomers.
Rubber materials serve a variety of purposes in our everyday life. This book gives a complete survey of the life cycle of rubber materials starting from the basics and covering everything to recycling of rubber. The important aspects for researchers and engineers in rubber industry such as vulcanization, thermoplastic elastomers, additives and fillers and rubber bonding is covered in one chapter each.