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The phenomenal growth of science and technology As a complementary effort to its Data Tables has brought about a universal appreciation of the fact Series, TPRC published in 1967 a work entitled that present limitations in many technical develop "Thermo physical Properties Research Literature Re ments are often a direct result of the paucity of knowl trieval Guide. " This three-book work reported 33,700 edge on material properties. Engineering develop references on seven thermophysical property groups ments in the years ahead will be closely linked to the and about 45,000 materials. This Basic Edition sys research that is done today to contribute to a better tematically covered the world's unclassified literature understanding of the properties of matter, of which published essentially between 1920 and mid-1964, in thermophysical properties constitute a major segment. many instances going much earlier. While research on the properties of materials con The present work, referred to as Supplement I to tinues, adequate steps are not being taken to ensure the Basic Edition, reports an additional 26,000 refer that this invaluable body of information be coordi ences on sixteen thermophysical properties of 20,000 nated, synthesized, organized, and disseminated to materials, covering the years from mid-1964 to 1971. the ultimate user, namely, the individual scientist and An additional 9,000 synonyms and trade names are engineer. cross-referenced to assist the user in identifying the material or substance of interest.
The 'Red Book' is the definitive guide for scientists requiring internationally approved inorganic nomenclature in a legal or regulatory environment.
When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century. Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will not only value during their formal education, but will keep and refer to throughout their careers as chemists. - Completely revised and updated - Unique approach to the subject - More comprehensive than competing titles
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Solubilities of Inorganic and Organic Compounds, Volume 1: Binary Systems, Part 1 is part of an approximately 5,500-page manual containing a selection from the International Chemical Literature on the Solubilities of Elements, Inorganic Compounds, Metallo-organic and Organic Compounds in Binary, Ternary and Multi-component Systems. A careful survey of the literature in all languages by a panel of scientists specially appointed for the task by the U.S.S.R. Academy of Sciences, Moscow, has made the compilation of this work possible. The complete English edition in five separately bound volumes will be published during 1963. Volume 1, parts 1 and 2, comprises the solubilities of elements, inorganic compounds, metallo-organic and organic compounds in binary systems. Volume II, parts 1, 2 and 3, comprises the solubilities in ternary and multi-component systems. The systematic arrangement of the compounds and the solvents together with the distinct and separate—binary, ternary, and multicomponent systems—ensures that the information required may be easily located. This manual will be of value to research workers, teaching establishments, and industry.
Descriptive Inorganic Chemistry, Second Edition, covers the synthesis, reactions, and properties of elements and inorganic compounds for courses in descriptive inorganic chemistry. This updated version includes expanded coverage of chemical bonding and enhanced treatment of Buckminster Fullerenes, and incorporates new industrial applications matched to key topics in the text. It is suitable for the one-semester (ACS-recommended) course or as a supplement in general chemistry courses. Ideal for majors and non-majors, the book incorporates rich graphs and diagrams to enhance the content and maximize learning. - Includes expanded coverage of chemical bonding and enhanced treatment of Buckminster Fullerenes - Incorporates new industrial applications matched to key topics in the text
An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Solubilities of Inorganic and Organic Compounds, Volume 2: Ternary Systems, Part I focuses on a selection from the International Chemical Literature on the Solubilities of Elements, Inorganic Compounds, Metallo-organic Compounds, and Organic Compounds in Ternary and Multicomponent Systems. The book underscores that Tables 1-4955 deal with Ternary Systems, while Tables 4956 et seq. are devoted to Multicomponent Systems. The first tables are systems in which an Element is a component, and these are supported by data for systems containing Inorganic Compounds and then Metallo-organic Compounds. The ion of ammonia is placed at the end of the first Group. The text also presents the arrangement of the compounds of elements. These include oxides and their hydrates and salts of halogen and other acids. The book is a dependable reference for readers interested in studying the solubilities of inorganic and organic compounds.